Experimental and Simulation Studies of Sequestration of Supercritical Carbon Dioxide in Depleted Gas Reservoirs

Experimental and Simulation Studies of Sequestration of Supercritical Carbon Dioxide in Depleted Gas Reservoirs PDF Author: Jeong Gyu Seo
Publisher:
ISBN:
Category :
Languages : en
Pages : 238

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Experimental and Simulation Studies of Sequestration of Supercritical Carbon Dioxide in Depleted Gas Reservoirs

Experimental and Simulation Studies of Sequestration of Supercritical Carbon Dioxide in Depleted Gas Reservoirs PDF Author: Jeong Gyu Seo
Publisher:
ISBN:
Category :
Languages : en
Pages : 238

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Experimental and Analytic Studies to Model Kinetics and Mass Transport of Carbon Dioxide Sequstration in Depleted Carbonate Reservoirs

Experimental and Analytic Studies to Model Kinetics and Mass Transport of Carbon Dioxide Sequstration in Depleted Carbonate Reservoirs PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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There is undeniable evidence that concentration of carbon dioxide in the atmosphere is rising at an increasingly rapid rate primarily as the result of burning fossil fuels. Although the debate continues, most of the scientific community believes that higher levels of atmospheric CO2 will lead to a significant warming of the Earth's climate and that there is already evidence that this is occurring. There are two ways to ameliorate this problem. One is to significantly reduce production of CO2, which is primarily a political-economic problem, and the other is to remove CO2 from emissions and/or the atmosphere and find some way to sequester it. Several possible ways to sequester CO2 are under investigation or have been suggested. These include removal by chemical reaction, deep seabed disposal, and pumping supercritical CO2 into various subsurface environments. Sequestration of carbon dioxide in depleted gas reservoirs appears to be a viable option, with a possible economic spin-off from the recovery of significant gas reserves. At the elevated temperatures and pressures encountered in reservoirs, carbon dioxide behaves as a supercritical fluid. Under these conditions, little was known regarding the, diffusion of carbon dioxide in natural gas, and displacement of natural gas by carbon dioxide. A major objective of this research was to obtain the necessary data to model these processes. Also, the added CO2 will react with reservoir waters that are often chemically complex high ionic strength brines making them more acidic. This can result in the dissolution of calcium carbonate (calcite) that is a common host rock or sandstone cement in reservoirs and lead to potentially serious problems for CO2 injection and the integrity of the reservoir. It was consequently a second major objective of this project to determine calcite solubility and dissolution kinetics in solutions representative of subsurface brines and produce a general dissolution rate equation. Both objectives were accomplished. Reservoir simulations indicated a large amount of CO2 would be sequestered, with the amount depending on reservoir water saturation. Simulation results also indicate a significant amount of natural gas could be produced. For an 80-acre pattern, natural gas production was calculated to be 3.2 BSCF or 63% of remaining gas-in-place for 30% reservoir water saturation. Gas revenues would help defray the cost of CO2 sequestration. Therefore, CO2 sequestration in depleted gas reservoirs appears to be a win-win technology. Considerable effort went into testing and refining the ability to predict calcite solubility in brines using a Pitzer-equation based computer model, with particular difficulties being encountered in solutions with high dissolved calcium concentrations. After that was accomplished, calcite dissolution kinetics were determined a wide range of brine compositions both including and not including potential inhibitors from 25 to 83 oC and a CO2 partial pressure from 0.1 to 1 atm. The reaction was found to be first order for undersaturations of 0.2 to ~1 and was surface controlled. The rate constant was fit to a multiple regression model, thus making it possible to predict calcite dissolution rates over a wide range of solution compositions, partial pressures of CO2 and temperature. Results indicate that equilibrium is likely to be reached relatively quickly in front of an advancing supercritical CO2 fluid.

