Design and Synthesis of Two Novel Pincer-type Ligands for Use in Asymmetric Catalysis

Design and Synthesis of Two Novel Pincer-type Ligands for Use in Asymmetric Catalysis PDF Author: Jennifer Beckman
Publisher:
ISBN:
Category : Asymmetric synthesis
Languages : en
Pages : 132

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Design and Synthesis of Two Novel Pincer-type Ligands for Use in Asymmetric Catalysis

Design and Synthesis of Two Novel Pincer-type Ligands for Use in Asymmetric Catalysis PDF Author: Jennifer Beckman
Publisher:
ISBN:
Category : Asymmetric synthesis
Languages : en
Pages : 132

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Pincer Compounds

Pincer Compounds PDF Author: David Morales-Morales
Publisher: Elsevier
ISBN: 0128129328
Category : Science
Languages : en
Pages : 756

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Book Description
Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen's The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. - Describes the chemistry and applications of this important class of organometallic and coordination compounds - Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes - Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

The Chemistry of Pincer Compounds

The Chemistry of Pincer Compounds PDF Author: David Morales-Morales
Publisher: Elsevier
ISBN: 0080545157
Category : Science
Languages : en
Pages : 467

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Book Description
Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties.The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials.* Describes the chemistry and applications of this important class of organometallic and coordination compounds* Covers the areas in which pincer complexes have had an impact* Includes information on more recent and interesting pincer compounds not just those that are well-known

Design and Synthesis of Novel Chiral Bisoxazoline Ligands for the Catalytic Asymmetric Allylic Oxidation

Design and Synthesis of Novel Chiral Bisoxazoline Ligands for the Catalytic Asymmetric Allylic Oxidation PDF Author: Davoud Asgari
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 150

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Chiral Ligands

Chiral Ligands PDF Author: Montserrat Diéguez
Publisher: CRC Press
ISBN: 1000378985
Category : Medical
Languages : en
Pages : 338

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Book Description
Many new drugs on the market are chiral compounds, that is, they can exist in two non-superimposable mirror-image forms. Asymmetric catalysis encompasses a large variety of processes for obtaining such compounds. The performance of the catalyst in those processes largely depends on the ligand that makes up the catalyst. This book describes the most relevant ligand libraries for some key processes, including an overview of the state of art and the key mechanistic aspects that favor a high catalytic performance. Key Features: The book presents historical content from the time of discovery for each family of ligands. Provides a description of the synthetic route and the ligand library's application in various catalytic asymmetric reactions Suitable as supplementary reading for courses targeting the design, synthesis and application of chiral catalysts, asymmetric catalysis and sustainable production Edited by a distinguished scientist in the field, the book has a diverse audience including research groups in homogeneous catalysis, particularly asymmetric transformations

Two-in-one pincer type ligands and their metal complexes for catalysis

Two-in-one pincer type ligands and their metal complexes for catalysis PDF Author: Alexander Gers-Barlag
Publisher:
ISBN:
Category :
Languages : de
Pages : 0

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Book Description
The synthesis, characterization and first applications in catalysis of dinuclear metal complexes of the new Two-in-one pincer ligand scaffold are described in this work. Zinc(II) compexes were used to compare structural and electronical features of two derivatives of the ligand system. Reactivity studies revealed a broad range of reactions for a cobalt(II) complex, although detailed analysis of the reaction products was not possible so far. Furthermore, several rhodium(I) complexes have been synthesized and fully characterized. For a rhodium(I) carbonyl complex a dearomatization sequence wa...

The Design and Synthesis of Two Novel, Polymerizable Ligands Affording a 1- to 0 Charge Transition and a 1+ to 2+ Charge Transition

The Design and Synthesis of Two Novel, Polymerizable Ligands Affording a 1- to 0 Charge Transition and a 1+ to 2+ Charge Transition PDF Author: Nicholas Ernest Bencivenga
Publisher:
ISBN:
Category :
Languages : en
Pages : 148

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Ligand Platforms in Homogenous Catalytic Reactions with Metals

Ligand Platforms in Homogenous Catalytic Reactions with Metals PDF Author: Ryohei Yamaguchi
Publisher: John Wiley & Sons
ISBN: 1118943090
Category : Technology & Engineering
Languages : en
Pages : 358

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Book Description
Serving as a user's manual for synthetic organic and catalytic chemists, this book guides chemists in the design and choice of ligands to catalyze organic reactions and apply the results for more efficient, green, and practical synthesis. • Focuses on the role of ligands in metal complexes that catalyze green organic transformations: a hot topic in the area of organic synthesis and green chemistry • Offers a comprehensive resource to help readers design and choose ligands and understand selectivity/reactivity characteristics • Addresses a gap by taking novel ligand approaches and including up-to-date discussion on hydrogen transfers and reactions • Presents important industrial perspective and provides rational explanations of ligand effects, impacts, and novelty

Synthesis of Novel N, P-ligands and Their Appliation in Asymmetric Catalysis

Synthesis of Novel N, P-ligands and Their Appliation in Asymmetric Catalysis PDF Author: John Bernard Hand
Publisher:
ISBN:
Category : Asymmetric synthesis
Languages : en
Pages : 180

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Design and Synthesis of New Monoterpenoid Derived Ligands for Asymmetric Catalysis

Design and Synthesis of New Monoterpenoid Derived Ligands for Asymmetric Catalysis PDF Author: Monte J. Millar
Publisher:
ISBN:
Category :
Languages : en
Pages :

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