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Author: Gaetano Granozzi
Publisher: MDPI
ISBN: 3039216422
Category : Science
Languages : en
Pages : 398
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Book Description
Electrochemical surface science (EC-SS) is the natural advancement of traditional surface science (where gas–vacuum/solid interfaces are studied) to liquid (solution)/electrified solid interfaces. Such a merging between two different disciplines—i.e., surface science (SS) and electrochemistry—officially advanced ca. three decades ago. The main characteristic of EC-SS versus electrochemistry is the reductionist approach undertaken, inherited from SS and aiming to understand the microscopic processes occurring at electrodes on the atomic level. A few of the exemplary keystone tools of EC-SS include EC-scanning probe microscopies, operando and in situ spectroscopies and electron microscopies, and differential EC mass spectrometry (DEMS). EC-SS indirectly (and often unconsciously) receives a great boost from the requirement for rational design of energy conversion and storage devices for the next generation of energetic landscapes. As a matter of fact, the number of material science groups deeply involved in such a challenging field has tremendously expanded and, within such a panorama, EC and SS investigations are intimately combined in a huge number of papers. The aim of this Special Issue is to offer an open access forum where researchers in the field of electrochemistry, surface science, and materials science could outline the great advances that can be reached by exploiting EC-SS approaches. Papers addressing both the basic science and more applied issues in the field of EC-SS and energy conversion and storage materials have been published in this Special Issue.
Author: Gaetano Granozzi
Publisher: MDPI
ISBN: 3039216422
Category : Science
Languages : en
Pages : 398
Get Book Here
Book Description
Electrochemical surface science (EC-SS) is the natural advancement of traditional surface science (where gas–vacuum/solid interfaces are studied) to liquid (solution)/electrified solid interfaces. Such a merging between two different disciplines—i.e., surface science (SS) and electrochemistry—officially advanced ca. three decades ago. The main characteristic of EC-SS versus electrochemistry is the reductionist approach undertaken, inherited from SS and aiming to understand the microscopic processes occurring at electrodes on the atomic level. A few of the exemplary keystone tools of EC-SS include EC-scanning probe microscopies, operando and in situ spectroscopies and electron microscopies, and differential EC mass spectrometry (DEMS). EC-SS indirectly (and often unconsciously) receives a great boost from the requirement for rational design of energy conversion and storage devices for the next generation of energetic landscapes. As a matter of fact, the number of material science groups deeply involved in such a challenging field has tremendously expanded and, within such a panorama, EC and SS investigations are intimately combined in a huge number of papers. The aim of this Special Issue is to offer an open access forum where researchers in the field of electrochemistry, surface science, and materials science could outline the great advances that can be reached by exploiting EC-SS approaches. Papers addressing both the basic science and more applied issues in the field of EC-SS and energy conversion and storage materials have been published in this Special Issue.
Author: Keith Oldham
Publisher: John Wiley & Sons
ISBN: 0470710853
Category : Science
Languages : en
Pages : 420
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Book Description
Electrochemistry is a discipline of wide scientific and technological interest. Scientifically, it explores the electrical properties of materials and especially the interfaces between different kinds of matter. Technologically, electrochemistry touches our lives in many ways that few fully appreciate; for example, materials as diverse as aluminum, nylon, and bleach are manufactured electrochemically, while the batteries that power all manner of appliances, vehicles, and devices are the products of electrochemical research. Other realms in which electrochemical science plays a crucial role include corrosion, the disinfection of water, neurophysiology, sensors, energy storage, semiconductors, the physics of thunderstorms, biomedical analysis, and so on. This book treats electrochemistry as a science in its own right, albeit resting firmly on foundations provided by chemistry, physics, and mathematics. Early chapters discuss the electrical and chemical properties of materials from which electrochemical cells are constructed. The behavior of such cells is addressed in later chapters, with emphasis on the electrodes and the reactions that occur on their surfaces. The role of transport to and from electrodes is a topic that commands attention, because it crucially determines cell efficiency. Final chapters deal with voltammetry, the methodology used to investigate electrode behavior. Interspersed among the more fundamental chapters are chapters devoted to applications of electrochemistry: electrosynthesis, power sources, “green electrochemistry”, and corrosion. Electrochemical Science and Technology is addressed to all who have a need to come to grips with the fundamentals of electrochemistry and to learn about some of its applications. It will constitute a text for a senior undergraduate or graduate course in electrochemistry. It also serves as a source of material of interest to scientists and technologists in various fields throughout academia, industry, and government – chemists, physicists, engineers, environmentalists, materials scientists, biologists, and those in related endeavors. This book: Provides a background to electrochemistry, as well as treating the topic itself. Is accessible to all with a foundation in physical science, not solely to chemists. Is addressed both to students and those later in their careers. Features web links (through www.wiley.com/go/EST) to extensive material that is of a more tangential, specialized, or mathematical nature. Includes questions as footnotes to support the reader’s evolving comprehension of the material, with fully worked answers provided on the web. Provides web access to Excel® spreadsheets which allow the reader to model electrochemical events. Has a copious Appendix of relevant data.
