Organic Conformational Analysis and Stereochemistry from Circular Dichroism Spectroscopy

Organic Conformational Analysis and Stereochemistry from Circular Dichroism Spectroscopy PDF Author: David A. Lightner
Publisher: John Wiley & Sons
ISBN: 9780471354055
Category : Science
Languages : en
Pages : 508

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Book Description
Unter Zirkulardichroismus (CD) versteht man die spezifisch unterschiedliche Absorption von links- und rechtszirkular polarisiertem Licht durch bestimmte Moleküle. CD-Effekte lassen sich in Abhängigkeit von der Wellenlänge messen und spektroskopisch auswerten; sie geben beispielsweise Auskunft über die Konformation organischer Verbindungen. Dieses Buch richtet sich an den organischen Chemiker, der mit den Grundprinzipien der Stereochemie vertraut ist, und erläutert die Anwendung der CD-Spektroskopie zur Konformationsanalyse ausführlich und verständlich. (06/00)

Organic Conformational Analysis and Stereochemistry from Circular Dichroism Spectroscopy

Organic Conformational Analysis and Stereochemistry from Circular Dichroism Spectroscopy PDF Author: David A. Lightner
Publisher: John Wiley & Sons
ISBN: 9780471354055
Category : Science
Languages : en
Pages : 508

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Book Description
Unter Zirkulardichroismus (CD) versteht man die spezifisch unterschiedliche Absorption von links- und rechtszirkular polarisiertem Licht durch bestimmte Moleküle. CD-Effekte lassen sich in Abhängigkeit von der Wellenlänge messen und spektroskopisch auswerten; sie geben beispielsweise Auskunft über die Konformation organischer Verbindungen. Dieses Buch richtet sich an den organischen Chemiker, der mit den Grundprinzipien der Stereochemie vertraut ist, und erläutert die Anwendung der CD-Spektroskopie zur Konformationsanalyse ausführlich und verständlich. (06/00)

Conformational Analysis

Conformational Analysis PDF Author:
Publisher:
ISBN: 9780121730505
Category : Conformational analysis
Languages : en
Pages : 524

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Book Description


Circular Dichroism and the Conformational Analysis of Biomolecules

Circular Dichroism and the Conformational Analysis of Biomolecules PDF Author: G.D. Fasman
Publisher: Springer Science & Business Media
ISBN: 1475725086
Category : Science
Languages : en
Pages : 739

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Book Description
''Excellent and very timely....It will undoubtedly become a standard reference for the application of circular dichroism (CD) to biomolecules.'' --- Quarterly Review of Biology, March 1997 ''[T]estament to the book's utility is the fact that during the course of my review I had to 'rescue' it from the desks of graduate students on an almost daily basis. In summary, this is a great book.'' --- American Scientist ''Well documented chapters provide a very good insight into the problems surrounding the conformation of biomacromolecules...An indispensible source of information.'' --- Nahrung, 42(2), 1998 Renowned experts present the first state-of-the-art description of circular dichroism spectroscopy (CD). Chapters present in-depth discussions of the history of the field, the theory of CD for application to globular proteins, membrane proteins, peptides, nucleic acids and their interactions, carbohydrates, and instrumentation. Discussions also feature new techniques using synchrotron radiation, vibrational Raman optical activity, and vibrational CD. More than 250 illustrations supplement the text.

Conformational Analysis of Molecules in Excited States

Conformational Analysis of Molecules in Excited States PDF Author: Jacek Waluk
Publisher: John Wiley & Sons
ISBN: 9780471297079
Category : Science
Languages : en
Pages : 400

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Book Description
A unique look at some of the hottest topics in photophysics and photochemistry today The study of molecules in excited states has exploded over the past decade, providing new insights into conformational changes in organic molecules and opening up research opportunities for scientists and professionals in chemistry, physics, biology, medicine, and materials engineering. Using conformational analysis as a unifying concept, this important new work provides readers with a cohesive and cutting-edge overview of this fascinating and challenging field. From conformational changes accompanying photoinduced electron transfer to elementary photophysical and photochemical processes in living systems, the most representative and challenging topics are carefully gleaned from the vast literature, highlighting major conceptual problems along with the relevant experimental techniques. Authoritative, detailed contributions from both experimentalists and theoreticians include coverage of: * Conformational changes in intramolecular excited state electron transfer * Conformational aspects of excited state proton transfer * The novel topic of solute-solvent friction in chemical reactions * Mechanisms and structural aspects of exciplex formations * Conformational aspects of organic photochemistry * Calculations of excited state conformational properties

Conformational Analysis

Conformational Analysis PDF Author: G Chiurdoglu
Publisher: Elsevier
ISBN: 0323157319
Category : Science
Languages : en
Pages : 293

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Book Description
Conformational Analysis: Scope and Present Limitations contains the proceedings of the Brussels International Symposium on Conformational Analysis held in Brussels, Belgium, in September 1969. The papers focus on the theoretical aspects and applications of conformational analysis, such as those concerning the aliphatic and especially the cyclic series. Topics covered include the geometry of five-membered rings; conformational transmission in steroids; conformational aspects of N-quaternization; and applications of nuclear magnetic resonance spectrometry in conformational studies of cyclohexane derivatives. This book is comprised of 20 chapters and begins with a discussion on the conformational aspects of some five-membered ring compounds based mainly on observed (diffraction methods) and calculated torsional angles. The reader is then introduced to nuclear magnetic resonance studies of the conformations and conformational barriers in cyclic molecules; conformational studies of six-membered heterocycles; conformational transmission in steroids; and solvolytic cyclizations involving double bonds. The remaining chapters explore the conformational analysis of methylcyclohexane, cyclohexane systems, and carbonium ions; conformations of membrane-active cyclodepsipeptides; energetics of isomeric transition states and competitive reaction pathways in conformational analysis; and conformational aspects of the reaction of the 1-methylcyclodecane-l,6-diols with acid. This monograph will be of interest to organic chemists.

