Glass Transition, Dynamics and Heterogeneity of Polymer Thin Films

Glass Transition, Dynamics and Heterogeneity of Polymer Thin Films PDF Author: Toshiji Kanaya
Publisher: Springer
ISBN: 9783642343407
Category : Technology & Engineering
Languages : en
Pages : 144

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Book Description
Mobility Gradient of Polystyrene in Films Supported on Solid Substrates, by Yoshihisa Fujii, Hiroshi Morita, Atsushi Takahara and Keiji Tanaka Probing Properties of Polymers in Thin Films Via Dewetting, by Günter Reiter Heterogeneous and Aging Dynamics in Single and Stacked Thin Polymer Films, by Koji Fukao, Takehide Terasawa, Kenji Nakamura, Daisuke Tahara Heterogeneous Dynamics of Polymer Thin Films as Studied by Neutron Scattering, by Rintaro Inoue and Toshiji Kanaya

Glass Transition, Dynamics and Heterogeneity of Polymer Thin Films

Glass Transition, Dynamics and Heterogeneity of Polymer Thin Films PDF Author: Toshiji Kanaya
Publisher: Springer
ISBN: 9783642343407
Category : Technology & Engineering
Languages : en
Pages : 144

Get Book

Book Description
Mobility Gradient of Polystyrene in Films Supported on Solid Substrates, by Yoshihisa Fujii, Hiroshi Morita, Atsushi Takahara and Keiji Tanaka Probing Properties of Polymers in Thin Films Via Dewetting, by Günter Reiter Heterogeneous and Aging Dynamics in Single and Stacked Thin Polymer Films, by Koji Fukao, Takehide Terasawa, Kenji Nakamura, Daisuke Tahara Heterogeneous Dynamics of Polymer Thin Films as Studied by Neutron Scattering, by Rintaro Inoue and Toshiji Kanaya

Glass Transition, Dynamics and Heterogeneity of Polymer Thin Films

Glass Transition, Dynamics and Heterogeneity of Polymer Thin Films PDF Author: Toshiji Kanaya
Publisher: Springer
ISBN: 3642343392
Category : Technology & Engineering
Languages : en
Pages : 150

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Book Description
Mobility Gradient of Polystyrene in Films Supported on Solid Substrates, by Yoshihisa Fujii, Hiroshi Morita, Atsushi Takahara and Keiji Tanaka Probing Properties of Polymers in Thin Films Via Dewetting, by Günter Reiter Heterogeneous and Aging Dynamics in Single and Stacked Thin Polymer Films, by Koji Fukao, Takehide Terasawa, Kenji Nakamura, Daisuke Tahara Heterogeneous Dynamics of Polymer Thin Films as Studied by Neutron Scattering, by Rintaro Inoue and Toshiji Kanaya

Dynamics in Geometrical Confinement

Dynamics in Geometrical Confinement PDF Author: Friedrich Kremer
Publisher: Springer
ISBN: 3319061003
Category : Technology & Engineering
Languages : en
Pages : 365

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Book Description
This book describes the dynamics of low molecular weight and polymeric molecules when they are constrained under conditions of geometrical confinement. It covers geometrical confinement in different dimensionalities: (i) in nanometer thin layers or self supporting films (1-dimensional confinement) (ii) in pores or tubes with nanometric diameters (2-dimensional confinement) (iii) as micelles embedded in matrices (3-dimensional) or as nanodroplets. The dynamics under such conditions have been a much discussed and central topic in the focus of intense worldwide research activities within the last two decades. The present book discusses how the resulting molecular mobility is influenced by the subtle counterbalance between surface effects (typically slowing down molecular dynamics through attractive guest/host interactions) and confinement effects (typically increasing the mobility). It also explains how these influences can be modified and tuned, e.g. through appropriate surface coatings, film thicknesses or pore diameters. "Dynamics in Confinement" sums up the present state-of-the-art and introduces to the analytical methods of choice for the study of dynamics in nanometer-scale confinement.

