Author: Mahamud Subir
Publisher: American Chemical Society
ISBN: 0841299277
Category : Science
Languages : en
Pages : 339
Book Description
Clarifying chemical processes in the environment is tantamount to creating a better and a safer planet. The chemistry that takes place within the natural world occurs not only in the bulk gaseous, liquid, and solid phases, but also in the region where two phases meet. This molecularly thin region between phases, also known as an interface, plays a significant role in various chemical processes because interfaces are ubiquitous in nature. Despite the significance of interfacial processes in environmental chemistry, investigating environmental interfaces experimentally has always been a challenge. Recent advances in nonlinear spectroscopy (NLS) have demonstrated that techniques such as sum frequency generation (SFG) and second harmonic generation (SHG) are unique in their ability to probe buried chemical interfaces. The theoretical and practical aspect of these techniques in probing environmental interfaces is the primary focus of this e-book. This e-book is geared toward curious and inquisitive minds eager to learn how molecules behave at the thin layers of chemical interfaces. A beautiful world, rich in unique insights into the interfacial environmental processes, awaits.
Environmental Interfacial Spectroscopy
Author: Mahamud Subir
Publisher: American Chemical Society
ISBN: 0841299277
Category : Science
Languages : en
Pages : 339
Book Description
Clarifying chemical processes in the environment is tantamount to creating a better and a safer planet. The chemistry that takes place within the natural world occurs not only in the bulk gaseous, liquid, and solid phases, but also in the region where two phases meet. This molecularly thin region between phases, also known as an interface, plays a significant role in various chemical processes because interfaces are ubiquitous in nature. Despite the significance of interfacial processes in environmental chemistry, investigating environmental interfaces experimentally has always been a challenge. Recent advances in nonlinear spectroscopy (NLS) have demonstrated that techniques such as sum frequency generation (SFG) and second harmonic generation (SHG) are unique in their ability to probe buried chemical interfaces. The theoretical and practical aspect of these techniques in probing environmental interfaces is the primary focus of this e-book. This e-book is geared toward curious and inquisitive minds eager to learn how molecules behave at the thin layers of chemical interfaces. A beautiful world, rich in unique insights into the interfacial environmental processes, awaits.
Publisher: American Chemical Society
ISBN: 0841299277
Category : Science
Languages : en
Pages : 339
Book Description
Clarifying chemical processes in the environment is tantamount to creating a better and a safer planet. The chemistry that takes place within the natural world occurs not only in the bulk gaseous, liquid, and solid phases, but also in the region where two phases meet. This molecularly thin region between phases, also known as an interface, plays a significant role in various chemical processes because interfaces are ubiquitous in nature. Despite the significance of interfacial processes in environmental chemistry, investigating environmental interfaces experimentally has always been a challenge. Recent advances in nonlinear spectroscopy (NLS) have demonstrated that techniques such as sum frequency generation (SFG) and second harmonic generation (SHG) are unique in their ability to probe buried chemical interfaces. The theoretical and practical aspect of these techniques in probing environmental interfaces is the primary focus of this e-book. This e-book is geared toward curious and inquisitive minds eager to learn how molecules behave at the thin layers of chemical interfaces. A beautiful world, rich in unique insights into the interfacial environmental processes, awaits.
Interfacial Water Organization and Ion Distributions Investigated with Vibrational Sum Frequency Spectroscopy
Author: Wei Hua
Publisher:
ISBN:
Category :
Languages : en
Pages : 219
Book Description
Abstract: Here, interface-specific nonlinear optical spectroscopies, conventional vibrational sum frequency generation (VSFG) and heterodyne-detected vibrational sum frequency generation (HD-VSFG), are employed to probe interfacial water molecules at the molecular level. HD-VSFG spectroscopy allows for direct interrogation of the average orientation of the transition dipole moment of interfacial water molecules that is intrinsically contained in the sign of the second-order nonlinear susceptibility, X(2). The water organization and ion distributions at air/aqueous interfaces of inorganic salt solutions are inferred from Im X(2) spectra obtained by HD-VSFG spectroscopy.
