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Author: Hartmut Zabel
Publisher: Springer Science & Business Media
ISBN: 3642752705
Category : Science
Languages : en
Pages : 365
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Book Description
The progress of materials science depends on the development of novel materials and the development of novel experimental techniques. The research on graphite intercalation compounds combines both aspects: new compounds with strikingly new and anisotropic properties have been synthesized and analyzed during the past couple of years by means of state-of-the-art experimental methods. At the same time, the preparation of the compounds already known has improved con siderably, giving increased reliability and reproducibility of the experimental results. The high quality experimental data now available have stimulated theo retical work. Moreover, the theoretical work has had a great impact on further experimental studies, with the effect of a much improved understanding of this class of materials. This volume is dedicated to a thorough description of all relevant experimen tal and theoretical aspects of the structural and dynamical properties of graphite intercalation compounds. Because of the large number of topics, a second vol ume, which is now in preparation, will follow and will treat the electronic, transport, magnetic, and optical properties. The second volume will also contain a chapter on applications of graphite intercalation compounds. There have been a number of reviews written on selected aspects of these compounds in various journals and conference proceedings during the last couple of years, but this is the first comprehensive review since the thorough overview provided by M.S. Dresselhaus and G. Dresselhaus appeared ten years ago.
Author: Hartmut Zabel
Publisher: Springer Science & Business Media
ISBN: 3642752705
Category : Science
Languages : en
Pages : 365
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Book Description
The progress of materials science depends on the development of novel materials and the development of novel experimental techniques. The research on graphite intercalation compounds combines both aspects: new compounds with strikingly new and anisotropic properties have been synthesized and analyzed during the past couple of years by means of state-of-the-art experimental methods. At the same time, the preparation of the compounds already known has improved con siderably, giving increased reliability and reproducibility of the experimental results. The high quality experimental data now available have stimulated theo retical work. Moreover, the theoretical work has had a great impact on further experimental studies, with the effect of a much improved understanding of this class of materials. This volume is dedicated to a thorough description of all relevant experimen tal and theoretical aspects of the structural and dynamical properties of graphite intercalation compounds. Because of the large number of topics, a second vol ume, which is now in preparation, will follow and will treat the electronic, transport, magnetic, and optical properties. The second volume will also contain a chapter on applications of graphite intercalation compounds. There have been a number of reviews written on selected aspects of these compounds in various journals and conference proceedings during the last couple of years, but this is the first comprehensive review since the thorough overview provided by M.S. Dresselhaus and G. Dresselhaus appeared ten years ago.
Author: Toshiaki Enoki
Publisher: Oxford University Press
ISBN: 0195351843
Category : Science
Languages : en
Pages : 453
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Book Description
Graphite intercalation compounds are a new class of electronic materials that are classified as graphite-based host guest systems. They have specific structural features based on the alternating stacking of graphite and guest intercalate sheets. The electronic structures show two-dimensional metallic properties with a large variety of features including superconductivity. They are also interesting from the point of two-dimensional magnetic systems. This book presents the synthesis, crystal structures, phase transitions, lattice dynamics, electronic structures, electron transport properties, magnetic properties, surface phenomena, and applications of graphite intercalation compounds. The applications covered include batteries, highly conductive graphite fibers, exfoliated graphite and intercalated fullerenes and nanotubes.
Author: Stanley M Whittingha
Publisher: Elsevier
ISBN: 0323140408
Category : Science
Languages : en
Pages : 614
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Book Description
Intercalation Chemistry introduces the specialist reader to the breadth of intercalation chemistry and the newcomer to the diverse research opportunities and challenges available in synthetic and reaction chemistry and also in the controlled modification of physical properties. Topics covered range from graphite chemistry to sheet silicate intercalates, diffusion and shape-selective catalysis in zeolites, organic and organometallic intercalation compounds of the transition metal dichalcogenides, and solvated intercalation compounds of layered chalcogenide and oxide bronzes. This book is comprised of 18 chapters and begins with an introduction to intercalation chemistry. The discussions that follow focus on the intercalation chemistry of graphite and of complex oxides with both two (clays and acid phosphates)- and three (zeolites)-dimensional structures, along with organic conversions that have been discovered using essentially smectite (i.e., montmorillonite- and hectorite-based) intercalates. The next chapters focus on ß-aluminas, acid salts of tetravalent metals with layered structure, and layered chalcogenides and halides with simple and hydrated cations as well as organic and organometallic ions. The book also considers the chemistry, thermodynamics, and applications of intermetallic compounds that incorporate hydrogen, intercalation in the context of biological systems, crystallographic shear structures, and intercalation reactions of oxides and chalcogenides of vanadium, molybdenum, and tungsten. The final chapter touches on the physical properties of some intercalation compounds of the dichalcogenides. This book is intended for researchers in the various materials science disciplines.