Carbon Dioxide Sequestration and Related Technologies

Carbon Dioxide Sequestration and Related Technologies PDF Author: Ying Wu
Publisher: John Wiley & Sons
ISBN: 0470938765
Category : Technology & Engineering
Languages : en
Pages : 510

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Book Description
Carbon dioxide sequestration is a technology that is being explored to curb the anthropogenic emission of CO2 into the atmosphere. Carbon dioxide has been implicated in the global climate change and reducing them is a potential solution. The injection of carbon dioxide for enhanced oil recovery (EOR) has the duel benefit of sequestering the CO2 and extending the life of some older fields. Sequestering CO2 and EOR have many shared elements that make them comparable. This volume presents some of the latest information on these processes covering physical properties, operations, design, reservoir engineering, and geochemistry for AGI and the related technologies.

Carbon Dioxide Sequestration in Geological Media

Carbon Dioxide Sequestration in Geological Media PDF Author: Matthias Grobe
Publisher: AAPG
ISBN: 0891810668
Category : Science
Languages : en
Pages : 702

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Book Description
Over the past 20 years, the concept of storing or permanently storing carbon dioxide in geological media has gained increasing attention as part of the important technology option of carbon capture and storage within a portfolio of options aimed at reducing anthropogenic emissions of greenhouse gases to the earths atmosphere. This book is structured into eight parts, and, among other topics, provides an overview of the current status and challenges of the science, regional assessment studies of carbon dioxide geological sequestration potential, and a discussion of the economics and regulatory aspects of carbon dioxide sequestration.

Geologic Carbon Sequestration

Geologic Carbon Sequestration PDF Author: V. Vishal
Publisher: Springer
ISBN: 3319270192
Category : Science
Languages : en
Pages : 336

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Book Description
This exclusive compilation written by eminent experts from more than ten countries, outlines the processes and methods for geologic sequestration in different sinks. It discusses and highlights the details of individual storage types, including recent advances in the science and technology of carbon storage. The topic is of immense interest to geoscientists, reservoir engineers, environmentalists and researchers from the scientific and industrial communities working on the methodologies for carbon dioxide storage. Increasing concentrations of anthropogenic carbon dioxide in the atmosphere are often held responsible for the rising temperature of the globe. Geologic sequestration prevents atmospheric release of the waste greenhouse gases by storing them underground for geologically significant periods of time. The book addresses the need for an understanding of carbon reservoir characteristics and behavior. Other book volumes on carbon capture, utilization and storage (CCUS) attempt to cover the entire process of CCUS, but the topic of geologic sequestration is not discussed in detail. This book focuses on the recent trends and up-to-date information on different storage rock types, ranging from deep saline aquifers to coal to basaltic formations.

The Carbon Dioxide Dilemma

The Carbon Dioxide Dilemma PDF Author: National Research Council
Publisher: National Academies Press
ISBN: 0309089212
Category : Science
Languages : en
Pages : 150

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Book Description
Growing concerns about climate change partly as a result of anthropogenic carbon dioxide emissions has prompted the research community to assess technologies and policies for sequestration. This report contains presentations of a symposium held in April of 2002. The sequestration options range form ocean disposal, terrestrial disposal in geologic formations, biomass based approaches and carbon trading schemes. The report also presents current efforts at enhanced oil recovery using carbon dioxide and demonstrating its utility. The volume is intended only as introduction to the subject and not the final word.

Carbon Capture, Utilization and Sequestration

Carbon Capture, Utilization and Sequestration PDF Author: Ramesh K. Agarwal
Publisher: BoD – Books on Demand
ISBN: 1789237645
Category : Technology & Engineering
Languages : en
Pages : 198

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Book Description
This book is divided in two sections. Several chapters in the first section provide a state-of-the-art review of various carbon sinks for CO2 sequestration such as soil and oceans. Other chapters discuss the carbon sequestration achieved by storage in kerogen nanopores, CO2 miscible flooding and generation of energy efficient solvents for postcombustion CO2 capture. The chapters in the second section focus on monitoring and tracking of CO2 migration in various types of storage sites, as well as important physical parameters relevant to sequestration. Both researchers and students should find the material useful in their work.

