Development of Control Systems and State Observers for Efficiency and Durability Improvement in PEM Fuel Cell Based Systems

Development of Control Systems and State Observers for Efficiency and Durability Improvement in PEM Fuel Cell Based Systems PDF Author: Julio Alberto Luna Pacho
Publisher:
ISBN:
Category :
Languages : en
Pages : 216

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Book Description
Proton exchange membrane (PEM) fuel cells, which use hydrogen as fuel, provide high power densities while operating at lower temperatures, reducing the cost of materials and maintenance. PEM fuel cells are suitable for a broad range of applications, such as stationary, combined heat and power (CHP), portable systems and automotive. Performance and degradation in PEM fuel cell-based systems is greatly influenced by the internal conditions of the fuel cell. In this doctoral thesis, an extensive study of modelling, observation and control strategies of a PEM fuel cell-based system is performed. The objective is to obtain advanced control solutions that aid to enhance the durability and improve the efficiency of fuel cells. These control solutions have to take into account the internal conditions of the fuel cell and use this information to operate the system under conditions that guarantee that the degradation rate of the fuel cell is not increased. At the same time, the controllers have to guarantee that the system achieves high efficiencies, considering the parasitic power consumption of the balance of plant (BoP) ancillaries. The observation and control solutions are evaluated using the New European Driving Cycle (NEDC) profile as a case study. The first part of the thesis introduces the motivation of the present work and the structure of the document. Additionally, the current state of the research regarding modelling, state observers and control strategies for PEM fuel cell-based systems are studied in detail. After the study of the state of the art, the objectives of this doctoral work are presented. The second part of the thesis is focused on the development, implementation and study in a simulation environment of a PEM fuel cell-based system model. The model considers spatial derivatives for the fuel cell in order to represent the internal dynamic behaviour, which affects the efficiency and degradation rate of the system. In this thesis, a special attention is given to the electrochemically active surface area (ECSA). The ECSA in the cathode catalyst layer (CCL) is modelled using a twophase water model at the cathode side of the fuel cell to better represent its effect on the output voltage. The BoP ancillaries are considered as a parasitic power consumption that has to be delivered by the fuel cell. The most relevant parasitic power consumption is that of the compressor, which is modelled to include its dynamic behaviour in the control strategies. Once the model equations are presented, model-based nonlinear distributed parameters observers (NDPO) are developed in the third part of the thesis. First, the partial differential equations (PDE) of the PEM fuel cell-based system are discretised and reformulated to obtain the observation model. Using this model, two novel sliding mode control (SMC) approaches for the observation of the internal conditions of the fuel cell are presented and compared, using the NEDC current profile as the case study for the simulations. The fourth part of the thesis is devoted to model-based predictive control of the PEM fuel cell-based system. In particular, a nonlinear model predictive control (NMPC) strategy is proposed to improve the efficiency and at the same time, enhance the lifetime of the fuel cell. The use of the NDPOs in the control scheme facilitates critical information about the internal conditions of the fuel cell. This allows to design advanced control objectives that would not be achievable if using only the limited measurements that are available in PEM fuel cell-based systems. A multi-objective cost function that can prioritise between the different objectives of the controller during the optimisation procedure is designed. Finally, a discussion of the results obtained comparing different prioritisation between control objectives is provided. The fifth and last part of the thesis is devoted to extract conclusions.