Author: F.A. Lévy
Publisher: Springer Science & Business Media
ISBN: 940099415X
Category : Science
Languages : en
Pages : 580
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Book Description
Materials with layered structures remain an extensively investigated subject in current physics and chemistry. Most of the promising technological applications however deal with intercalation compounds of layered materials. Graphite intercalation compounds have now been known for a long time. Intercalation in transition metal dichalcogenides, on the other hand, has been investigated only recently. The amount of information on intercalated layered materials has increased far beyond the original concept for this volume in the series Physics and Chemistry of Materials with Layered Structures. The large size of this volume also indicates how important this field of research will be, not only in basic science, but also in industrial and energy applications. In this volume, two classes of materials are included, generally investigated by different scientists. Graphite intercalates and intercalates of other inorganic com pounds actually constitute separate classes of materials. However, the similarity between the intercalation techniques and some intercalation processes does not justify this separation, and accounts for the inclusion of both classes in this volume. The first part of the volume deals with intercalation processes and intercalates of transition metal dichalcogenides. Several chapters include connected topics necessary to give a good introduction or comprehensive review of these types of materials. Organic as well as inorganic intercalation compounds are treated. The second part includes contributions concerning graphite intercalates. It should be noted that graphite intercalation compounds have already been mentioned in Volumes I and V.
Author: Hubert Jaeger
Publisher: John Wiley & Sons
ISBN: 3527674039
Category : Technology & Engineering
Languages : de
Pages : 1008
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Book Description
An excellent overview of industrial carbon and graphite materials, especially their manufacture, use and applications in industry. Following a short introduction, the main part of this reference deals with industrial forms, their raw materials, properties and manifold applications. Featuring chapters on carbon and graphite materials in energy application, and as catalysts. It covers all important classes of carbon and graphite, from polygranular materials to fullerenes, and from activated carbon to carbon blacks and nanoforms of carbon. Indispensable for chemists and engineers working in such fields as steel, aluminum, electrochemistry, nanotechnology, catalyst, carbon fibres and lightweight composites.
Author: Toshiaki Enoki
Publisher: Oxford University Press, USA
ISBN: 0195128273
Category : Clathrate compounds
Languages : en
Pages : 453
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Book Description
Graphite intercalation compounds are a new class of electronic materials that are classified as graphite-based host guest systems. They have specific structural features based on the alternating stacking of graphite and guest intercalate sheets. The electronic structures show two-dimensional metallic properties with a large variety of features including superconductivity. They are also interesting from the point of two-dimensional magnetic systems. This book presents the synthesis, crystal structures, phase transitions, lattice dynamics, electronic structures, electron transport properties, magnetic properties, surface phenomena, and applications of graphite intercalation compounds. The applications covered include batteries, highly conductive graphite fibers, exfoliated graphite and intercalated fullerenes and nanotubes.
Author: Michio Inagaki
Publisher: Elsevier
ISBN: 0080525709
Category : Technology & Engineering
Languages : en
Pages : 241
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Book Description
The discovery of fullerenes and nanotubes has greatly stimulated the interest of scientists and engineers in carbon materials, and has resulted in much scientific research. These materials have provided us with many interesting ideas and potential applications, some of them practical and some simply dreams for the future. In the early 1960s, carbon fibers, glass-like carbons and pyrolytic carbons were developed which were quite different from the carbon materials that had previously been used. Carbon fibers exhibited surprisingly good mechanical properties, glass-like carbons exhibited brittle fracture resulting in a conchoidal fracture surface similar to sodium glass, and giving no carbon dust, and pyrolytic carbons were produced by a new production process of chemical vapour deposition and showed very high anisotropy. These carbons materials made a great impact not only on the carbon community who had been working on carbon materials but also on people working in the fields of materials science and engineering. They were used to develop a variety of new applications in technological fields, such as semiconductors, microelectronics, aerospace and high temperature, etc. These newly developed carbon materials were called NEW CARBONS, in comparison with carbon materials such as artificial graphites represented by graphite electrodes, carbon blacks and activated carbons, which maybe thought of as CLASSICAL CARBONS. Later, other new carbons, such as activated carbons and those with novel functions, isotropic high-density graphites, intercalation compounds, various composites, etc., were developed. In 1994, Professor Michio Inagaki published a book entitled "New Carbon Materials — Structure and Functions" with his friend Professor Yoshihiro Hishiyama of Musashi Institute of Technology, published by Gihoudou Shuppan in Japanese. However, progress in the fields of these new carbons is so rapid that the previous book is already out of date. For this reason the author has decided to write an English text on New Carbons. The text focuses on New Carbons based on hexagonal networks of carbon-atoms, i.e. graphite-related materials. The fundamental concept underlying this book is that the structure and functions of these materials are principally governed by their texture. The aim is to give readers a comprehensive understanding of New Carbons through the description of their structure and texture, along with the properties that are largely dependent on them.