Carbon Dioxide Capture and Acid Gas Injection

Carbon Dioxide Capture and Acid Gas Injection PDF Author: Ying Wu
Publisher: John Wiley & Sons
ISBN: 1118938682
Category : Science
Languages : en
Pages : 266

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Book Description
This is the sixth volume in a series of books on natural gas engineering, focusing carbon dioxide (CO2) capture and acid gas injection. This volume includes information for both upstream and downstream operations, including chapters on well modeling, carbon capture, chemical and thermodynamic models, and much more. Written by some of the most well-known and respected chemical and process engineers working with natural gas today, the chapters in this important volume represent the most cutting-edge and state-of-the-art processes and operations being used in the field. Not available anywhere else, this volume is a must-have for any chemical engineer, chemist, or process engineer working with natural gas. There are updates of new technologies in other related areas of natural gas, in addition to the CO2 capture and acid gas injection, including testing, reservoir simulations, and natural gas hydrate formations. Advances in Natural Gas Engineering is an ongoing series of books meant to form the basis for the working library of any engineer working in natural gas today. Every volume is a must-have for any engineer or library.

Geological Sequestration of Carbon Dioxide

Geological Sequestration of Carbon Dioxide PDF Author: Luigi Marini
Publisher: Elsevier
ISBN: 0080466885
Category : Science
Languages : en
Pages : 471

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Book Description
The contents of this monograph are two-scope. First, it intends to provide a synthetic but complete account of the thermodynamic and kinetic foundations on which the reaction path modeling of geological CO2 sequestration is based. In particular, a great effort is devoted to review the thermodynamic properties of CO2 and of the CO2-H2O system and the interactions in the aqueous solution, the thermodynamic stability of solid product phases (by means of several stability plots and activity plots), the volumes of carbonation reactions, and especially the kinetics of dissolution/precipitation reactions of silicates, oxides, hydroxides, and carbonates. Second, it intends to show the reader how reaction path modeling of geological CO2 sequestration is carried out. To this purpose the well-known high-quality EQ3/6 software package is used. Setting up of computer simulations and obtained results are described in detail and used EQ3/6 input files are given to guide the reader step-by-step from the beginning to the end of these exercises. Finally, some examples of reaction-path- and reaction-transport-modeling taken from the available literature are presented. The results of these simulations are of fundamental importance to evaluate the amounts of potentially sequestered CO2, and their evolution with time, as well as the time changes of all the other relevant geochemical parameters (e.g., amounts of solid reactants and products, composition of the aqueous phase, pH, redox potential, effects on aquifer porosity). In other words, in this way we are able to predict what occurs when CO2 is injected into a deep aquifer. * Provides applications for investigating and predicting geological carbon dioxide sequestration * Reviews the geochemical literature in the field * Discusses the importance of geochemists in the multidisciplinary study of geological carbon dioxide sequestration

Training Graduate and Undergraduate Students in Simulation and Risk Assessment for Carbon Sequestration

Training Graduate and Undergraduate Students in Simulation and Risk Assessment for Carbon Sequestration PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
Capturing carbon dioxide (CO2) and injecting it into deep underground formations for storage (carbon capture and underground storage, or CCUS) is one way of reducing anthropogenic CO2 emissions. Gas or aqueous-phase leakage may occur due to transport via faults and fractures, through faulty well bores, or through leaky confining materials. Contaminants of concern include aqueous salts and dissolved solids, gaseous or aqueous-phase organic contaminants, and acidic gas or aqueous-phase fluids that can liberate metals from aquifer minerals. Understanding the mechanisms and parameters that can contribute to leakage of the CO2 and the ultimate impact on shallow water aquifers that overlie injection formations is an important step in evaluating the efficacy and risks associated with long-term CO2 storage. Three students were supported on the grant Training Graduate and Undergraduate Students in Simulation and Risk Assessment for Carbon Sequestration. These three students each examined a different aspect of simulation and risk assessment related to carbon dioxide sequestration and the potential impacts of CO2 leakage. Two performed numerical simulation studies, one to assess leakage rates as a function of fault and deep reservoir parameters and one to develop a method for quantitative risk assessment in the event of a CO2 leak and subsequent changes in groundwater chemistry. A third student performed an experimental evaluation of the potential for metal release from sandstone aquifers under simulated leakage conditions. This study has resulted in two student first-authored published papers {Siirila, 2012 #560}{Kirsch, 2014 #770} and one currently in preparation {Menke, In prep. #809}.