Hydrolysis Rates of Polysubstituted Phenyl Benzoates

Hydrolysis Rates of Polysubstituted Phenyl Benzoates PDF Author: Stephen Winter Tobey
Publisher:
ISBN:
Category :
Languages : en
Pages : 80

Get Book Here

Book Description

Hydrolysis Rates of Polysubstituted Phenyl Benzoates

Hydrolysis Rates of Polysubstituted Phenyl Benzoates PDF Author: Stephen Winter Tobey
Publisher:
ISBN:
Category :
Languages : en
Pages : 80

Get Book Here

Book Description


Substituent, Temperature and Solvent Effects on the Alkaline Hydrolysis of Substituted Phenyl and Alkyl Esters of Benzoic Acid

Substituent, Temperature and Solvent Effects on the Alkaline Hydrolysis of Substituted Phenyl and Alkyl Esters of Benzoic Acid PDF Author: Mare Piirsalu
Publisher:
ISBN:
Category : Hydrolysis
Languages : en
Pages : 162

Get Book Here

Book Description


Boronic Acids

Boronic Acids PDF Author: Dennis G. Hall
Publisher: John Wiley & Sons
ISBN: 3527606823
Category : Science
Languages : en
Pages : 571

Get Book Here

Book Description
For the first time, the whole field of organoboronic acids is presented in one comprehensive handbook. Professor Dennis Hall, a rising star within the community, covers all aspects of this important substance class, including applications in chemistry, biology and medicine. Starting with an introduction to the structure, properties, and preparation of boronic acid derivatives, together with an overview of their reactions and applications, the book goes on to look at metal-catalyzed borylation of alkanes and arenas, coupling reactions and rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds. There follows chapters on copper-promoted C-O and C-N cross-coupling of boronic acids, recent applications in organic synthesis, as well as alpha-haloalkylboronic esters in asymmetric synthesis. Later sections deal with cycloadditions, organoboronic acids, oxazaborolidines as asymmetric inducers, and boronic acid based receptors and sensors. The whole is rounded off with experimental procedures, making this invaluable reading for organic, catalytic and medicinal chemists, as well as those working in organometallics.

Side Reactions in Organic Synthesis

Side Reactions in Organic Synthesis PDF Author: Florencio Zaragoza Dörwald
Publisher: John Wiley & Sons
ISBN: 3527604987
Category : Science
Languages : en
Pages : 389

Get Book Here

Book Description
Most syntheses in the chemical research laboratory fail and usually require several attempts before proceeding satisfactorily. Failed syntheses are not only discouraging and frustrating, but also cost a lot of time and money. Many failures may, however, be avoided by understanding the structure-reactivity relationship of organic compounds. This textbook highlights the competing processes and limitations of the most important reactions used in organic synthesis. By allowing chemists to quickly recognize potential problems this book will help to improve their efficiency and success-rate. A must for every graduate student but also for every chemist in industry and academia. Contents: 1 Organic Synthesis: General Remarks 2 Stereoelectronic Effects and Reactivity 3 The Stability of Organic Compounds 4 Aliphatic Nucleophilic Substitutions: Problematic Electrophiles 5 The Alkylation of Carbanions 6 The Alkylation of Heteroatoms 7 The Acylation of Heteroatoms 8 Palladium-Catalyzed C-C Bond Formation 9 Cyclizations 10 Monofunctionalization of Symmetric Difunctional Substrates

Artificial Metalloenzymes and MetalloDNAzymes in Catalysis

Artificial Metalloenzymes and MetalloDNAzymes in Catalysis PDF Author: Montserrat Diéguez
Publisher: John Wiley & Sons
ISBN: 3527804072
Category : Technology & Engineering
Languages : en
Pages : 431

