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Languages : en
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Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy's National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N'-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2 concentration resulted in incremental loss in IAS performance and revealed progressive degrees of "staining" upon testing. Adsorption of SO2 by the IAS necessitates upstream removal of SO2 prior to CO2 capture.
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Languages : en
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Book Description
Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy's National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N'-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2 concentration resulted in incremental loss in IAS performance and revealed progressive degrees of "staining" upon testing. Adsorption of SO2 by the IAS necessitates upstream removal of SO2 prior to CO2 capture.
Author: Athanasios I. Papadopoulos
Publisher: John Wiley & Sons
ISBN: 1119106435
Category : Science
Languages : en
Pages : 690
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Book Description
This comprehensive volume brings together an extensive collection of systematic computer-aided tools and methods developed in recent years for CO2 capture applications, and presents a structured and organized account of works from internationally acknowledged scientists and engineers, through: Modeling of materials and processes based on chemical and physical principles Design of materials and processes based on systematic optimization methods Utilization of advanced control and integration methods in process and plant-wide operations The tools and methods described are illustrated through case studies on materials such as solvents, adsorbents, and membranes, and on processes such as absorption / desorption, pressure and vacuum swing adsorption, membranes, oxycombustion, solid looping, etc. Process Systems and Materials for CO2 Capture: Modelling, Design, Control and Integration should become the essential introductory resource for researchers and industrial practitioners in the field of CO2 capture technology who wish to explore developments in computer-aided tools and methods. In addition, it aims to introduce CO2 capture technologies to process systems engineers working in the development of general computational tools and methods by highlighting opportunities for new developments to address the needs and challenges in CO2 capture technologies.
Author: Mohammad Reza Rahimpour
Publisher: Woodhead Publishing
ISBN: 0128227583
Category : Science
Languages : en
Pages : 574
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Book Description
Advances in Carbon Capture reviews major implementations of CO2 capture, including absorption, adsorption, permeation and biological techniques. For each approach, key benefits and drawbacks of separation methods and technologies, perspectives on CO2 reuse and conversion, and pathways for future CO2 capture research are explored in depth. The work presents a comprehensive comparison of capture technologies. In addition, the alternatives for CO2 separation from various feeds are investigated based on process economics, flexibility, industrial aspects, purification level and environmental viewpoints. - Explores key CO2 separation and compare technologies in terms of provable advantages and limitations - Analyzes all critical CO2 capture methods in tandem with related technologies - Introduces a panorama of various applications of CO2 capture
Author: De-en Jiang
Publisher: John Wiley & Sons
ISBN: 1119091195
Category : Science
Languages : en
Pages : 376
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Book Description
Covers a wide range of advanced materials and technologies for CO2 capture As a frontier research area, carbon capture has been a major driving force behind many materials technologies. This book highlights the current state-of-the-art in materials for carbon capture, providing a comprehensive understanding of separations ranging from solid sorbents to liquid sorbents and membranes. Filled with diverse and unconventional topics throughout, it seeks to inspire students, as well as experts, to go beyond the novel materials highlighted and develop new materials with enhanced separations properties. Edited by leading authorities in the field, Materials for Carbon Capture offers in-depth chapters covering: CO2 Capture and Separation of Metal-Organic Frameworks; Porous Carbon Materials: Designed Synthesis and CO2 Capture; Porous Aromatic Frameworks for Carbon Dioxide Capture; and Virtual Screening of Materials for Carbon Capture. Other chapters look at Ultrathin Membranes for Gas Separation; Polymeric Membranes; Carbon Membranes for CO2 Separation; and Composite Materials for Carbon Captures. The book finishes with sections on Poly(amidoamine) Dendrimers for Carbon Capture and Ionic Liquids for Chemisorption of CO2 and Ionic Liquid-Based Membranes. A comprehensive overview and survey of the present status of materials and technologies for carbon capture Covers materials synthesis, gas separations, membrane fabrication, and CO2 removal to highlight recent progress in the materials and chemistry aspects of carbon capture Allows the reader to better understand the challenges and opportunities in carbon capture Edited by leading experts working on materials and membranes for carbon separation and capture Materials for Carbon Capture is an excellent book for advanced students of chemistry, materials science, chemical and energy engineering, and early career scientists who are interested in carbon capture. It will also be of great benefit to researchers in academia, national labs, research institutes, and industry working in the field of gas separations and carbon capture.
