Dynamics in Small Confining Systems PDF Download
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Author:
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Category : Molecular dynamics
Languages : en
Pages : 408
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Book Description
Author:
Publisher:
ISBN:
Category : Molecular dynamics
Languages : en
Pages : 408
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Book Description
Author:
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 782
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Author: J. M. Drake
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 488
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Book Description
Interfacial science has rapidly expanded beyond the original realm of chemistry to include physics, mechanical and chemical engineering, biology, materials science, and other specialized sub-fields. All of these scientific disciplines come together in this book to share viewpoints and bridge gaps among the different approaches and methods presented. Discussions focus on how ultrasmall geometries can force a system to behave in ways significantly different than it behaves in bulk, how this difference affects molecular properties, and how it is probed. Topics include: probing confined systems; structure and dynamics of thin films; nanorheology; diffusion in porous systems; adsorption and phase transitions; and reaction dynamics.
Author: Easo P. George
Publisher:
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Category : Technology & Engineering
Languages : en
Pages : 584
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Book Description
The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.
Author: Sidney Michael Kilbey
Publisher:
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Category :
Languages : en
Pages : 352
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Author:
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ISBN:
Category : Electric insulators and insulation
Languages : en
Pages : 320
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Author:
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ISBN:
Category : Metallurgy
Languages : en
Pages : 724
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Author: Toh-Ming Lu
Publisher:
ISBN:
Category : Electric insulators and insulation
Languages : en
Pages : 312
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Book Description
Author: Monde A. Otooni
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 304
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Book Description
Author: B. E. Conway
Publisher: Springer Science & Business Media
ISBN: 1475730586
Category : Science
Languages : en
Pages : 714
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Book Description
The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as point charges as in the Gouy-Chapman treatment, and let the center of the ion charges reside at some distance from the metal surface while the distribution was still governed by the Gouy-Chapman view. Finally, in 1947, D. C. Grahame transferred the knowledge of the struc ture of electrolyte solutions into the model of a metal/solution interface, by en visaging different planes of closest approach to the electrode surface depending on whether an ion is solvated or interacts directly with the solid wall. Thus, the Gouy-Chapman-Stern-Grahame model of the so-called electrical double layer was born, a model that is still qualitatively accepted, although theoreti cians have introduced a number of new parameters of which people were not aware 50 years ago.
