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Author: R. Cooks
Publisher: Springer Science & Business Media
ISBN: 1461339553
Category : Science
Languages : en
Pages : 467
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Book Description
R. G. Cooks This introduction has three purposes: (a) to summarize some of the chief features of energy spectrometry of ions and to sketch in a little of the background to this subject, (b) to present some simple facts about collision processes which one skilled in, say, mass spectrometry but innocent of any knowledge of bimolecular collisions might find of value, and (c) to indicate the scope and content of the volume. 1. The Subject This book takes as its subject, ion-molecule and ion-atom reactions occurring at high energies. It emphasizes the study of inelastic reactions at high energy through measurements of translational energy. The investiga tion of these reactions using other procedures has been important in the cases of the simpler systems. In particular, the emitted radiation has been investigated and this subject is therefore discussed where appropriate. For more complex species, however, there is little information available other than from energy spectra. The defining characteristic of the energy range of interest is that momentum transfer to the neutral target is negligible for small scattering angles. The result of this apparently bland condition is a welcome simplicity in the interpretation of the results of what appears to be developing into a R. G. Cooks • Department of Chemistry, Purdue University, West Lafayette, Indiana 47907. 2 Introduction unique form of spectroscopy. The names ion kinetic-energy spectrometry, translational energy spectrometry, collision spectroscopy, and energy-loss spectrometry have all been used to describe this subject (d. Section 5).
Author: R. Cooks
Publisher: Springer Science & Business Media
ISBN: 1461339553
Category : Science
Languages : en
Pages : 467
Get Book Here
Book Description
R. G. Cooks This introduction has three purposes: (a) to summarize some of the chief features of energy spectrometry of ions and to sketch in a little of the background to this subject, (b) to present some simple facts about collision processes which one skilled in, say, mass spectrometry but innocent of any knowledge of bimolecular collisions might find of value, and (c) to indicate the scope and content of the volume. 1. The Subject This book takes as its subject, ion-molecule and ion-atom reactions occurring at high energies. It emphasizes the study of inelastic reactions at high energy through measurements of translational energy. The investiga tion of these reactions using other procedures has been important in the cases of the simpler systems. In particular, the emitted radiation has been investigated and this subject is therefore discussed where appropriate. For more complex species, however, there is little information available other than from energy spectra. The defining characteristic of the energy range of interest is that momentum transfer to the neutral target is negligible for small scattering angles. The result of this apparently bland condition is a welcome simplicity in the interpretation of the results of what appears to be developing into a R. G. Cooks • Department of Chemistry, Purdue University, West Lafayette, Indiana 47907. 2 Introduction unique form of spectroscopy. The names ion kinetic-energy spectrometry, translational energy spectrometry, collision spectroscopy, and energy-loss spectrometry have all been used to describe this subject (d. Section 5).
Author: G.C. Tabisz
Publisher: Springer Science & Business Media
ISBN: 9401101833
Category : Science
Languages : en
Pages : 581
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Book Description
Collision-or interaction-induced spectroscopy refers to radiative transitions, which are forbidden in free atoms or molecules, but which occur in clusters of interacting atoms or molecules. The most common phenomena are induced absorption, in the infrared region, and induced light scattering, which involves inelastic scattering of visible laser light. The particle interactions giving rise to the necessary induced dipole moments and polarizabilities are modelled at long range by multipole expansions; at short range, electron overlap and exchange mechanisms come into play. Information on atomic and molecular interactions and dynamics in dense media on a picosecond timescale may be drawn from the spectra. Collision-induced absorption in the infrared was discovered at the University of Toronto in 1949 by Crawford, Welsh and Locke who studied liquid O and N. Through the 1950s and 1960s, 2 2 experimental elucidation of the phenomenon, particularly in gases, continued and theoretical underpinnings were established. In the late 1960s, the related phenomenon of collision-induced light scattering was first observed in compressed inert gases. In 1978, an 'Enrico Fermi' Summer School was held at Varenna, Italy, under the directorship of J. Van Kranendonk. The lectures, there, reviewed activity from the previous two decades, during which the approach to the subject had not changed greatly. In 1983, a highly successful NATO Advanced Research Workshop was held at Bonas, France, under the directorship of G. Birnbaum. An important outcome of that meeting was the demonstration of the maturity and sophistication of current experimental and theoretical techniques.