Author: Mohammad Reza Rahimpour
Publisher: Elsevier
ISBN: 0443192340
Category : Technology & Engineering
Languages : en
Pages : 581
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Book Description
Advances and Technology Development in Greenhouse Gases: Emission, Capture and Conversion is a comprehensive seven-volume set of books that discusses the composition and properties of greenhouse gases, and introduces different sources of greenhouse gases emission and the relation between greenhouse gases and global warming. The comprehensive and detailed presentation of common technologies as well as novel research related to all aspects of greenhouse gases makes this work an indispensable encyclopedic resource for researchers in academia and industry.Volume 4 titled Carbon Capture Technologies is devoted to efficient technologies utilized for separation that are the heart of controlling carbon-made greenhouse gases (GHGs). The book starts with a review of carbon capture concepts with a focus on energy penalties as well as the operating pilots and plants followed by a meticulous investigation of different classes of capture methods. Section 2 surveys the absorption process including amines, physical absorbents, alkaline solvents, ionic liquids and deep eutectic solvents, nanoparticle-enhanced solvents, as well as a number of novel materials and structures, that are employed to eliminate GHGs utilizing absorption. Section 3 addresses adsorption-based strategies with a focus on the role of different solid adsorbents, introduces technologies that benefit from membranes, and considers different materials utilized in the fabrication of membranes. The final section deals with other as state-of-the-art alternatives in carbon capture. Moreover, each section reviews the economic assessments and environmental challenges. - Introduces carbon capture concepts and challenges - Describes various absorption and adsorption processes for carbon capture - Includes various membrane technologies for carbon capture
Author: Qiang Wang
Publisher: Royal Society of Chemistry
ISBN: 1788015452
Category : Technology & Engineering
Languages : en
Pages : 318
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Book Description
Inorganic solid adsorbents/sorbents are attractive materials for capturing carbon dioxide (CO2) from flue gases after fossil fuel combustion. Post-combustion Carbon Dioxide Capture Materials introduces the key inorganic materials used as adsorbents/sorbents with specific emphasis on their design, synthesis, characterization, performance, and mechanism. Dedicated chapters cover carbon-based adsorbents, zeolite- and silica-based adsorbents, metal–organic framework (MOF)-based adsorbents, and alkali-metal-carbonate-based adsorbents. The final chapter discusses the practical application aspects of these adsorbents used in carbon dioxide capture from flue gases. Edited and written by world-renowned scientists in each class of the specific material, this book will provide a comprehensive introduction for advanced undergraduates, postgraduates and researchers from both academic and industrial fields wishing to learn about the topic.
Author: Esgeboria Obhielo
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
In this study, a suite of novel CO2 capture sorbents were prepared employing three facile synthetic routes: amine assimilation (co-synthesis), wet impregnation and in situ-impregnation synthesis, to develop a range of materials capable of efficiently adsorbing CO2 while demonstrating their applicability as alternative materials for CO2 capture from coal and gas fired power plants via post-combustion carbon capture. Prepared sorbents were characterised for individual physical and chemical properties, using, scanning electron microscopy, infrared spectroscopy, thermogravimetric analysis, elemental analyses and N2 sorption at 77 K. CO2capture capacities were determined using gravimetric analysis under a range of analysis conditions (different temperature and pressure), with the corresponding effects of materials characteristics on CO2 capacities investigated. The effect of amine incorporation was explored in detail, with findings first bench-marked against the corresponding amine free counterparts, and, then, the effect of increasing amine content analysed. So far, within the context of this study, results suggest that materials prepared via the synthetic routes adopted, exhibit high degrees of synthetic control; in addition, CO2 capture capacities were determined to be dependent upon both textural properties but, more importantly, the basic nitrogen functionalities contained within these materials. This observation was prominent with amine in-situ impregnated silica and melamine resorcinol formaldehyde samples, but not wholly for bio-inspired amine silica samples, as the degree of amine functionalisation could not be controlled by the synthetic route chosen. Irrespective, all materials have shown enhanced adsorption performance as a result of the incorporation of basic nitrogen functionalities into the sorbent structures. Furthermore, prepared materials exhibited easy regeneration and maintained stable sorption capacities ≤ 99.9% over the cycles analysed, with results obtained suggesting new strategies for carbon capture materials development for efficient CO2 capture from power plant flue gas and other relevant applications.
Author: Shin-ichi Nakao
Publisher: Springer
ISBN: 3030188582
Category : Technology & Engineering
Languages : en
Pages : 83
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Book Description
This book summarises the advanced CO2 capture technologies that can be used to reduce greenhouse gas emissions, especially those from large-scale sources, such as power-generation and steel-making plants. Focusing on the fundamental chemistry and chemical processes, as well as advanced technologies, including absorption and adsorption, it also discusses other aspects of the major CO2 capture methods: membrane separation; the basic chemistry and process for CO2 capture; the development of materials and processes; and practical applications, based on the authors’ R&D experience. This book serves as a valuable reference resource for researchers, teachers and students interested in CO2 problems, providing essential information on how to capture CO2 from various types of gases efficiently. It is also of interest to practitioners and academics, as it discusses the performance of the latest technologies applied in large-scale emission sources.