Development of Control Systems and State Observers for Efficiency and Durability Improvement in PEM Fuel Cell Based Systems

Development of Control Systems and State Observers for Efficiency and Durability Improvement in PEM Fuel Cell Based Systems PDF Author: Julio Alberto Luna Pacho
Publisher:
ISBN:
Category :
Languages : en
Pages : 216

Get Book Here

Book Description
Proton exchange membrane (PEM) fuel cells, which use hydrogen as fuel, provide high power densities while operating at lower temperatures, reducing the cost of materials and maintenance. PEM fuel cells are suitable for a broad range of applications, such as stationary, combined heat and power (CHP), portable systems and automotive. Performance and degradation in PEM fuel cell-based systems is greatly influenced by the internal conditions of the fuel cell. In this doctoral thesis, an extensive study of modelling, observation and control strategies of a PEM fuel cell-based system is performed. The objective is to obtain advanced control solutions that aid to enhance the durability and improve the efficiency of fuel cells. These control solutions have to take into account the internal conditions of the fuel cell and use this information to operate the system under conditions that guarantee that the degradation rate of the fuel cell is not increased. At the same time, the controllers have to guarantee that the system achieves high efficiencies, considering the parasitic power consumption of the balance of plant (BoP) ancillaries. The observation and control solutions are evaluated using the New European Driving Cycle (NEDC) profile as a case study. The first part of the thesis introduces the motivation of the present work and the structure of the document. Additionally, the current state of the research regarding modelling, state observers and control strategies for PEM fuel cell-based systems are studied in detail. After the study of the state of the art, the objectives of this doctoral work are presented. The second part of the thesis is focused on the development, implementation and study in a simulation environment of a PEM fuel cell-based system model. The model considers spatial derivatives for the fuel cell in order to represent the internal dynamic behaviour, which affects the efficiency and degradation rate of the system. In this thesis, a special attention is given to the electrochemically active surface area (ECSA). The ECSA in the cathode catalyst layer (CCL) is modelled using a twophase water model at the cathode side of the fuel cell to better represent its effect on the output voltage. The BoP ancillaries are considered as a parasitic power consumption that has to be delivered by the fuel cell. The most relevant parasitic power consumption is that of the compressor, which is modelled to include its dynamic behaviour in the control strategies. Once the model equations are presented, model-based nonlinear distributed parameters observers (NDPO) are developed in the third part of the thesis. First, the partial differential equations (PDE) of the PEM fuel cell-based system are discretised and reformulated to obtain the observation model. Using this model, two novel sliding mode control (SMC) approaches for the observation of the internal conditions of the fuel cell are presented and compared, using the NEDC current profile as the case study for the simulations. The fourth part of the thesis is devoted to model-based predictive control of the PEM fuel cell-based system. In particular, a nonlinear model predictive control (NMPC) strategy is proposed to improve the efficiency and at the same time, enhance the lifetime of the fuel cell. The use of the NDPOs in the control scheme facilitates critical information about the internal conditions of the fuel cell. This allows to design advanced control objectives that would not be achievable if using only the limited measurements that are available in PEM fuel cell-based systems. A multi-objective cost function that can prioritise between the different objectives of the controller during the optimisation procedure is designed. Finally, a discussion of the results obtained comparing different prioritisation between control objectives is provided. The fifth and last part of the thesis is devoted to extract conclusions.

Experimental and model-based analysis for performance and durability improvement of PEM fuel cells

Experimental and model-based analysis for performance and durability improvement of PEM fuel cells PDF Author: Stephan Strahl
Publisher:
ISBN:
Category :
Languages : ca
Pages : 48