Anionic Polymerization

Anionic Polymerization PDF Author: Nikos Hadjichristidis
Publisher: Springer
ISBN: 4431541861
Category : Technology & Engineering
Languages : en
Pages : 1082

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Book Description
This book presents these important facts: a) The mechanism of anionic polymerization, a more than 50-year challenge in polymer chemistry, has now become better understood; b) Precise synthesis of many polymers with novel architectures (triblock, multi-block, graft, exact graft, comb, cyclic, many armed stars with multi-components, dendrimer-like hyper-branched, and their structural mixed (co)polymers, etc.) have been advanced significantly; c) Based on such polymers, new morphological and self-organizing nano-objects and supra molecular assemblies have been created and widely studied and are considered nanodevices in the fields of nano science and technology; d) New high-tech and industrial applications for polymeric materials synthesized by anionic polymerization have been proposed. These remarkable developments have taken place in the last 15 years. Anionic polymerization continues to be the only truly living polymerization system (100 % termination free under appropriate conditions) and consequently the only one with unique capabilities in the synthesis of well-defined (i.e., precisely controlled molecular weight, nearly mono-disperse molecular weight distribution, structural and compositional homogeneity) complex macromolecular architectures. This book, with contributions from the world’s leading specialists, will be useful for all researchers, including students, working in universities, in research organizations, and in industry.

Recent Advances in Broadband Dielectric Spectroscopy

Recent Advances in Broadband Dielectric Spectroscopy PDF Author: Yuri P. Kalmykov
Publisher: Springer
ISBN: 9400750129
Category : Science
Languages : en
Pages : 206

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Book Description
This volume considers experimental and theoretical dielectric studies of the structure and dynamics of complex systems. Complex systems constitute an almost universal class of materials including associated liquids, polymers, biomolecules, colloids, porous materials, doped ferroelectric crystals, nanomaterials, etc. These systems are characterized by a new "mesoscopic" length scale, intermediate between molecular and macroscopic. The mesoscopic structures of complex systems typically arise from fluctuations or competing interactions and exhibit a rich variety of static and dynamic behaviour. This growing field is interdisciplinary; it complements solid state and statistical physics, and overlaps considerably with chemistry, chemical engineering, materials science, and biology. A common theme in complex systems is that while such materials are disordered on the molecular scale and homogeneous on the macroscopic scale, they usually possess a certain degree of order on an intermediate, or mesoscopic, scale due to the delicate balance of interaction and thermal effects. In the present Volume it is shown how the dielectric spectroscopy studies of complex systems can be applied to determine both their structures and dynamics.

Polymer Glasses

Polymer Glasses PDF Author: Connie B. Roth
Publisher: CRC Press
ISBN: 1315305135
Category : Science
Languages : en
Pages : 752

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Book Description
"the present book will be of great value for both newcomers to the field and mature active researchers by serving as a coherent and timely introduction to some of the modern approaches, ideas, results, emerging understanding, and many open questions in this fascinating field of polymer glasses, supercooled liquids, and thin films" –Kenneth S. Schweizer, Morris Professor of Materials Science & Engineering, University of Illinois at Urbana-Champaign (from the Foreword) This book provides a timely and comprehensive overview of molecular level insights into polymer glasses in confined geometries and under deformation. Polymer glasses have become ubiquitous to our daily life, from the polycarbonate eyeglass lenses on the end of our nose to large acrylic glass panes holding water in aquarium tanks, with advantages over glass in that they are lightweight and easy to manufacture, while remaining transparent and rigid. The contents include an introduction to the field, as well as state of the art investigations. Chapters delve into studies of commonalities across different types of glass formers (polymers, small molecules, colloids, and granular materials), which have enabled microscopic and molecular level frameworks to be developed. The authors show how glass formers are modeled across different systems, thereby leading to treatments for polymer glasses with first-principle based approaches and molecular level detail. Readers across disciplines will benefit from this topical overview summarizing the key areas of polymer glasses, alongside an introduction to the main principles and approaches.