Author: Mohammad Khalid
Publisher: Elsevier
ISBN: 0323885691
Category : Technology & Engineering
Languages : en
Pages : 502
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Book Description
Carbon dioxide (CO2) capture and conversion to value added products, such as chemicals, polymers, and carbon-based fuels represents a promising approach to transform a potential threat to the environment into a value-added product for long term sustainability. Emerging Carbon Capture Technologies: Towards a Sustainable Future provides a multidisciplinary view of the research that is being carried out in this field, covering materials and processes for CO2 capture and utilization and including a broad discussion of the impact of novel technologies in carbon capture on the energy landscape, society and climate. Of interest to students, researchers and professionals in industries related to greenhouse gas mitigation, post-combustion CO2 capture processes, coal-fired power plants, environmental sustainability, green solvents, green technologies, and the utilization of clean energy for environmental protection, this book covers both the experimental and theoretical aspects of novel materials and process development providing a holistic approach toward a sustainable energy future. Includes a wide range of processes and their applications Covers the experimental and theoretical aspects of novel materials and process development Includes techno-economics analysis, regulation, policies and future prospects
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Book Description
An innovative, low-cost, and low-energy-consuming carbon dioxide (CO2) capture technology was developed, based on CO2adsorption on a high-capacity and durable carbon sorbent. This report describes the (1) performance of the concept on a bench-scale system; (2) results of parametric tests to determine the optimum operating conditions; (3) results of the testing with a flue gas from coal-fired boilers; and (4) evaluation of the technical and economic viability of the technology. The process uses a falling bed of carbon sorbent microbeads to separate the flue gas into two streams: a CO2 -lean flue gas stream from which> 90% of the CP2 is removed and a pure stream of CO2 that is ready for compression and sequestration. The carbo sorbent microbeads have several unique properties such as high CO2 capacity, low heat of adsorption and desorption (25 to 28 kJ/mole), mechanically robust, and rapid adsorption and desorption rates. The capture of CO2 from the flue gas is performed at near ambient temperatures in whic the sorbent microbeads flow down by gravity counter-current with the up-flow of the flue gas. The adsorbed CO2 is stripped by heating the CO2-loaded sorbent to - 100°C, in contact with low-pressure ( - 5 psig) steam in a section at the bottom of the adsorber. The regenerated sorben is dehydrated of adsorbed moisture, cooled, and lifted back to the adsorber. The CO2 from the desorber is essentially pure and can be dehydrated, compressed, and transported to a sequestration site. Bench-scale tests using a simulated flue gas showed that the integrated system can be operated to provide> 90% CO2 capture from a 15% CO2 stream in the adsorber and produce> 98% CO2 at the outlet of the stripper. Long-term tests (1,000 cycles) showed that the system can be operated reliably without sorbent agglomeration or attrition. The bench-scale reactor was also operated using a flue gas stream from a coal-fired boil at the University of Toledo campus for about 135 h, comprising 7,000 cycles of adsorption and desorption using the desulfurized flue gas that contained only 4.5% v/v CO2. A capture efficiency of 85 to 95% CO2 was achieved under steady-state conditi ons. The CO2 adsorption capacity did not change significantly during the field test, as determined from the CO2 adsorptio isotherms of fresh and used sorbents. The process is also being tested using the flue gas from a PC-fired power plant at the National Carbon Capture Center (NCCC), Wilsonville, AL. The cost of electricity was calculated for CO2 capture using the carbon sorbent and compared with the no-CO2 capture and CO2 capture with an amine-based system. The increase i the levelized cost of electricity (L-COE) is about 37% for CO2 capture using the carbon sorbent in comparison to 80% for an amine-based system, demonstrating the economic advantage of C capture using the carbon sorbent. The 37% increase in the L-COE corresponds to a cost of capture of $30/ton of CO2, including compression costs, capital cost for the capture system, and increased plant operating and capital costs to make up for reduced plant efficiency. Preliminary sensitivity analyses showed capital costs, pressure drops in the adsorber, and steam requirement for the regenerator are the major variables in determining the cost of CO2 capture. The results indicate that further long-term testing with a flue gas from a pulverized coal fired boiler should be performed to obtain additional data relating to the effects of flue gas contaminants, the ability to reduce pressure drop by using alternate structural packing, and the use of low-cost construction materials.