Publisher:
ISBN:
Category :
Languages : en
Pages : 219
Book Description
Abstract: Here, interface-specific nonlinear optical spectroscopies, conventional vibrational sum frequency generation (VSFG) and heterodyne-detected vibrational sum frequency generation (HD-VSFG), are employed to probe interfacial water molecules at the molecular level. HD-VSFG spectroscopy allows for direct interrogation of the average orientation of the transition dipole moment of interfacial water molecules that is intrinsically contained in the sign of the second-order nonlinear susceptibility, X(2). The water organization and ion distributions at air/aqueous interfaces of inorganic salt solutions are inferred from Im X(2) spectra obtained by HD-VSFG spectroscopy.
Interfacial Electrochemistry
Author: Andrzej Wieckowski
Publisher: Routledge
ISBN: 1351437577
Category : Science
Languages : en
Pages : 992
Book Description
This text probes topics and reviews progress in interfacial electrochemistry. It supplies chapter abstracts to give readers a concise overview of individual subjects and there are more than 1500 drawings, photographs, micrographs, tables and equations. The 118 contributors are international scholars who present theory, experimentation and applications.
Publisher: Routledge
ISBN: 1351437577
Category : Science
Languages : en
Pages : 992
Book Description
This text probes topics and reviews progress in interfacial electrochemistry. It supplies chapter abstracts to give readers a concise overview of individual subjects and there are more than 1500 drawings, photographs, micrographs, tables and equations. The 118 contributors are international scholars who present theory, experimentation and applications.
Molecular Environmental Soil Science at the Interfaces in the Earth’s Critical Zone
Author: Jian-Ming Xu
Publisher: Springer Science & Business Media
ISBN: 3642052975
Category : Science
Languages : en
Pages : 352
Book Description
"Molecular Environmental Soil Science at the Interfaces in the Earth's Critical Zone" presents contributions from the 1st International Symposium of Molecular Environmental Soil Science at the Interfaces in the Earth's Critical Zone held in Hangzhou, China. It introduces new ideas, findings, methods, and experience on above new and emerging subject areas. A broad range of topics are covered: the role of mineral colloids in carbon turnover and sequestration and the impact on climate change, biogeochemical interfacial reactions and dynamics of vital and toxic elements, ecotoxicology of anthropogenic organics, environmental nanoparticles and their impacts, and ecosystem health. The book will be a valuable reference for researchers in soil chemistry, environmental chemistry, mineralogy, microbiology, ecology, ecotoxicology, and physics. Jianming Xu is a Professor at the Institute of Soil and Water Resources and Environmental Science, Zhejiang University, China. Pan Ming Huang is a Professor at the Department of Soil Science, University of Saskatchewan, Canada.
Publisher: Springer Science & Business Media
ISBN: 3642052975
Category : Science
Languages : en
Pages : 352
Book Description
"Molecular Environmental Soil Science at the Interfaces in the Earth's Critical Zone" presents contributions from the 1st International Symposium of Molecular Environmental Soil Science at the Interfaces in the Earth's Critical Zone held in Hangzhou, China. It introduces new ideas, findings, methods, and experience on above new and emerging subject areas. A broad range of topics are covered: the role of mineral colloids in carbon turnover and sequestration and the impact on climate change, biogeochemical interfacial reactions and dynamics of vital and toxic elements, ecotoxicology of anthropogenic organics, environmental nanoparticles and their impacts, and ecosystem health. The book will be a valuable reference for researchers in soil chemistry, environmental chemistry, mineralogy, microbiology, ecology, ecotoxicology, and physics. Jianming Xu is a Professor at the Institute of Soil and Water Resources and Environmental Science, Zhejiang University, China. Pan Ming Huang is a Professor at the Department of Soil Science, University of Saskatchewan, Canada.