Get Book Here

Book Description
An important reference for researchers in the field of metal-enzyme hybrid catalysis Artificial Metalloenzymes and MetalloDNAzymes in Catalysis offers a comprehensive review of the most current strategies, developed over recent decades, for the design, synthesis, and optimization of these hybrid catalysts as well as material about their application. The contributors—noted experts in the field—present information on the preparation, characterization, and optimization of artificial metalloenzymes in a timely and authoritative manner. The authors present a thorough examination of this interesting new platform for catalysis that combines the excellent selective recognition/binding properties of enzymes with transition metal catalysts. The text includes information on the various applications of metal-enzyme hybrid catalysts for novel reactions, offers insights into the latest advances in the field, and contains an informative perspective on the future: Explores the development of artificial metalloenzymes, the modern and strongly evolving research field on the verge of industrial application Contains a comprehensive reference to the research area of metal-enzyme hybrid catalysis that has experienced tremendous growth in recent years Includes contributions from leading researchers in the field Shows how this new catalysis combines the selective recognition/binding properties of enzymes with transition metal catalysts Written for catalytic chemists, bioinorganic chemists, biochemists, and organic chemists, Artificial Metalloenzymes and MetalloDNAzymes in Catalysis offers a unique reference to the fundamentals, concepts, applications, and the most recent developments for more efficient and sustainable synthesis.

Energetic Compounds

Energetic Compounds PDF Author: Mohammad Hossein Keshavarz
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 311067775X
Category : Technology & Engineering
Languages : en
Pages : 143

Get Book Here

Book Description
This book discusses methods for the assessment of energetic compounds through heat of detonation, detonation pressure, velocity and temperature, Gurney energy and power. The authors focus on the detonation pressure and detonation velocity of non-ideal aluminized energetic compounds. This 2nd Edition includes an updated and improved presentation of simple, reliable methods for the design, synthesis and development of novel energetic compounds.

Organic Matter and Rice

Organic Matter and Rice PDF Author:
Publisher: Int. Rice Res. Inst.
ISBN: 9711041049
Category : Agricultural wastes
Languages : en
Pages : 642

Get Book Here

Book Description


Nitration and Aromatic Reactivity

Nitration and Aromatic Reactivity PDF Author: J. G. Hoggett
Publisher: Cambridge University Press
ISBN: 9780521080293
Category : Science
Languages : en
Pages : 266

Get Book Here

Book Description
First published in 1971 this volume claims that nitration is important because it is the most general process for the preparation of aromatic nitro-compounds.

Sourcebook of Advanced Organic Laboratory Preparations

Sourcebook of Advanced Organic Laboratory Preparations PDF Author: Stanley R. Sandler
Publisher: Academic Press
ISBN: 0080925537
Category : Science
Languages : en
Pages : 347

Get Book Here

Book Description
In the case of students, this laboratory preparations manual can be used to find additional experiments to illustrate concepts in synthesis and to augment existing laboratory texts. A name reaction index is also included to direct the reader to the location where specific reactions appear in this manual. The industrial chemist is frequently required to prepare a variety of compounds, and this manual can serve as a convenient guide to choose a synthetic route. - Offers detailed directions for the synthesis of various functional groups - Includes up-to-date references to the journal literature and patents (foreign and domestic) - Reviews the chemistry for each functional group with suggestions where additional research is needed - Name reactions are indexed along with the preparations cited

Advances in Linear Free Energy Relationships

Advances in Linear Free Energy Relationships PDF Author: N. Chapman
Publisher: Springer Science & Business Media
ISBN: 1461586607
Category : Science
Languages : en
Pages : 493

Get Book Here

Book Description
Louis P. Hammett Mitchill Professor Emeritus of Chemistry, Columbia University My interest in linear free energy relationships began when, just out of graduate school, I read in 1924 the article by Bmnsted and Pedersen which for the first time reported the existence of such a relationship. That interest continues to be an active one and, to judge merely by the extensive biblio graphies contained in the present volume, it is widely shared. To my mind a particularly happy aspect of the existence of linear free energy relationships has been the proof it supplies that one need not suppose that the behavior of nature is hopelessly complicated merely because one cannot find a theoretical reason for supposing it to be otherwise. The effect of a substituent in an organic molecule on rate or equilibrium of reaction involves a fourfold difference between relatively large quantities, a situation which always makes for difficult theory. Yet systematic organic chemistry could hardly have existed were it not true that like changes in structure lead to like changes in reactivity. Linear free energy relationships constitute the quantitative specialisation of this fundamental principle, and they stand indeed more in the office of teacher to theory than in that of learner from it.