Polymer Thin Films

Polymer Thin Films PDF Author: Ophelia Kwan Chui Tsui
Publisher: World Scientific
ISBN: 9812818820
Category : Science
Languages : en
Pages : 312

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Book Description
Ch. 1. Block copolymer thin films / J.-Y. Wang, S. Park and T. P. Russell -- ch. 2. Equilibration of block copolymer films on chemically patterned surfaces / G. S. W. Craig, H. Kang and P. F. Nealey -- ch. 3. Structure formation and evolution in confined cylinder-forming block copolymers / G. J. A. Sevink and J. G. E. M. Fraaije -- ch. 4. Block copolymer lithography for magnetic device fabrication / J. Y. Cheng and C. A. Ross -- ch. 5. Hierarchical structuring of polymer nanoparticles by self-organization / M. Shimomura ... [et al.] -- ch. 6. Wrinkling polymers for surface structure control and functionality / E. P. Chan and A. J. Crosby -- ch. 7. Crystallization in polymer thin films: morphology and growth / R. M. Van Horn and S. Z. D. Cheng -- ch. 8. Friction at soft polymer surface / M. K. Chaudhury, K. Vorvolakos and D. Malotky -- ch. 9. Relationship between molecular architecture, large-strain mechanical response and adhesive performance of model, block copolymer-based pressure sensitive adhesives / C. Creton and K. R. Shull -- ch. 10. Stability and dewetting of thin liquid films / K. Jacobs, R. Seemann and S. Herminghaus -- ch. 11. Anomalous dynamics of polymer Films / O. K. C. Tsui.

Polymer Glasses

Polymer Glasses PDF Author: Connie B. Roth
Publisher: CRC Press
ISBN: 1315305143
Category : Science
Languages : en
Pages : 573

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Book Description
"the present book will be of great value for both newcomers to the field and mature active researchers by serving as a coherent and timely introduction to some of the modern approaches, ideas, results, emerging understanding, and many open questions in this fascinating field of polymer glasses, supercooled liquids, and thin films" –Kenneth S. Schweizer, Morris Professor of Materials Science & Engineering, University of Illinois at Urbana-Champaign (from the Foreword) This book provides a timely and comprehensive overview of molecular level insights into polymer glasses in confined geometries and under deformation. Polymer glasses have become ubiquitous to our daily life, from the polycarbonate eyeglass lenses on the end of our nose to large acrylic glass panes holding water in aquarium tanks, with advantages over glass in that they are lightweight and easy to manufacture, while remaining transparent and rigid. The contents include an introduction to the field, as well as state of the art investigations. Chapters delve into studies of commonalities across different types of glass formers (polymers, small molecules, colloids, and granular materials), which have enabled microscopic and molecular level frameworks to be developed. The authors show how glass formers are modeled across different systems, thereby leading to treatments for polymer glasses with first-principle based approaches and molecular level detail. Readers across disciplines will benefit from this topical overview summarizing the key areas of polymer glasses, alongside an introduction to the main principles and approaches.

The Glass Transition

The Glass Transition PDF Author: E. Donth
Publisher: Springer Science & Business Media
ISBN: 3662043653
Category : Science
Languages : en
Pages : 433

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Book Description
Describes and interrelates the following processes: cooperative alpha processes in a cold liquid, structural relaxation in the glass near Tg, the Johari-Goldstein beta process, the Williams-Götze process in a warm liquid, fast nonactivated cage rattling and boson peak, and ultraslow Fischer modes.

Polymer Structure Characterization

Polymer Structure Characterization PDF Author: Richard Arthur Pethrick
Publisher: Royal Society of Chemistry
ISBN: 184973433X
Category : Education
Languages : en
Pages : 493

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Book Description
A textbook aimed at polymer and material scientists, but also of interest to chemists and physicists studying organic materials.