Development of Micro-spectroscopic Tools for Analysis of Environmental Interfaces
Author: Deborah Kim
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Book Description
Interfacial chemistry is important in many key molecular processes that are critical to water quality and treatment and can also drive the fate and transport of chemical contaminants in the environment. There are three key constituents of these environmentally-relevant water systems that are well-known to interact with geochemical interfaces: organic matter, oxyanions, and biological components. Mineral surfaces in particular are extremely diverse in composition and structure; they can include iron oxides, clay minerals, and carbonates. Therefore, these different geochemical interfaces present a complex array of surface compositions and structures whereby surface catalyzed reactions can occur and potential byproducts can lead to chemical contaminants in the environment. Traditional IR spectroscopy has offered valuable information in understanding how environmental adsorbates interact with mineral surfaces. The reason for this is due to the inherent molecular-level information that can be obtained due to changes in the vibrational mode frequencies for adsorbed versus solution phase species. To date, there still remains a bit of uncertainty with how individual components interact both as isolated components and when co-adsorbed with other species and the degree to which there is heterogeneity within these systems. In this dissertation, micro-spectroscopic probes such as Atomic Force Microscopy-Infrared (AFM-IR) spectroscopy and Optical Photothermal Infrared (O-PTIR) spectroscopy are compared to more traditional infrared methods in order to provide insights and a different perspective on these interactions as they probe both morphology and spectral signals with submicron spatial resolution. Overall, these novel studies have shown that micro-spectroscopic probes offer new insights into the chemistry occurring on solid mineral surfaces in the environment and provide examples of how these techniques can be used in future work.
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Book Description
Interfacial chemistry is important in many key molecular processes that are critical to water quality and treatment and can also drive the fate and transport of chemical contaminants in the environment. There are three key constituents of these environmentally-relevant water systems that are well-known to interact with geochemical interfaces: organic matter, oxyanions, and biological components. Mineral surfaces in particular are extremely diverse in composition and structure; they can include iron oxides, clay minerals, and carbonates. Therefore, these different geochemical interfaces present a complex array of surface compositions and structures whereby surface catalyzed reactions can occur and potential byproducts can lead to chemical contaminants in the environment. Traditional IR spectroscopy has offered valuable information in understanding how environmental adsorbates interact with mineral surfaces. The reason for this is due to the inherent molecular-level information that can be obtained due to changes in the vibrational mode frequencies for adsorbed versus solution phase species. To date, there still remains a bit of uncertainty with how individual components interact both as isolated components and when co-adsorbed with other species and the degree to which there is heterogeneity within these systems. In this dissertation, micro-spectroscopic probes such as Atomic Force Microscopy-Infrared (AFM-IR) spectroscopy and Optical Photothermal Infrared (O-PTIR) spectroscopy are compared to more traditional infrared methods in order to provide insights and a different perspective on these interactions as they probe both morphology and spectral signals with submicron spatial resolution. Overall, these novel studies have shown that micro-spectroscopic probes offer new insights into the chemistry occurring on solid mineral surfaces in the environment and provide examples of how these techniques can be used in future work.
Modern Techniques of Spectroscopy
Author: Dheeraj Kumar Singh
Publisher: Springer Nature
ISBN: 9813360844
Category : Technology & Engineering
Languages : en
Pages : 663
Book Description
The book highlights recent developments in the field of spectroscopy by providing the readers with an updated and high-level of overview. The focus of this book is on the introduction to concepts of modern spectroscopic techniques, recent technological innovations in this field, and current examples of applications to molecules and materials relevant for academia and industry. The book will be beneficial to researchers from various branches of science and technology, and is intended to point them to modern techniques, which might be useful for their specific problems. Spectroscopic techniques, that are discussed include, UV-Visible absorption spectroscopy, XPS, Raman spectroscopy, SERS, TERS, CARS, IR absorption spectroscopy, SFG, LIBS, Quantum cascade laser (QCL) spectroscopy, fluorescence spectroscopy, ellipsometry, cavity-enhanced absorption spectroscopy, such as cavity ring-down spectroscopy (CRDS) and evanescent wave-CRDS both in gas and condensed phases, time-resolved spectroscopy etc. Applications introduced in the different chapters demonstrates the usefulness of the spectroscopic techniques for the characterization of fundamental properties of molecules, e.g. in connection with environmental impact, bio-activity, or usefulness for pharmaceutical drugs, and materials important e.g. for nano-science, nuclear chemistry, or bio-applications. The book presents how spectroscopic techniques can help to better understand substances, which have also great impact on questions of social and economic relevance (environment, alternative energy, etc.).
