Controlled Modification of Metal-organic Frameworks at Metal Sites PDF Download
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Author: Wenhua Zhang
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Author: Wenhua Zhang
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Masoud Mozafari
Publisher: Woodhead Publishing
ISBN: 0128169842
Category : Medical
Languages : en
Pages : 584
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Book Description
Metal-Organic Frameworks for Biomedical Applications is a comprehensive, authoritative reference that offers a substantial and complete treatment of published results that have yet to be critically reviewed. It offers a summary of current research and provides in-depth understanding of the role of metal-organic frameworks in biomedical engineering. The title consists of twenty-two chapters presented by leading international researchers in the field. Chapters are arranged by target-application in biomedical engineering, allowing medical and pharmaceutic specialists to translate current materials and engineering science on metal-organic frameworks into their work. Presents the state-of-the art in metal-organic frameworks for biomedical applications Offers comprehensive treatment of metal-organic frameworks that is useful to pharmaceutic and medical experts who are non-specialists in materials science Helps materials scientists and engineers understand the needs of biomedical engineering Critically-reviews published results and current research in the field
Author: Leonard R. MacGillivray
Publisher: John Wiley & Sons
ISBN: 1118931580
Category : Science
Languages : en
Pages : 1210
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Book Description
Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc
Author: Leonard R. MacGillivray
Publisher: John Wiley & Sons
ISBN: 111803516X
Category : Science
Languages : en
Pages : 440
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Book Description
Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.
Author: Olivier Kahn
Publisher: Courier Dover Publications
ISBN: 0486837424
Category : Science
Languages : en
Pages : 419
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Book Description
Highly regarded and historic book covers basic concepts of magnetization and magnetic susceptibility, establishes the fundamental equations of molecular magnetism, and examines molecules containing a unique magnetic center. 2019 edition.
Author: Clara Casado-Coterillo
Publisher: MDPI
ISBN: 3039219766
Category : Technology & Engineering
Languages : en
Pages : 146
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Book Description
Mixed matrix membranes (MMMs) have attracted a large amount of interest in research laboratories worldwide in recent decades, motivated by the gap between a growing interest in developing novel mixed matrix membranes by various research groups and the lack of large-scale implementation. This Special Issue contains six publications dealing with the current opportunities and challenges of mixed matrix membranes development and applications to solve environmental and health challenges of the society of 21st century.
Author: Wei Xia
Publisher: Springer
ISBN: 9811068119
Category : Technology & Engineering
Languages : en
Pages : 148
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Book Description
This thesis systematically introduces readers to a new metal-organic framework approach to fabricating nanostructured materials for electrochemical applications. Based on the metal-organic framework (MOF) approach, it also demonstrates the latest ideas on how to create optimal MOF and MOF-derived nanomaterials for electrochemical reactions under controlled conditions. The thesis offers a valuable resource for researchers who want to understand electrochemical reactions at nanoscale and optimize materials from rational design to achieve enhanced electrochemical performance. It also serves as a useful reference guide to fundamental research on advanced electrochemical energy storage materials and the synthesis of nanostructured materials.
