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Author: Eli Ruckenstein
Publisher: CRC Press
ISBN: 0429649045
Category : Technology & Engineering
Languages : en
Pages : 303
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Book Description
Comprising one volume of Functional and Modified Polymeric Materials, Two-Volume Set, this curated collection of papers by Professor Eli Ruckenstein and co-workers discusses the merits of concentrated emulsion polymerization systems, as well as their ability to yield a broad variety of products with high synthetic efficiency. Comprised of carefully curated chapters previously published by these pioneering scientists in the field, this volume offers a comprehensive view of the subject and presents functional and modified polymeric materials prepared by concentrated emulsion polymerization approaches. It covers conductive polymer composites, core-shell latex particles, enzyme/catalyst carriers, and plastics toughening and compatibilization polymerization. The authors have performed seminal studies on the preparation of functional and modified polymeric materials via concentrated emulsion polymerization. The corresponding research papers, after further selection and classification, are collected in the four chapters of this book.
Author: Eli Ruckenstein
Publisher: CRC Press
ISBN: 0429649045
Category : Technology & Engineering
Languages : en
Pages : 303
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Book Description
Comprising one volume of Functional and Modified Polymeric Materials, Two-Volume Set, this curated collection of papers by Professor Eli Ruckenstein and co-workers discusses the merits of concentrated emulsion polymerization systems, as well as their ability to yield a broad variety of products with high synthetic efficiency. Comprised of carefully curated chapters previously published by these pioneering scientists in the field, this volume offers a comprehensive view of the subject and presents functional and modified polymeric materials prepared by concentrated emulsion polymerization approaches. It covers conductive polymer composites, core-shell latex particles, enzyme/catalyst carriers, and plastics toughening and compatibilization polymerization. The authors have performed seminal studies on the preparation of functional and modified polymeric materials via concentrated emulsion polymerization. The corresponding research papers, after further selection and classification, are collected in the four chapters of this book.
Author: Eli Ruckenstein
Publisher: CRC Press
ISBN: 0429651686
Category : Technology & Engineering
Languages : en
Pages : 335
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Book Description
Comprising one volume ofFunctional and Modified Polymeric Materials, Two-Volume Set, this curated collection of papers by Professor Eli Ruckenstein and co-workers discusses the merits of concentrated emulsion polymerization systems, as well as their ability to yield a broad variety of products with high synthetic efficiency. Comprised of carefully curated chapters previously published by these pioneering scientists in the field, this volume offers a comprehensive view of the subject and presents functional and modified polymeric materials prepared by concentrated emulsion polymerization approaches. It covers conductive polymer composites, core-shell latex particles, enzyme/catalyst carriers, and plastics toughening and compatibilization polymerization. The authors have performed seminal studies on the preparation of functional and modified polymeric materials via concentrated emulsion polymerization. The corresponding research papers, after further selection and classification, are collected in the four chapters of this book.
Author: Masayoshi Okubo
Publisher: Springer Science & Business Media
ISBN: 9783540229230
Category : Technology & Engineering
Languages : en
Pages : 388
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Book Description
In this special volume on polymer particles, recent trends and developments in the synthesis of nano- to micron-sized polymer particles by radical polymerization (Emulsion, Miniemulsion, Microemulsion, and Dispersion Polymerizations) of vinyl monomers in environmentally friendly heterogeneous aqueous and supercritical carbon dioxide fluid media are reviewed by prominent worldwide researchers. In addition to the important challenges and possibilities with regards to design and preparation of functionalized polymer particles of controlled size, the topics described are of great current interest due to the increased awareness of environmental issues.