Conformational Analysis of Polymers

Conformational Analysis of Polymers PDF Author: Yuji Sasanuma
Publisher: John Wiley & Sons
ISBN: 1119716357
Category : Science
Languages : en
Pages : 500

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Book Description
Conformational Analysis of Polymers Comprehensive resource focusing on theoretical methods and experimental techniques to analyze physical polymer chemistry Connecting varied issues to demonstrate the impact on areas like biodegradability, environmental friendliness, structure-property relationship, and molecular design, Conformational Analysis of Polymers introduces theoretical methods and experimental techniques to analyze physical polymer chemistry. Opening with a description of fundamental concepts and then describing the conformational characteristics of various polymers, including different heteroatoms and chemical species, the text continues onto the applications of density functional theory (DFT) to polymer crystals and structure-property relationships. The book concludes by bringing these issues together to demonstrate their practical impact on different areas of the field. Various methods and techniques, including DFT, statistical mechanics, NMR, spectroscopy, and molecular orbital theory, are also covered. Written by a highly qualified author, Conformational Analysis of Polymers explores sample topics such as: Fundamentals of polymer physical chemistry: stereochemistry of polymers, models for polymeric chains, Flory-Huggins theory, and rubber elasticity Quantum chemistry for polymers: ab initio molecular orbital theory, DFT, NMR parameters, and periodic DFT of polymer crystals Statistical mechanics of polymeric chains: basic rotational isomeric state (RIS) scheme, refined RIS method, inversional-rotational isomeric state method, and probability theory for RIS scheme Experimental techniques: NMR and scattering methods Providing a timely update to the field of chain conformations of synthetic polymers and connecting fundamental theoretical approaches, experimental techniques, and case study applications; Conformational Analysis of Polymers is an essential resource for polymer chemists, physicists, and material scientists, industrial engineers who synthesize and process polymers, and academic researchers.

Principles of Conformation Analysis: Equus Reference Guide

Principles of Conformation Analysis: Equus Reference Guide PDF Author: Deb Bennett
Publisher: Trafalgar Square Publishing
ISBN: 9781929164608
Category : Nature
Languages : en
Pages : 300

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Book Description
Everything you need to know about horse anatomy is found here. Follow expert Dr. Deb Bennett as she takes an in-depth, informed look at conformation and reveals how to improve your performance and harmony with your horse. The three popular volumes of Principles of Conformation Analysis are now available in this one edition, providing the most comprehensive insight into equine structure and its effects on movement, soundness, and performance. Within these pages, you'll find: * Valuable guidelines for examining the suitability of horses for various activities * Hundreds of photos, charts, and drawings explaining various body parts and the way they work together * Detailed information on how to minimize conformational limitations and maximize your horse's performance, whatever his breed or sport * Simple methods for analyzing hind legs and detecting horses with lame backs * Exclusive lab exercises from Dr. Deb's files that offer practical help in evaluating your own horse Whether you're looking for an international dressage horse or a comfortable pleasure mount, Principles of Conformation Analysis will improve your eye for conformation.And no matter how you're involved in the horse industry--as a buyer, trainer, rider, or breeder--this book will enrich your equestrian experience.

Modern Conformational Analysis

Modern Conformational Analysis PDF Author: Helena Dodziuk
Publisher: John Wiley & Sons
ISBN: 9780471186113
Category : Science
Languages : en
Pages : 280

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Book Description
Viele Bücher über organische Zusammensetzungen behandeln die Stereochemie, schenken aber der räumlichen Struktur der organischen Moleküle, vor allem der weniger gebräuchlichen, kaum Beachtung. Diese Monographie stellt nun ein umfassendes Werk zur organischen Struktur und der Konformationsanalyse dar. Das Interesse des Autors an der Formenvielfalt der organischen Moleküle spiegelt sich besonders intensiv in der Betrachtung der Molekülordnung wider, die in organisch chemischen und biologischen Systemen von großer Bedeutung ist. Der neue Band in der Reihe 'Methods in Stereochemical Analysis' stellt vor allem diese Bedeutung der Molekülgestalt und die Einwirkung theoretischer Studien und synthetischer Chemie zu diesem Themenkomplex in den Vordergrund.

Approaches to the Conformational Analysis of Biopharmaceuticals

Approaches to the Conformational Analysis of Biopharmaceuticals PDF Author: Roger L. Lundblad
Publisher: CRC Press
ISBN: 1439807817
Category : Medical
Languages : en
Pages : 370

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Book Description
The activity of many biopharmaceutical polymers is dependent on conformation, and the next several years will see increased interest in the conformational analysis of these polymers resulting from the development of biosimilar or "follow-on" biological products. While a wide variety of approaches to analysis exists, finding the most viable ones wou

AMolecular Description of Biological Membrane Components by Computer Aided Conformational Analysis

AMolecular Description of Biological Membrane Components by Computer Aided Conformational Analysis PDF Author: Robert Brasseur
Publisher: CRC Press
ISBN: 1000697665
Category : Medical
Languages : en
Pages : 444

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Book Description
First published in 1990, the goal of these two volumes is to help fill the gap between theory and experiment in membrane science. Those involved with biochemistry, biophysics, pharmacology, and biology will find these volumes interesting and informative.