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Book Description
Increasing global energy demand, growing carbon emissions and the depletion of fossil fuel sources are some of the most important driving forces for the development of sustainable energy solutions. Proton Exchange Membrane (PEM) fuel cells have been demonstrated to be a potential candidate for clean energy conversion in a wide range of applications reaching from highly dynamic transportation systems to stationary systems. Despite their benefits, such as high efficiency and wide operating range, PEM fuel cells must still meet or exceed the technological advantages, such as durability and cost, of conventional power systems in order to be truly competitive. Thus, current research is focused on improving these aspects. This doctoral thesis combines experimental and model-based studies in order to improve performance and durability of PEM fuel cells, that work without external humidification, as demanded by recent government-supported research programs. Improved performance and durability can be obtained by proper system control. The key factor for the development of successful control strategies is adequate thermal and water management considering their interconnections. Therefore, this work investigates the important links between performance, efficiency and lifetime with respect to fuel cell temperature and humidification. The experimental evaluation of temperature-related and purge-related effects shows the great potential of improving the system performance by proper thermal management. In-situ and ex-situ experiments, such as electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), gas chromatography (GC), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscopy (SEM) were utilized in order to explore short-term and long-term effects of operation modes on performance and durability. To provide a better understanding of the experimentally observed phenomena and their different dynamics with respect to the development of efficient controllers, mathematical models have been derived. The dynamic models allow for relating electrode structure to the cell voltage transient behavior during changes in fuel cell temperature and humidification, including important phase change and ionomer sorption dynamics of water. The experimentally validated, model-based analysis provides recommendations of proper operating conditions and catalyst structure, such as optimal fuel cell temperature and adequate pore-size-distribution, in order to improve the PEM fuel cell performance. The modular character and inherent adaptability of the models has been successfully demonstrated in the study of water transport in a high temperature PEM fuel cell stack. It is shown how mathematical modeling can improve the interpretation of experimental results and provide insight into experimentally non-observable interactions. In conclusion, the presented laboratory and model-based work, including the developed experimental and mathematical tools, contribute to current international research targets for advancing sustainable energy solutions.

Sliding-Mode Control of PEM Fuel Cells

Sliding-Mode Control of PEM Fuel Cells PDF Author: Cristian Kunusch
Publisher: Springer Science & Business Media
ISBN: 1447124308
Category : Technology & Engineering
Languages : en
Pages : 188

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Book Description
Sliding-mode Control of PEM Fuel Cells demonstrates the application of higher-order sliding-mode control to PEMFC dynamics showing the advantages of sliding modes. The book introduces the theory of fuel cells and sliding-mode control. It contextualises PEMFCs both in terms of their development and within the hydrogen economy and today’s energy production situation as a whole. It then discusses fuel-cell operation principles, the mathematical background of high-order sliding-mode control and to a feasibility study for the use of sliding modes in the control of an automotive fuel stack. Part II presents experimental results of sliding-mode-control application to laboratory fuel cells and deals with subsystem-based modelling, detailed design, and observability and controllability. Simulation results are contrasted with empirical data and performance, robustness and implementation issues are treated in depth. Possibilities for future research are also laid out.

Control of Fuel Cell Power Systems

Control of Fuel Cell Power Systems PDF Author: Jay T. Pukrushpan
Publisher: Springer Science & Business Media
ISBN: 1447137922
Category : Technology & Engineering
Languages : en
Pages : 175

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Book Description
Presenting the latest research in the control of fuel cell technology, this book will contribute to the commercial viability of the technology. The authors’ background in automotive technology gives the work added authority as a vital element of future planning.

State Observers Design for PEMFC Systems

State Observers Design for PEMFC Systems PDF Author: Julio Alberto Luna Pacho
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
A series of nonlinear state observers are developed to estimate unmeasurable variables in a Proton Exchange Membrane Fuel Cell (PEMFC) system. A study of the most relevant variables to estimate which will improve the e ciency of the system and its performance is done. The implementation of the observers is based on the partial di erential equations that de ne the dynamics of the plant, represented by a distributed parameters model. Forward and backward discretization of the distributed model are performed to take advantage of the boundary conditions of the problem. A super-twisting corrective control action is implemented in the nonlinear observers to reduce the estimation error to zero in a finite amount of time. Simulation results are presented to show the performance of the observers to recover the values of the gas species concentrations and to extract conclusions for future research work.