Author: Ali A. Ensafi
Publisher: Elsevier
ISBN: 0128164921
Category : Science
Languages : en
Pages : 390
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Book Description
Electrochemical Biosensors summarizes fundamentals and trends in electrochemical biosensing. It introduces readers to the principles of transducing biological information to measurable electrical signals to identify and quantify organic and inorganic substances in samples. The complexity of devices related to biological matrices makes this challenging, but this measurement and analysis are critically valuable in biotechnology and medicine. Electrochemical biosensors combine the sensitivity of electroanalytical methods with the inherent bioselectivity of the biological component. Some of these sensor devices have reached the commercial stage and are routinely used in clinical, environmental, industrial and agricultural applications. - Describes several electrochemical methods used as detection techniques with biosensors - Discusses different modifiers, including nanomaterials, for preparing suitable pathways for immobilizing biomaterials at the sensor - Explains various types of signal monitoring, along with several recognition systems, including antibodies/antigens, DNA-based biosensors, aptamers (protein-based), and more
Author: B. E. Conway
Publisher: Springer Science & Business Media
ISBN: 1475730586
Category : Science
Languages : en
Pages : 714
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Book Description
The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as point charges as in the Gouy-Chapman treatment, and let the center of the ion charges reside at some distance from the metal surface while the distribution was still governed by the Gouy-Chapman view. Finally, in 1947, D. C. Grahame transferred the knowledge of the struc ture of electrolyte solutions into the model of a metal/solution interface, by en visaging different planes of closest approach to the electrode surface depending on whether an ion is solvated or interacts directly with the solid wall. Thus, the Gouy-Chapman-Stern-Grahame model of the so-called electrical double layer was born, a model that is still qualitatively accepted, although theoreti cians have introduced a number of new parameters of which people were not aware 50 years ago.
Author: Manuel P. Soriaga
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 578
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Book Description
Author: Nicolas Alonso-Vante
Publisher: John Wiley & Sons
ISBN: 1119460093
Category : Technology & Engineering
Languages : en
Pages : 293
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Book Description
This book addresses some essential topics in the science of energy converting devices emphasizing recent aspects of nano-derived materials in the application for the protection of the environment, storage, and energy conversion. The aim, therefore, is to provide the basic background knowledge. The electron transfer process and structure of the electric double layer and the interaction of species with surfaces and the interaction, reinforced by DFT theory for the current and incoming generation of fuel cell scientists to study the interaction of the catalytic centers with their supports. The chief focus of the chapters is on materials based on precious and non-precious centers for the hydrogen electrode, the oxygen electrode, energy storage, and in remediation applications, where the common issue is the rate-determining step in multi-electron charge transfer processes in electrocatalysis. These approaches are used in a large extent in science and technology, so that each chapter demonstrates the connection of electrochemistry, in addition to chemistry, with different areas, namely, surface science, biochemistry, chemical engineering, and chemical physics.
Author: Cynthia G. Zoski
Publisher: Elsevier
ISBN: 0444519580
Category : Science
Languages : en
Pages : 935
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Book Description
Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)
Author: Jiaguo Yu
Publisher: Academic Press
ISBN: 0081028903
Category : Technology & Engineering
Languages : en
Pages : 602
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Book Description
Surface Science of Photocatalysis, Volume 32, summarizes significant findings on the surface science behind various classic and novel photocatalysts for energy and environmental applications, with special emphasis on important surface/interface processes in photocatalysis, such as interfacial charge transfer, function of co-catalysts, and adsorption over photocatalyst surface. This book timely and systematically reviews the state-of-the-art of the surface science in semiconductor-based photocatalysis, serving as a useful reference book for both new and experienced researchers in this field.
Author: Fabienne Delaunois
Publisher: CRC Press
ISBN: 0429881134
Category : Science
Languages : en
Pages : 342
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Book Description
Electroless Nickel Plating: Fundamentals to Applications provides a complete and actualized view of electroless nickel plating, thus greatly improving the accessibility of knowledge on the subject. It touches upon all aspects of electroless nickel, from the fundamentals (including thermodynamics of electroless plating, bath chemistry, and substrate preparation) to more applied areas of the field such as bath replenishment, composite coatings, post-treatments, polyalloys, graded and multilayer coatings, ultrasound assistance, applications, and properties. Contributed to by a variety of international authors to ensure different points of view and interests are addressed, this book stands as the first complete and updated state-of-the-art text on electroless nickel in the twenty-first century. It also serves as the first technical book with a strong emphasis on nickel-boron. It also focuses on environmental aspects. Including cutting-edge content presented sufficiently extensive to be directly useful to the practitioner, this book is aimed at materials scientists, metallurgists, and other professionals working with electroless nickel plating.
Author: Sushma Dave
Publisher: Elsevier
ISBN: 0323907849
Category : Technology & Engineering
Languages : en
Pages : 288
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Book Description
Electrochemical Applications of Metal -Organic Frameworks: Advances and Future Potential brings together the basics of Metal-Organic Frameworks (MOFs and it's chemistry and electrochemistry), giving the reader an understanding of the complexities and possibilities of MOF electrochemistry. Providing in-depth coverage of various methods of the synthesis of MOFs for their electrochemical applications, the morphological and electrochemical properties of these materials are discussed along with their future development. Sections cover electrochemical applications of MOFs in batteries, supercapacitors, fuel cells, as anti-corrosive materials, sensors and in electrocatalysis, and more. Recent developments in MOFs that can hold active molecules such as enzymes, bacteria, nanoparticles and promote electrochemical activity are included. This book will be of great interest to researchers and professionals working in industry and academia or anyone interested in the applications of MOF in industrial processes. Provides in-depth coverage of the various methods of synthesis for metal-organic frameworks and their applications in electrochemistry Describes MOF based research in emerging technologies, including solid-state electrolytes and battery operation in extreme environments Provides an instructive roadmap for future MOF research in advanced energy storage devices