Author: Robert Graham Cooks
Publisher: Springer
ISBN: 9781461339571
Category : Science
Languages : en
Pages : 458
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Book Description
R. G. Cooks This introduction has three purposes: (a) to summarize some of the chief features of energy spectrometry of ions and to sketch in a little of the background to this subject, (b) to present some simple facts about collision processes which one skilled in, say, mass spectrometry but innocent of any knowledge of bimolecular collisions might find of value, and (c) to indicate the scope and content of the volume. 1. The Subject This book takes as its subject, ion-molecule and ion-atom reactions occurring at high energies. It emphasizes the study of inelastic reactions at high energy through measurements of translational energy. The investiga tion of these reactions using other procedures has been important in the cases of the simpler systems. In particular, the emitted radiation has been investigated and this subject is therefore discussed where appropriate. For more complex species, however, there is little information available other than from energy spectra. The defining characteristic of the energy range of interest is that momentum transfer to the neutral target is negligible for small scattering angles. The result of this apparently bland condition is a welcome simplicity in the interpretation of the results of what appears to be developing into a R. G. Cooks • Department of Chemistry, Purdue University, West Lafayette, Indiana 47907. 2 Introduction unique form of spectroscopy. The names ion kinetic-energy spectrometry, translational energy spectrometry, collision spectroscopy, and energy-loss spectrometry have all been used to describe this subject (d. Section 5).
Author: Wolfgang Demtröder
Publisher: Springer Science & Business Media
ISBN: 3662051559
Category : Science
Languages : en
Pages : 997
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Book Description
Keeping abreast of the latest techniques and applications, this new edition of the standard reference and graduate text on laser spectroscopy has been completely revised and expanded. While the general concept is unchanged, the new edition features a broad array of new material, e.g., frequency doubling in external cavities, reliable cw-parametric oscillators, tunable narrow-band UV sources, more sensitive detection techniques, tunable femtosecond and sub-femtosecond lasers (X-ray region and the attosecond range), control of atomic and molecular excitations, frequency combs able to synchronize independent femtosecond lasers, coherent matter waves, and still more applications in chemical analysis, medical diagnostics, and engineering.
Author:
Publisher:
ISBN:
Category : Mass spectrometry
Languages : en
Pages : 900
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Book Description
Author: R.G. Cooks
Publisher:
ISBN: 9781461339564
Category :
Languages : en
Pages : 476
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Book Description
Author:
Publisher:
ISBN:
Category : Mass spectrometry
Languages : en
Pages : 626
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Book Description
Author: Wolfgang Demtröder
Publisher: Springer
ISBN: 3662446413
Category : Science
Languages : en
Pages : 773
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Book Description
Keeping abreast of the latest techniques and applications, this new edition of the standard reference and graduate text on laser spectroscopy has been completely revised and expanded. While the general concept is unchanged, the new edition features a broad array of new material, e.g., ultrafast lasers (atto- and femto-second lasers), coherent matter waves, Doppler-free Fourier spectroscopy, interference spectroscopy, quantum optics and gravitational waves and still more applications in chemical analysis, medical diagnostics, and engineering.
Author: James Russell Veale
Publisher:
ISBN:
Category :
Languages : en
Pages : 340
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Book Description
Author: Jean-Michel Hartmann
Publisher: Elsevier
ISBN: 0128227362
Category : Science
Languages : en
Pages : 577
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Book Description
Gas phase molecular spectroscopy is a powerful tool for obtaining information on the geometry and internal structure of isolated molecules and their interactions with others. It enables the understanding and description, through measurements and modeling, of the influence of pressure on light absorption, emission, and scattering by gas molecules, which must be taken into account for the correct analysis and prediction of the resulting spectra. Collisional Effects on Molecular Spectra: Laboratory Experiments and Models, Consequences for Applications, Second Edition provides an updated review of current experimental techniques, theoretical knowledge, and practical applications. After an introduction to collisional effects on molecular spectra, the book moves on by taking a threefold approach: it highlights key models, reviews available data, and discusses the consequences for applications. These include areas such as heat transfer, remote sensing, optical sounding, metrology, probing of gas media, and climate predictions. This second edition also contains, with respect to the first one, significant amounts of new information, including 23 figures, 8 tables, and around 700 references.Drawing on the extensive experience of its expert authors, Collisional Effects on Molecular Spectra: Laboratory Experiments and Models, Consequences for Applications, Second Edition, is a valuable guide for all those involved with sourcing, researching, interpreting, or applying gas phase molecular spectroscopy techniques across a range of fields. Provides updated information on the latest advances in the field, including isolated line shapes, line-broadening and -shifting, line-mixing, the far wings and associated continua, and collision-induced absorption Reviews recently developed experimental techniques of high accuracy and sensitivity Highlights the latest practical applications in areas such as metrology, probing of gas media, and climate prediction
