Free Radical Chain Reactions in Organic Synthesis PDF Download
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Author: William B. Motherwell
Publisher: Elsevier
ISBN: 0080924956
Category : Science
Languages : en
Pages : 289
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Book Description
Written for both the experienced practitioner and the newcomer, this book provides essential guidance to the practical aspects of free radical chain reactions. The book presents tried and tested synthetic schemes as well as a selection of recently developed methods describing rationally designed, highly efficient syntheses giving high yield interconversions of functional groups and carbon*b1carbon bond formation under mild, neutral conditions. Written by two experienced practitioners in the field, this volume explodes the myth that free radicals are highly reactive, non-selective intermediates. Contains an extensive introduction discussing principles, advantages, and disadvantages of radical chain reactions Demonstrates functional group interconversions by radical chain reactions Lists carbon*b1carbon bond formations Presents inter- and intramolecular radical chain reactions Includes many examples and experimental details selected by experienced practitioners in this field
Author: William B. Motherwell
Publisher: Elsevier
ISBN: 0080924956
Category : Science
Languages : en
Pages : 289
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Book Description
Written for both the experienced practitioner and the newcomer, this book provides essential guidance to the practical aspects of free radical chain reactions. The book presents tried and tested synthetic schemes as well as a selection of recently developed methods describing rationally designed, highly efficient syntheses giving high yield interconversions of functional groups and carbon*b1carbon bond formation under mild, neutral conditions. Written by two experienced practitioners in the field, this volume explodes the myth that free radicals are highly reactive, non-selective intermediates. Contains an extensive introduction discussing principles, advantages, and disadvantages of radical chain reactions Demonstrates functional group interconversions by radical chain reactions Lists carbon*b1carbon bond formations Presents inter- and intramolecular radical chain reactions Includes many examples and experimental details selected by experienced practitioners in this field
Author: Hideo Togo
Publisher: Elsevier
ISBN: 9780080524252
Category : Science
Languages : en
Pages : 270
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Book Description
Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists. Introduces and reviews the use of radicals to perform synthetic transformations Practical details are provided for the most important methods Numerous references to the original literature
Author: Samir Z. Zard
Publisher: Oxford University Press, USA
ISBN: 9780198502401
Category : Science
Languages : en
Pages : 276
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Book Description
Introduction and some general concepts. -- General principles: chain reactions based on stannane chemistry. -- Further chain reactions of stannanes. -- Organo-silicon, -germanium, and -mercury hydrides. -- The Barton decarboxylation and related reactions. -- Atom and group transfer reactions. -- The persistent radical effect: non-chain processes. -- Redox processes. -- Some concluding remarks.
Author: D. I. Davies
Publisher: Springer Science & Business Media
ISBN: 3642669220
Category : Science
Languages : en
Pages : 181
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Book Description
Author: Bernd Giese
Publisher: C R C Press Reprints
ISBN:
Category : Science
Languages : en
Pages : 318
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Book Description
Author: V. Tamara Perchyonok
Publisher: Royal Society of Chemistry
ISBN: 1849730008
Category : Science
Languages : en
Pages : 142
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Book Description
Radical Reactions in Aqueous Media provides a step-wise introduction, taking students from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes."--Jacket.
Author: V V Azatyan
Publisher: CRC Press
ISBN: 9789069940021
Category : Science
Languages : en
Pages : 360
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Book Description
This text explores nonbranching reactions, including in-depth information on the inhibitors of free radical polymerisation and the mechanisms of antioxidants on oxidationprocesses. Auto-initiated chain reactions are also explored, with detailed descriptions on the kinetics, mechanisms, and inhibition of the autoxidation of organic compounds, A special chapter deals with the synergism of antioxidant actions. The theory of chain-branching reactions is investigated, and a large amount of new experimental data concerning the use of chemical additives to regulate combustion processes is also presented, including the mode of chain thermal explosion.
Author: Chao-Jun Li
Publisher: John Wiley & Sons
ISBN: 0470131438
Category : Science
Languages : en
Pages : 435
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Book Description
An extensive update of the classic reference on organic reactions in water Published almost a decade ago, the first edition has served as the guide for research in this burgeoning field. Due to the cost, safety, efficiency, and environmental friendliness of water as a solvent, there are many new applications in industry and academic laboratories. More than forty percent of this extensively updated second edition covers new reactions. For ease of reference, it is organized by functional groups. A core reference, Comprehensive Organic Reactions in Aqueous Media, Second Edition: * Provides the most comprehensive coverage of aqueous organicreactions available * Covers the basic principles and theory and progresses to applications * Includes alkanes, alkenes, aromatics, electrophilic substitutions, carbonyls, alpha, beta-unsaturated carbonyls, carbon-nitrogen bonds, organic halides, pericyclic reactions, photochemical reactions, click chemistry, and multi-step syntheses? * Provides examples of applications in industry This is the premier reference for chemists and chemical engineers in industry or research, as well as for students in advanced-level courses.
Author: Jay K. Kochi
Publisher:
ISBN: 9780471497011
Category : Free radicals (Chemistry)
Languages : en
Pages :
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Book Description
Author: Robert B. Grossman
Publisher: Springer Science & Business Media
ISBN: 0387954686
Category : Science
Languages : en
Pages : 371
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Book Description
Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error alerts" are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.