Author: E. Yasuda
Publisher: Elsevier
ISBN: 0080528538
Category : Science
Languages : en
Pages : 584
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Book Description
In recent years the Japanese have funded a comprehensive study of carbon materials which incorporate other elements including boron, nitrogen and fluorine, hence the title of the project "Carbon Alloys".Coined in 1992, the phrase "Carbon Alloys" can be applied to those materials mainly composed of carbon materials in multi-component systems. The carbon atoms of each component have a physical and/or chemical interactive relationship with other atoms or compounds. The carbon atoms of the components may have different hybrid bonding orbitals to create quite different carbon components.Eiichi Yasuda and his team consider the definition of Carbon Alloys, present the results of the Carbon Alloys projects, describe typical Carbon Alloys and their uses, discuss recent techniques for their characterization, and finally, illustrate potential applications and future developments for Carbon Alloy science. The book contains over thirty chapters on these studies from as many researchers.The most modern of techniques, particularly in the area of spectroscopy, were used as diagnostic tools, and many of these are applicable to pure carbons also. Porosity in carbons received considerable attention.
Author: Peter G. Bruce
Publisher: Cambridge University Press
ISBN: 9780521599498
Category : Science
Languages : en
Pages : 364
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Book Description
This book describes, for the first time in a modern text, the fundamental principles on which solid state electrochemistry is based. In this sense it is in contrast to other books in the field which concentrate on a description of materials. Topics include solid (ceramic) electrolytes, glasses, polymer electrolytes, intercalation electrodes, interfaces and applications. The different nature of ionic conductivity in ceramic, glassy and polymer electrolytes is described as are the thermodynamics and kinetics of intercalation reactions. The interface between solid electrolytes and electrodes is discussed and contrasted with the more conventional liquid state electrochemistry. The text provides an essential foundation of understanding for postgraduates or others entering the field for the first time and will also be of value in advanced undergraduate courses.
Author: Deborah D L Chung
Publisher: World Scientific
ISBN: 9813221925
Category : Technology & Engineering
Languages : en
Pages : 382
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Book Description
'The field of carbon materials is huge and often difficult to comprehend, but this book is easy to read and methodically covers the subject, including presenting materials properties and performance data with clear illustrations and graphs. References include relevant older and up-to-date sources of information. The book is tutorial style in nature and is an excellent resource for senior undergraduates, graduate students, researchers, and anyone who wants to learn more about carbon and incorporate carbon materials into new applications.'MRS BulletinElemental carbon materials take numerous forms including graphite, carbon fiber, carbon nanotube, graphene, carbon black, activated carbon, fullerene and diamond. These forms differ greatly in the structure, properties, fabrication method, and applications. The applications of these carbon forms include electronic, electromagnetic, electrochemical, environmental and biomedical applications. Carbon materials are a subject of intense research, with strong relevance to both science and technology.This book provides a tutorial-style and up-to-date coverage of the carbon forms. In addition to an introductory chapter on carbon materials, the book includes chapters on graphite, graphene, carbon black, activated carbon, carbon fibers, and carbon nanofibers/nanotubes. For example, the chapter on graphite covers various materials in the graphite family, including polycrystalline graphite, pyrolytic graphite, turbostratic carbon, intercalated graphite, graphite oxide, exfoliated graphite and flexible graphite, in addition to their electronic and mechanical properties.This book is suitable for use as a textbook for undergraduate and graduate students in science and engineering, and as a reference book for professionals. It is dedicated to the memory of the author's PhD thesis advisor, Professor M S Dresselhaus (1930-2017) of Massachusetts Institute of Technology.