Author: Dinara Andirova
Publisher:
ISBN:
Category : Adsorption
Languages : en
Pages : 194
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Book Description
Metal organic frameworks (MOFs) belong to a class of crystalline materials where metal constituting building blocks are connected by organic ligands to form well-defined nanoporous structures. These materials exhibit uniform pores, extremely high surface area, and potential for chemical tunability rendering MOFs available for many applications such as gas storage and separations, drug delivery, and catalysis. In the first part of this work structural optimization of MOFs for practical CO2 capture processes have been studied. It has been reported that the adsorption properties of MOFs in practical CO2 capture tend to be harmed by the presence of moisture possibly due to the hydrophilic nature of the coordinatively unsaturated sites (CUSs) present within the frameworks. Here, the CUSs were functionalized with amine-containing molecules to prevent its structural degradation in a humid CO2 capture environment. Specifically, it was demonstrated that amine groups could be grafted on the metal sites of the magnesium dioxybenzenedicarboxylate (Mg/DOBDC) without changing the framework structure of the material. The amine modified framework showed better structural preservation and retained CO2 capture capacity after exposure to strident humid conditions. In the second part of this work, synthesis of layered metal organic frameworks was investigated. Layered materials are solids with strong in-plane chemical bonds and weak out-of-plane bonds,which are stacked to form 3D materials. Currently this field is expanding from layered clays, graphene, silicates to studies of layered MOF s. Here, a layered MOF where each layer is composed of cobalt-carboxylate building units connected via organic ligands of benzene 1,4-dicarboxylic acid was synthesized. The interlayer space provides the ability for introduction of additional ligands and simple post-synthesis interlayer ligand exchange with larger or smaller molecules. Such ligand introduction was performed using simple amine groups. It was found that crystalline materials could be generated with well-defined layers and addition of amine ligands might be exhibiting a templating role in the crystallization. This type of modification could open up chemistry of MOFs providing structures where both micropores and mesopores could exist and introduce a post-synthesis method of exchanging interlayer ligands therefore manipulating the gallery space between the layers. These layered MOF structures have a promising potential in CO2 selective separation from mixed gas streams. In the third part of the work, metal oxide nanoparticles were obtained utilizing structures of MOFs as precursor materials. It was found that crystalline cobalt oxide nanoparticles could be generated where particle size could be controlled with different calcination temperatures. The obtained nanoparticles also retained the original morphology of starting MOF crystals.
Author: Anish Khan
Publisher: Materials Research Forum LLC
ISBN: 1644900424
Category : Technology & Engineering
Languages : en
Pages : 426
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Book Description
Because of their nanoporous structures and ultra-high surface areas Metal-Organic Framework Composites (MOFs) are very interesting materials. The book focusses on the following applications: gas capture and storage, especially molecular hydrogen storage; performance enhancement of Li-ion batteries; gas separation, nano-filtration, ionic sieving, water treatment, and catalysis; sustainable renewable energy resources, electrochemical capacitors, including supercapacitors, asymmetric supercapacitors and hybrid supercapacitors; biomedical disciplines including drug delivery, theranostics; biological detection and imaging; nanoparticle photosensitizers for photodynamic therapy (PDT) and photothermal therapy (PTT). Keywords: MOF Materials, Hydrogen Storage, Renewable Energy Applications, Lithium Batteries, MOF-Quantum Dots, Clean Energy, Nanoporous MOFs, Supercapacitors, Therapeutic Applications, Biosensing, Bioimaging, Phototherapy of Cancer, Gas Separation, Nano-filtration, Ionic Sieving, Water Treatment, Drug Delivery, Theranostics; Nanoparticle Photosensitizers, Photodynamic Therapy (PDT), Photothermal Therapy (PTT).
Author: Omar M. Yaghi
Publisher: John Wiley & Sons
ISBN: 3527821104
Category : Science
Languages : en
Pages : 684
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Book Description
A concise introduction to the chemistry and design principles behind important metal-organic frameworks and related porous materials Reticular chemistry has been applied to synthesize new classes of porous materials that are successfully used for myraid applications in areas such as gas separation, catalysis, energy, and electronics. Introduction to Reticular Chemistry gives an unique overview of the principles of the chemistry behind metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and zeolitic imidazolate frameworks (ZIFs). Written by one of the pioneers in the field, this book covers all important aspects of reticular chemistry, including design and synthesis, properties and characterization, as well as current and future applications Designed to be an accessible resource, the book is written in an easy-to-understand style. It includes an extensive bibliography, and offers figures and videos of crystal structures that are available as an electronic supplement. Introduction to Reticular Chemistry: -Describes the underlying principles and design elements for the synthesis of important metal-organic frameworks (MOFs) and related materials -Discusses both real-life and future applications in various fields, such as clean energy and water adsorption -Offers all graphic material on a companion website -Provides first-hand knowledge by Omar Yaghi, one of the pioneers in the field, and his team. Aimed at graduate students in chemistry, structural chemists, inorganic chemists, organic chemists, catalytic chemists, and others, Introduction to Reticular Chemistry is a groundbreaking book that explores the chemistry principles and applications of MOFs, COFs, and ZIFs.
