Design, Synthesis and XRD Structural Characterization of New Coordination Polymers Based on Trinuclear Unit ... PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Design, Synthesis and XRD Structural Characterization of New Coordination Polymers Based on Trinuclear Unit ... PDF full book. Access full book title Design, Synthesis and XRD Structural Characterization of New Coordination Polymers Based on Trinuclear Unit ... by . Download full books in PDF and EPUB format.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
Author: Mona Feizbakhsh Bazargani
Publisher:
ISBN:
Category :
Languages : de
Pages : 0
Get Book Here
Book Description
The present work deals with the preparation and characterization of ten new coordination polymers prepared from different metal ions and ligands by different synthetic methods. In addition to the structural characterization of these compounds by means of X-ray singlecrystal diffraction data, the focus is on the consideration of thermal and spectroscopic properties. The new silver coordination polymer exhibits very unique, robust and interesting polymeric structure with high thermal stability. Two new lanthanide coordination polymers (neodymium and samarium) have been synthesized with H2FDA = 2,5-furandicarboxylic acid in DMF as solvent via capped tube method. The compounds are iso-structural and exhibit threedimensional coordination polymers. The goal of using DMF as pure solvent instead of mixture of water and other solvents was to synthesize new coordination polymer which might show very intensive luminescence effect. The investigation has turned out that these compounds emerge no significant luminescence effect. As it has been reported in previous works in which the H2FDA = 2,5-furandicarboxylic acid was used for construction of lanthanide coordination polymers in water as solvent, however the compounds have exposed very interesting luminescence properties [229-230]. A new cerium coordination polymer has been produced with ligand (H2pdc = 3,5-pyrazoledicarboxylic acid) under solvothermal condition in DMF as solvent. Indeed, ligand (H2pdc = 3,5-pyrazoledicarboxylic acid) is very versatile to construct coordination network by various coordination modes. Three copper (I) coordination polymers have been successfully synthesized via solvent diffusion technique in test tube. The compounds all display 1D polymeric structure with rather similar coordination environment around metal ions. Moreover, they are very stable against temperature rising. The compounds [Pb3(CH3COO)2(N3)4]n and [Na2Pb2(CH3COO)6]n were synthesized under same synthesis conditions and starting materials but with different metal salt and ligand ratios. Interestingly, the both products show three-dimentional frameworks, however they expose different coordination structures. Actually, the investigation shows that the changing metal salt and ligand ratio can result in the formation different structures of coordination networks, although they have been produced under same reaction conditions. Compound [Pb(DHBDA)]n has been made with ligand 2,5-Dihydroxy-1,4-benzenediacetic acid which has been reported in very few works for constructing coordination compounds.
Author: Delia Maria Ciurtin
Publisher:
ISBN:
Category :
Languages : en
Pages : 388
Get Book Here
Book Description
Author: Federica Garau
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
Author: Stefan Kaskel
Publisher: John Wiley & Sons
ISBN: 3527693084
Category : Science
Languages : en
Pages : 904
Get Book Here
Book Description
Providing vital knowledge on the design and synthesis of specific metal-organic framework (MOF) classes as well as their properties, this ready reference summarizes the state of the art in chemistry. Divided into four parts, the first begins with a basic introduction to typical cluster units or coordination geometries and provides examples of recent and advanced MOF structures and applications typical for the respective class. Part II covers recent progress in linker chemistries, while special MOF classes and morphology design are described in Part III. The fourth part deals with advanced characterization techniques, such as NMR, in situ studies, and modelling. A final unique feature is the inclusion of data sheets of commercially available MOFs in the appendix, enabling experts and newcomers to the field to select the appropriate MOF for a desired application. A must-have reference for chemists, materials scientists, and engineers in academia and industry working in the field of catalysis, gas and water purification, energy storage, separation, and sensors.