Publisher: Springer Nature
ISBN: 9813360844
Category : Technology & Engineering
Languages : en
Pages : 663
Book Description
The book highlights recent developments in the field of spectroscopy by providing the readers with an updated and high-level of overview. The focus of this book is on the introduction to concepts of modern spectroscopic techniques, recent technological innovations in this field, and current examples of applications to molecules and materials relevant for academia and industry. The book will be beneficial to researchers from various branches of science and technology, and is intended to point them to modern techniques, which might be useful for their specific problems. Spectroscopic techniques, that are discussed include, UV-Visible absorption spectroscopy, XPS, Raman spectroscopy, SERS, TERS, CARS, IR absorption spectroscopy, SFG, LIBS, Quantum cascade laser (QCL) spectroscopy, fluorescence spectroscopy, ellipsometry, cavity-enhanced absorption spectroscopy, such as cavity ring-down spectroscopy (CRDS) and evanescent wave-CRDS both in gas and condensed phases, time-resolved spectroscopy etc. Applications introduced in the different chapters demonstrates the usefulness of the spectroscopic techniques for the characterization of fundamental properties of molecules, e.g. in connection with environmental impact, bio-activity, or usefulness for pharmaceutical drugs, and materials important e.g. for nano-science, nuclear chemistry, or bio-applications. The book presents how spectroscopic techniques can help to better understand substances, which have also great impact on questions of social and economic relevance (environment, alternative energy, etc.).
State-of-the-art Application of Surface and Interface Analysis Methods to Environmental Material Interactions
Author: Electrochemical Society. Corrosion Division
Publisher: The Electrochemical Society
ISBN: 9781566773119
Category : Corrosion and anti-corrosives
Languages : en
Pages : 332
Book Description
Publisher: The Electrochemical Society
ISBN: 9781566773119
Category : Corrosion and anti-corrosives
Languages : en
Pages : 332
Book Description
Encyclopedia of Surface and Colloid Science -
Author: Arthur T. Hubbard
Publisher: CRC Press
ISBN: 9780824707576
Category : Science
Languages : en
Pages : 1580
Book Description
This comprehensive reference collects fundamental theories and recent research from a wide range of fields including biology, biochemistry, physics, applied mathematics, and computer, materials, surface, and colloid science-providing key references, tools, and analytical techniques for practical applications in industrial, agricultural, and forensic processes, as well as in the production of natural and synthetic compounds such as foods, minerals, paints, proteins, pharmaceuticals, polymers, and soaps.
Publisher: CRC Press
ISBN: 9780824707576
Category : Science
Languages : en
Pages : 1580
Book Description
This comprehensive reference collects fundamental theories and recent research from a wide range of fields including biology, biochemistry, physics, applied mathematics, and computer, materials, surface, and colloid science-providing key references, tools, and analytical techniques for practical applications in industrial, agricultural, and forensic processes, as well as in the production of natural and synthetic compounds such as foods, minerals, paints, proteins, pharmaceuticals, polymers, and soaps.