PEM Fuel Cells with Bio-Ethanol Processor Systems

PEM Fuel Cells with Bio-Ethanol Processor Systems PDF Author: Marta S. Basualdo
Publisher: Springer Science & Business Media
ISBN: 1849961840
Category : Technology & Engineering
Languages : en
Pages : 479

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Book Description
An apparently appropriate control scheme for PEM fuel cells may actually lead to an inoperable plant when it is connected to other unit operations in a process with recycle streams and energy integration. PEM Fuel Cells with Bio-Ethanol Processor Systems presents a control system design that provides basic regulation of the hydrogen production process with PEM fuel cells. It then goes on to construct a fault diagnosis system to improve plant safety above this control structure. PEM Fuel Cells with Bio-Ethanol Processor Systems is divided into two parts: the first covers fuel cells and the second discusses plants for hydrogen production from bio-ethanol to feed PEM fuel cells. Both parts give detailed analyses of modeling, simulation, advanced control, and fault diagnosis. They give an extensive, in-depth discussion of the problems that can occur in fuel cell systems and propose a way to control these systems through advanced control algorithms. A significant part of the book is also given over to computer-aided engineering software tools that can be used to evaluate the dynamic performance of the overall plant. PEM Fuel Cells with Bio-Ethanol Processor Systems is intended for use by researchers and advanced students on chemical, electrical-electronic and mechanical engineering courses in which dynamics and control are incorporated with the traditional steady-state coverage of flowsheet synthesis, engineering economics and optimization.

Hybridization, Diagnostic and Prognostic of PEM Fuel Cells

Hybridization, Diagnostic and Prognostic of PEM Fuel Cells PDF Author: Samir Jemei
Publisher: John Wiley & Sons
ISBN: 1786301679
Category : Science
Languages : en
Pages : 244

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Book Description
Hydrogen is the most abundant element in the universe. It has a place in the energy mix of the future, especially regarding fuel cells (FCs). This book is an investigation into FCs. Prominence is given to the subject of PEMFCs (proton exchange membrane fuel cells) as they offer interesting perspectives on transport and stationary applications. This being said, a number of technological and scientific obstacles remain to be overcome before an industrial level of development can be reached.

PEM Fuel Cells

PEM Fuel Cells PDF Author: Frano Barbir
Publisher: Academic Press
ISBN: 0123877105
Category : Science
Languages : en
Pages : 537

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Book Description
Demand for fuel cell technology is growing rapidly. Fuel cells are being commercialized to provide power to buildings like hospitals and schools, to replace batteries in portable electronic devices, and as replacements for internal combustion engines in vehicles. PEM (Proton Exchange Membrane) fuel cells are lighter, smaller, and more efficient than other types of fuel cell. As a result, over 80% of fuel cells being produced today are PEM cells. This new edition of Dr. Barbir's groundbreaking book still lays the groundwork for engineers, technicians and students better than any other resource, covering fundamentals of design, electrochemistry, heat and mass transport, as well as providing the context of system design and applications. Yet it now also provides invaluable information on the latest advances in modeling, diagnostics, materials, and components, along with an updated chapter on the evolving applications areas wherein PEM cells are being deployed. Comprehensive guide covers all aspects of PEM fuel cells, from theory and fundamentals to practical applications Provides solutions to heat and water management problems engineers must face when designing and implementing PEM fuel cells in systems Hundreds of original illustrations, real-life engineering examples, and end-of-chapter problems help clarify, contextualize, and aid understanding

System-level Modeling and Component Level Control of Fuel Cells

System-level Modeling and Component Level Control of Fuel Cells PDF Author: Xingjian Xue
Publisher:
ISBN:
Category :
Languages : en
Pages : 300

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Book Description


PEM Fuel Cell Durability Handbook, Two-Volume Set

PEM Fuel Cell Durability Handbook, Two-Volume Set PDF Author: Haijiang Wang
Publisher: CRC Press
ISBN: 1439863164
Category : Science
Languages : en
Pages : 952

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Book Description
While PEM fuel cells are highly efficient, environmentally friendly sources of power, their durability hinders the commercialization of this technology. With contributions from international scientists active in PEM fuel cell research, PEM Fuel Cell Durability Handbook, Two-Volume Set provides a comprehensive source of state-of-the-art research in