Author: Armando J. L. Pombeiro
Publisher: John Wiley & Sons
ISBN: 1118742893
Category : Science
Languages : en
Pages : 848
Get Book Here
Book Description
A contemporary compilation of recent achievements in organometallic chemistry The prestigious International Conference on Organometallic Chemistry (ICOMC) was launched in 1963, providing a forum for researchers from around the world to share their findings and explore new paths to advance our knowledge and application of organometallic chemistry. The 25th ICOMC, held in Lisbon in 2012, gathered more than 1,200 participants from 54 countries. This volume celebrates the 25th Silver Edition and the 50th Gold Year of the ICOMC. Featuring contributions from invited 25th ICOMC speakers, Advances in Organometallic Chemistry and Catalysis highlights recent achievements and new and emerging areas of research in the field. Its seven sections cover: Activation and Functionalization of Carbon Single Bonds and Small Molecules Organometallic Synthesis and Catalysis Organometallic Polymerization Catalysis Organometallic Polymers and Materials Organometallic Chemistry and Sustainable Energy Bioorganometallic Chemistry Organometallic Electrochemistry Chapters discuss fundamental underlying concepts, offer illustrative examples and cases, and explore future avenues for continued research. Readers will discover basic principles and properties of organometallic compounds, reaction mechanisms, and detailed descriptions of current applications. Collectively, these chapters underscore the versatility, richness, and potential of modern organometallic chemistry, including its interrelationships with other scientific disciplines. All the contributions are extensively referenced, providing a gateway to the most important original research papers and reviews in organometallic chemistry. Presenting a contemporary understanding of organometallic chemistry and its many applications, Advances in Organometallic Chemistry and Catalysis is recommended for all researchers in the field, from students to advanced investigators.
Author: Alan Earnshaw
Publisher: Elsevier
ISBN: 1483270696
Category : Science
Languages : en
Pages : 127
Get Book Here
Book Description
Introduction to Magnetochemistry provides an introduction to the more important aspects of magnetochemistry. The measurement of magnetic moment has been one of the most consistently useful to coordination chemists. For teaching purposes it provides a simple method of illustrating the ideas of electronic structure, and in research it can provide fundamental information about the bonding and stereochemistry of complexes. The book contains six chapters covering topics such as free atoms and ions, transition metal complexes, crystal field theory, second and third row transition metal complexes, antiferromagnetism, and spin-pairing of electrons. The final chapter describes important experimental methods and then to shows briefly the way in which the problems of interpretation may be tackled.
Author: Leonard R. MacGillivray
Publisher: John Wiley & Sons
ISBN: 111803516X
Category : Science
Languages : en
Pages : 440
Get Book Here
Book Description
Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.
Author: Catherine E. Housecroft
Publisher: MDPI
ISBN: 3036514635
Category : Science
Languages : en
Pages : 264
Get Book Here
Book Description
This Special Issue is one of the first for the new MDPI flagship journal Chemistry (ISSN 2624-8549) which has a broad remit for publishing original research in all areas of chemistry. The theme of this issue is Supramolecular Chemistry in the 3rd Millennium and I am sure that this topic will attract many exciting contributions. We chose this topic because it encompasses the unity of contemporary pluridisciplinary science, in which organic, inorganic, physical and theoretical chemists work together with molecular biologists and physicists to develop a systems-level understanding of molecular interactions. The description of supramolecular chemistry as 'chemistry beyond the molecule' (Jean-Marie Lehn, Nobel Lecture and Gautam R. Desiraju, Nature, 2001, 412, 397) addresses the wide variety of weak, non-covalent interactions that are the basis for the assembly of supramolecular architectures, molecular receptors and molecular recognition, programed molecular systems, dynamic combinatorial libraries, coordination networks and functional supramolecular materials. We welcome submissions from all disciplines involved in this exciting and evolving area of science.
Author: Stuart R. Batten
Publisher: Royal Society of Chemistry
ISBN: 0854048375
Category : Science
Languages : en
Pages : 440
Get Book Here
Book Description
The field of coordination polymer research is now vast, & one of the fastest growing areas of chemistry in recent times, with important work being done on a variety of different aspects. This book provides a broad overview of all the major facets of modern coordination polymer science in the one place.