Author: Robert G. Gilbert
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 392
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Book Description
This book provides a modern overview of the principles governing emulsion polymerization, a topic of both academic and industrial importance. The reader is provided with the mathematical, physical and technical tools to understand the mechanisms and physical chemistry of these systems, particularly the major advances of the last 15 years. The book describes the mechanisms that govern the various aspects of an emulsion polymerization, and how from appropriate experimental studies, the dominant mechanisms in a particular system may be deduced. From such deductions, the means are developed whereby the properties of the result of the emulsion polymerization can be quantitatively modelled and trends can be qualitatively understood and predicted. This book opens the way to the intelligent, knowledge-based design that is the future for improvements and innovations in products and processes from this important technology. Provides a thoroughly up-to-date overview of the principles and practices of emulsion polymerization Contains mathematical, physical, and technical tools which enable the reader to understand the mechanisms and physical chemistry used in the field Includes extensive exercises with model answers
Author: A. M. van Herk
Publisher: John Wiley & Sons
ISBN: 1405171782
Category : Technology & Engineering
Languages : en
Pages : 328
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Book Description
Emulsion polymerisation produces high value polymers in a low cost, environmentally friendly process. The drive to develop environmentally benign production methods for polymers has resulted in widespread development and implementation of the emulsion polymerisation technique. In addition, when combined with novel polymerisation mechanisms the process can give rise to a range of polymer products with particularly useful properties. Emulsion polymerisation is a complex process, governed by the interplay of both chemical and physical properties including polymerisation kinetics and dispersion stability. Successful industrial application relies on understanding and controlling those properties. By carefully explaining the principles of the reaction, based on well-designed experimental investigation, Chemistry and Technology of Emulsion Polymerisation provides a practical and intuitive explanation of emulsion polymerisation. In the development of industrial processes, coupling that understanding with everyday practice can be a further difficult step, so the book emphasises a clear, comprehensive and straightforward discussion to illustrate how the principles relate to practical application. Written for research chemists, technologists and engineers in the polymer, fine and specialty chemicals industries, and in university or government laboratories, this book will be particularly valuable to those early on in their careers. The comprehensive and straightforward coverage will also ensure it is an important resource for advanced courses in emulsion polymerisation.
Author: Chorng-Shyan Chern
Publisher: John Wiley & Sons
ISBN: 0470377933
Category : Science
Languages : en
Pages : 268
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Book Description
Up-to-date coverage of methods of emulsion polymerization This book provides a comprehensive reference on emulsion polymerization methods,focusing on the fundamental mechanisms and kinetics of each process, as well as howthey can be applied to the manufacture of environmentally friendly polymeric materials. Topics covered include: Conventional emulsion polymerization Miniemulsion polymerization Microemulsion polymerization Industrial emulsion polymerization processes (primarily the semibatch and continuous reactions systems) The role of various colloidal phenomena in emulsion polymerization Important end-use properties of emulsion polymer (latex) products Information on industrial applications in paints, coatings, adhesives, paper and board, and more This is a hands-on reference for graduate students and professionals in polymerchemistry, chemical engineering, and materials science who are involved in researchon coatings, adhesives, rubber, latex, paints, finishes, and other materials that can becreated using various methods of emulsion polymerization.
Author: Mohamed S. El-Aasser
Publisher: Springer Science & Business Media
ISBN: 9400981147
Category : Science
Languages : en
Pages : 250
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Book Description
It is particularly appropriate that this symposium on the emulsion polymeriza tion of vinyl acetate was held in recognition of the industrial importance of poly(vinyl acetate) and vinyl acetate copolymers, and their rather unique properties among emulsion polymers in general. Poly( vinyl acetate) latexes were the first synthetic polymer latexes to be made on a commercial scale: their production using polyvinyl alcohol as emulsifier began in Germany during the mid-1930s and has continued to the present day, growing steadily with the years. Indeed, poly(vinyl acetate) latexes prepared with polyvinyl alcohol are still one of the mainstays of the adhesives industry. With the passing of time, however, vinyl acetate copolymers have been developed: copolymers with maleate esters such as dibutyl maleate, acrylate esters such as ethyl acrylate and butyl acrylate, versatic acid esters, and, more recently, ethylene. These versatile copolymers have found increasing use in more sophisticated adhesives with specialized properties, adhesives for clay coatings on paper, carpet backing, and interior and exterior paints. Thus more than 45 years after the first commercial production of vinyl acetate latexes, their use is still growing, both in actual quantities and different applications. The industrial importance of vinyl acetate latexes makes the mechanism and kinetics of their emulsion polymerization of practical as well as scientific interest.