Advanced Ceramic Coatings
Author: Ram Gupta
Publisher: Elsevier
ISBN: 0323996604
Category : Technology & Engineering
Languages : en
Pages : 524
Book Description
Handbook of Advanced Ceramic Coatings: Fundamentals, Manufacturing and Classification introduces ceramic coating materials, methods of fabrication, characterizations, the interaction between fillers, reinforcers, and environmental impact, and the functional classification of ceramic coatings. The book is one of four volumes that together provide a comprehensive resource in the field of Advanced Ceramic Coatings, also including titles covering energy, biomedical and emerging applications. These books will be extremely useful for academic and industrial researchers and practicing engineers who need to find reliable and up-to-date information about recent progresses and new developments in the field of advanced ceramic coatings. Smart ceramic coatings containing multifunctional components are now finding application in transportation and automotive industries, in electronics, and energy sectors, in aerospace and defense, and in industrial goods and healthcare. Their wide application and stability in harsh environments are only possible due to the stability of the inorganic components used. Ceramic coatings are typically silicon nitride, chromia, hafnia, alumina, alumina-magnesia, silica, silicon carbide, titania, and zirconia-based compositions. The increased demand for these materials and their application in energy, transportation, and the automotive industry, are considered, to be the main drivers. - Comprehensively covers the production, characterization and properties of advanced ceramic coatings - Features the latest manufacturing processes - Covers basic principles of surface chemistry, along with the fundamentals of ceramic materials and engineering - Features the latest progress and recent technological developments - Discusses basic science relevant to both the materials and preparation methods
Publisher: Elsevier
ISBN: 0323996604
Category : Technology & Engineering
Languages : en
Pages : 524
Book Description
Handbook of Advanced Ceramic Coatings: Fundamentals, Manufacturing and Classification introduces ceramic coating materials, methods of fabrication, characterizations, the interaction between fillers, reinforcers, and environmental impact, and the functional classification of ceramic coatings. The book is one of four volumes that together provide a comprehensive resource in the field of Advanced Ceramic Coatings, also including titles covering energy, biomedical and emerging applications. These books will be extremely useful for academic and industrial researchers and practicing engineers who need to find reliable and up-to-date information about recent progresses and new developments in the field of advanced ceramic coatings. Smart ceramic coatings containing multifunctional components are now finding application in transportation and automotive industries, in electronics, and energy sectors, in aerospace and defense, and in industrial goods and healthcare. Their wide application and stability in harsh environments are only possible due to the stability of the inorganic components used. Ceramic coatings are typically silicon nitride, chromia, hafnia, alumina, alumina-magnesia, silica, silicon carbide, titania, and zirconia-based compositions. The increased demand for these materials and their application in energy, transportation, and the automotive industry, are considered, to be the main drivers. - Comprehensively covers the production, characterization and properties of advanced ceramic coatings - Features the latest manufacturing processes - Covers basic principles of surface chemistry, along with the fundamentals of ceramic materials and engineering - Features the latest progress and recent technological developments - Discusses basic science relevant to both the materials and preparation methods
Fundamentals of Sum-Frequency Spectroscopy
Author: Y. R. Shen
Publisher: Cambridge University Press
ISBN: 131647304X
Category : Science
Languages : en
Pages : 570
Book Description
The first book on the topic, and written by the founder of the technique, this comprehensive resource provides a detailed overview of sum-frequency spectroscopy, its fundamental principles, and the wide range of applications for surfaces, interfaces, and bulk. Beginning with an overview of the historical context, and introductions to the basic theory of nonlinear optics and surface sum-frequency generation, topics covered include discussion of different experimental arrangements adopted by researchers, notes on proper data analysis, an up-to-date survey commenting on the wide range of successful applications of the tool, and a valuable insight into current unsolved problems and potential areas to be explored in the future. With the addition of chapter appendices that offer the opportunity for more in-depth theoretical discussion, this is an essential resource that integrates all aspects of the subject and is ideal for anyone using, or interested in using, sum-frequency spectroscopy.
Publisher: Cambridge University Press
ISBN: 131647304X
Category : Science
Languages : en
Pages : 570
Book Description
The first book on the topic, and written by the founder of the technique, this comprehensive resource provides a detailed overview of sum-frequency spectroscopy, its fundamental principles, and the wide range of applications for surfaces, interfaces, and bulk. Beginning with an overview of the historical context, and introductions to the basic theory of nonlinear optics and surface sum-frequency generation, topics covered include discussion of different experimental arrangements adopted by researchers, notes on proper data analysis, an up-to-date survey commenting on the wide range of successful applications of the tool, and a valuable insight into current unsolved problems and potential areas to be explored in the future. With the addition of chapter appendices that offer the opportunity for more in-depth theoretical discussion, this is an essential resource that integrates all aspects of the subject and is ideal for anyone using, or interested in using, sum-frequency spectroscopy.