Homologation Reactions

Homologation Reactions PDF Author: Vittorio Pace
Publisher: John Wiley & Sons
ISBN: 3527830219
Category : Science
Languages : en
Pages : 1256

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Book Description
Provides a unique summary of homologation strategies in organic synthesis Homologation Reactions presents different concepts underpinning the use of homologating reagents as well as their applications in organic synthesis. It covers in-depth discussions on the rationales governing this kind of transformations with a strong emphasis on mechanistic elements modulating critical aspects (e.g. selectivity) of the processes. In addition, this two-volume work features: Metal carbenoids, ylides, and diazo reagents Homologating agents working under nucleophilic, electrophilic, and radical regime Homologations realized on boron-containing or carbon-centered linchpins Use of highly sensitive fluorinated homologating agents Progressive homologations and the concept of assembly line synthesis Homologation processes followed by rearrangement cascades Construction of cyclic motifs and ring-expansion Homologation reactions with carbon monoxide and carbon dioxide New and/or challenging directions to expect in the future Written by an international team of leaders in the field, the book is a useful guide for designing effective transformations by using homologation reactions. It is a must-read for every synthetic chemist in academia and industry!

Homologation Reactions

Homologation Reactions PDF Author: Vittorio Pace
Publisher: John Wiley & Sons
ISBN: 3527830219
Category : Science
Languages : en
Pages : 1256

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Book Description
Provides a unique summary of homologation strategies in organic synthesis Homologation Reactions presents different concepts underpinning the use of homologating reagents as well as their applications in organic synthesis. It covers in-depth discussions on the rationales governing this kind of transformations with a strong emphasis on mechanistic elements modulating critical aspects (e.g. selectivity) of the processes. In addition, this two-volume work features: Metal carbenoids, ylides, and diazo reagents Homologating agents working under nucleophilic, electrophilic, and radical regime Homologations realized on boron-containing or carbon-centered linchpins Use of highly sensitive fluorinated homologating agents Progressive homologations and the concept of assembly line synthesis Homologation processes followed by rearrangement cascades Construction of cyclic motifs and ring-expansion Homologation reactions with carbon monoxide and carbon dioxide New and/or challenging directions to expect in the future Written by an international team of leaders in the field, the book is a useful guide for designing effective transformations by using homologation reactions. It is a must-read for every synthetic chemist in academia and industry!

Name Reactions for Homologation, Part 2

Name Reactions for Homologation, Part 2 PDF Author: Jie Jack Li
Publisher: John Wiley & Sons
ISBN: 0470487038
Category : Science
Languages : en
Pages : 874

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Book Description
"A valuable addition to the literature by any measure and surely will prove its merit in years to come. The new knowledge that arises with its help will be impressive and of great benefit to humankind." —From the Foreword by E. J. Corey, Nobel Prize Laureate An invaluable guide to name reactions and reagents for homologations Name Reactions for Homologations, Part II of Wiley's Comprehensive Name Reactions series comprises a comprehensive treatise on name reactions for homologations. With contributions from world-recognized authorities in the field, this reference offers an up-to-date, concise compilation of the most commonly used and widely known name reactions and reagents. Part II discusses Rearrangements, Asymmetric C-C Bond Formation, and Miscellaneous Homologation Reactions. Arranged alphabetically by name reactions, the listing provides: Description of the reaction Historical perspective A mechanism for the reaction Variations and improvements on the reaction Synthetic utilities of the reaction Experimental details References to the current primary literature Armed with this invaluable resource, both students and professionals will have at their fingertips a comprehensive guide to important mechanisms and phenomena in homologation.

Modern Aldol Reactions, 2 Volume Set

Modern Aldol Reactions, 2 Volume Set PDF Author: Rainer Mahrwald
Publisher: John Wiley & Sons
ISBN: 3527307141
Category : Science
Languages : en
Pages : 759

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Book Description
At long last, the complete spectrum of the aldol reaction is presented here in this two-volume handbook. Top authors guarantee contributions of the highest quality, beginning with fundamentals and then moving on to enolates and catalytic aldol reactions, including the Mukaiyama Reaction. Further sections are devoted to enzymatic aldol reactions in synthesis as well as such related reactions as the Henry, Ene and Aldol-Tishchenko reactions. The wealth of information contained here allows a comprehensive overview of this important topic in organic chemistry, removing the need for the hitherto time-consuming research among the widely dispersed literature. With a foreword by Professor D. A. Evans.

Homologation Reactions

Homologation Reactions PDF Author: Vittorio Pace
Publisher:
ISBN: 9783527351237
Category : Chemical tests and reagents
Languages : en
Pages : 0

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Book Description
Homologation Reactions presents different concepts underpinning the use of homologating reagents as well as their applications in organic synthesis. It covers in-depth discussions on the rationales governing this kind of transformations with a strong emphasis on mechanistic elements modulating critical aspects (e.g. selectivity) of the processes. In addition, this two-volume work features: Metal carbenoids, ylides, and diazo reagents; Homologating agents working under nucleophilic, electrophilic, and radical regime; Homologations realized on boron-containing or carbon-centered linchpins; Use of highly sensitive fluorinated homologating agents; Progressive homologations and the concept of assembly line synthesis; Homologation processes followed by rearrangement cascades; Construction of cyclic motifs and ring-expansion; Homologation reactions with carbon monoxide and carbon dioxide; New and/or challenging directions to expect in the future.