Author: Dimiter N. Petsev
Publisher: Elsevier
ISBN: 0080472656
Category : Science
Languages : en
Pages : 781
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Book Description
Emulsions: Structure, Stability and Interactions is the perfect handbook for scientists looking to obtain up-to-date knowledge about the fundamentals of emulsion science, and those looking to familiarize themselves with the subject in greater detail. As a 'stand-alone' source of information, it is also ideal for solving the practical issues encountered daily in the field of emulsion science. While each chapter presents a concise review on a specific topic, the book offers a consistent presentation of the important physical concepts relevant to emulsions. Some of the topics covered include statistical mechanics of fluid interfaces, the structure of fluid interfaces determined by neutron scattering, hydrodynamic interactions and stability of emulsion films, theory of emulsion flocculation, coalescence kinetics of Brownian emulsions, and Brownian dynamics simulation of emulsion stability. - Full and comprehensive presentations - Rigorous approach to each topic, providing in-depth information - Acts as a 'stand-alone' source of information
Author: Jerôme Bibette
Publisher: Springer
ISBN: 3540708200
Category : Technology & Engineering
Languages : en
Pages : 148
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Book Description
Emulsions occur either as end products or during the processing of products in a huge range of areas including the food, agrochemical, pharmaceuticals, paints and oil industries. As end products, emulsions allow to avoid organic solvent in processing hydrophobic coatings. Emulsion technology is a suitable approach to vehicle viscous phases. It is also a remarkable mean of targeting actives or capturing specific species. The range of applications of emulsions progresses and their manufacturing becomes more and more sophisticated. Besides this broad domain of technological interest, emulsions are raising a variety of fundamental questions at the frontier between physic and chem istry. Indeed, as a class of soft colloidal materials, emulsions science is linked to various aspects of these disciplines: phase transitions, surface forces and wetting, metastability and hydrodynamic instabilities, mechanical properties and flow. The aim of this book is to review the main important concepts governing emulsion science. In Chapter 2, repulsive interactions between liquid films are discussed as well as adhesive interaction related to wetting. In Chap ter 3, consequences of weak and strong attractions are presented, related to the well accepted liquid solid transition analogy. In Chapter 4, the basics of both bulk compressibility and shear elasticity are presented, the role of disorder being the most important aspect of the elastic behavior of these soft systems. In Chapter 5 the central question of the emulsion lifetime related to metastability is discussed.
Author: K.L. Mittal
Publisher: Springer Science & Business Media
ISBN: 1461578809
Category : Psychology
Languages : en
Pages : 527
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Book Description
The 52nd Colloid and Surface Science Symposium of the Divis ion of Colloid and Surface Chemistry of the American Chemical Society was held in Knoxville, TN, June 12-14, 1978, and one of its Sections was devoted to the topic of Solution Chemistry of Surfactants. Although it was billed as the Section on Solution Chemistry of Surfactants, but it was indeed a veritable inter national symposium on this topic as 51 papers by about 100 con tributors from 12 countries were listed in the program. The present volume and its companion volume 2 document the proceedings of the above-mentioned Section on Solution Chemistry of Surfactants. In 1976 there was held an international symposium on Micellization, Solubilization and Microemulsions in Albany, l the proceedings of which have been chronicled in two volumes. A great deal of material dealing with micelles contributed by a legion of prominent researchers constitutes these volumes but a few subtopics were not adequately covered; so it was deemed appro priate to cover these topics as well as the recent progress in the general area of aggregation of surfactants in this Section. Also as it is the amphiphilicity or amphipathicity* of a surfact ant molecule which is responsible for both adsorption at inter faces and aggregation in solution, so it was considered quite apropos to include the topic of adsorption at interfaces in this Section. Concomitantly, the present volumes not only cover the aggregation phenomena but also the adsorption at interfaces.