Comprehensive Organometallic Chemistry II, Volume 14

Comprehensive Organometallic Chemistry II, Volume 14 PDF Author: Edward W. Abel
Publisher: Elsevier
ISBN: 0080912745
Category : Science
Languages : en
Pages : 399

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Book Description
Since the publication Comprehensive Organometallic Chemistry in 1982, studies on the chemistry of molecules with carbon-metal bonds have continued to expand rapidly. This is due to many factors, ranging from the sheer intellectual challenge and excitement provided by the continuing production of novel results, which demand new ideas, through to the successful application of organometallic species in organic syntheses, the generation of living catalysts for polymerization, and the synthesis of precursors for materials employed in the electronic and ceramic industries. These factors led to the publication of the updated Comprehensive Organometallic Chemistry II. The original work serves as a basis for new volumes, focusing on organometallic chemistry reported since 1982, with reference back to the original work when necessary. For ease of use the new volumes maintain the same general structure as employed previously but reflect the changes in substance and direction the field has undergone in the last ten years. This book will serve as a pivotal reference point for new work and will function to generate new ideas and perceptions for the continued advance of what will surely continue as a vibrant area of chemistry.

Name Reactions for Homologation, Part 1

Name Reactions for Homologation, Part 1 PDF Author: Jie Jack Li
Publisher: John Wiley & Sons
ISBN: 0470487011
Category : Science
Languages : en
Pages : 733

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Book Description
"A valuable addition to the literature by any measure and surely will prove its merit in years to come. The new knowledge that arises with its help will be impressive and of great benefit to humankind." —From the Foreword by E. J. Corey, Nobel Prize Laureate An invaluable guide to name reactions and reagents for homologations Name Reactions for Homologations, Part I of Wiley's Comprehensive Name Reactions series comprises a comprehensive treatise on name reactions for homologations. With contributions from world-recognized authorities in the field, this reference offers an up-to-date, concise compilation of the most commonly used and widely known name reactions and reagents. Part I discusses Organometallics, Carbon-chain Homologation, and Radical Chemistry. Arranged alphabetically by name reactions, the listing provides: Description of the reaction Historical perspective A mechanism for the reaction Variations and improvements on the reaction Synthetic utilities of the reaction Experimental details References to the current primary literature Armed with this invaluable resource, both students and professionals will have at their fingertips a comprehensive guide to important mechanisms and phenomena in homologation.

Organic Reactions

Organic Reactions PDF Author:
Publisher: John Wiley & Sons
ISBN: 1119771218
Category : Science
Languages : en
Pages : 928

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Book Description
The 105th volume in this series for organic chemists in academia and industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Kirk-Othmer Concise Encyclopedia of Chemical Technology, 2 Volume Set

Kirk-Othmer Concise Encyclopedia of Chemical Technology, 2 Volume Set PDF Author: Kirk-Othmer
Publisher: John Wiley & Sons
ISBN: 0470047488
Category : Science
Languages : en
Pages : 2762

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Book Description
This is an easily-accessible two-volume encyclopedia summarizing all the articles in the main volumes Kirk-Othmer Encyclopedia of Chemical Technology, Fifth Edition organized alphabetically. Written by prominent scholars from industry, academia, and research institutions, the Encyclopedia presents a wide scope of articles on chemical substances, properties, manufacturing, and uses; on industrial processes, unit operations in chemical engineering; and on fundamentals and scientific subjects related to the field.

Name Reactions in Heterocyclic Chemistry II

Name Reactions in Heterocyclic Chemistry II PDF Author: Jie Jack Li
Publisher: John Wiley & Sons
ISBN: 0470085088
Category : Science
Languages : en
Pages : 704

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Book Description
The up-to-DATE guide to name reactions in heterocyclic chemistry Name Reactions in Heterocyclic Chemistry II presents a comprehensive treatise on name reactions in heterocyclic chemistry, one of the most exciting and important fields within organic chemistry today. The book not only covers fresh ground, but also provides extensive information on new and/or expanded reactions in: Three- and four-membered heterocycles Five-membered heterocycles (pyrroles and pyrrolidines, indoles, furans, thiophenes, and oxazoles) Six-membered heterocycles, including pyridines, quinolines, and isoquinolines Featuring contributions from the leading authorities in heterocyclic chemistry. Each section includes a description of the given reaction, as well as the relevant historical perspective, mechanism, variations and improvements, synthetic utilities, experimental details, and references to the current primary literature. The reactions covered in Name Reactions in Heterocyclic Chemistry have been widely adopted in all areas of organic synthesis, from the medicinal/pharmaceutical field, to agriculture, to fine chemicals, and the book brings the most cutting-edge knowledge to practicing synthetic chemists and students, along with the tools needed to synthesize new and useful molecules.

Thiophene and Its Derivatives, Volume 44, Part 3

Thiophene and Its Derivatives, Volume 44, Part 3 PDF Author: Salo Gronowitz
Publisher: John Wiley & Sons
ISBN: 0470188774
Category : Science
Languages : en
Pages : 1289

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Book Description
The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects – properties, synthesis, reactions, physiological and industrial significance – of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists.