Chemical Electrostatics

Chemical Electrostatics PDF Author: Fernando Galembeck
Publisher: Springer
ISBN: 3319523740
Category : Science
Languages : en
Pages : 237

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Book Description
This book provides new clues for understanding electrostatic charging in solids and liquids, resulting from the surge of research in this active area of science that is taking place since the 1990's but is still largely unknown to most researchers, lecturers and engineers. Written by a leading researcher in this field, this book describes the formation and properties of the Earth capacitor, the production of environmental electricity and its effect on natural and anthropic systems and examines many situations in which water may play a decisive role in electrostatic behavior. The authors present an informed critique of the long-held assumption that pure substances should be electroneutral. In this regard, the authors show that charge partition and accumulation is expected considering the electrochemical potential under non-zero electrostatic potential, which prevails at Earth surface. This book provides conceptual tools to guide the reader through the complexities and consequences of electrostatic phenomena while covering exciting current topics such as energy scavenging from the environment, electrostatic based green production, energy-saving processes, electrochemistry at the solid-gas interface, therapeutic electrostatic treatments, applications in sanitation and pest control and control of atmospheric electricity and its use in climate engineering.

Chemical Electrostatics

Chemical Electrostatics PDF Author: Fernando Galembeck
Publisher: Springer
ISBN: 3319523740
Category : Science
Languages : en
Pages : 237

Get Book Here

Book Description
This book provides new clues for understanding electrostatic charging in solids and liquids, resulting from the surge of research in this active area of science that is taking place since the 1990's but is still largely unknown to most researchers, lecturers and engineers. Written by a leading researcher in this field, this book describes the formation and properties of the Earth capacitor, the production of environmental electricity and its effect on natural and anthropic systems and examines many situations in which water may play a decisive role in electrostatic behavior. The authors present an informed critique of the long-held assumption that pure substances should be electroneutral. In this regard, the authors show that charge partition and accumulation is expected considering the electrochemical potential under non-zero electrostatic potential, which prevails at Earth surface. This book provides conceptual tools to guide the reader through the complexities and consequences of electrostatic phenomena while covering exciting current topics such as energy scavenging from the environment, electrostatic based green production, energy-saving processes, electrochemistry at the solid-gas interface, therapeutic electrostatic treatments, applications in sanitation and pest control and control of atmospheric electricity and its use in climate engineering.

Molecular Electrostatic Potentials

Molecular Electrostatic Potentials PDF Author: J.S. Murray
Publisher: Elsevier
ISBN: 0080536859
Category : Science
Languages : en
Pages : 681

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Book Description
Over the past 25 years, the molecular electrostatic potential has become firmly established as an effective guide to molecular interactions. With the recent advances in computational technology, it is currently being applied to a variety of important chemical and biological systems. Its range of applicability has expanded from primarily a focus on sites for electrophilic and nucleophilic attack to now include solvent effects, studies of zeolite, molecular cluster and crystal behavior, and the correlation and prediction of a wide range of macroscopic properties. Moreover, the increasing prominence of density functional theory has raised the molecular electrostatic potential to a new stature on a more fundamental conceptual level. It is rigorously defined in terms of the electron density, and has very interesting topological characteristics since it explicitly reflects opposing contributions from the nuclei and the electrons.This volume opens with a survey chapter by one of the original pioneers of the use of the electrostatic potential in studies of chemical reactivity, Jacopo Tomasi. Though the flow of the succeeding chapters is not stringently defined, the overall trend is that the emphasis changes gradually from methodology to applications. Chapters discussing more theoretical topics are placed near the end. Readers will find the wide variety of topics provided by an international group of authors both convincing and useful.

Electrostatics of Atoms and Molecules

Electrostatics of Atoms and Molecules PDF Author: Shridhar R. Gadre
Publisher: Universities Press
ISBN: 9788173712968
Category : Electrostatics
Languages : en
Pages : 158

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Book Description
This book introduces the subject of molecular electrostatics to postgraduate students, teachers and young researchers in chemistry, physics and biology. It discusses rigorous as well as applied aspects of the molecular electrostatic potential (MESP) and provides an essence of relevant mathematical arguments, without going into detailed derivations. A number of color illustrations highlight the salient features of MESP.

Electrostatics at the Molecular Level

Electrostatics at the Molecular Level PDF Author: Ulrich Zürcher
Publisher: Morgan & Claypool Publishers
ISBN: 1643271865
Category : Science
Languages : en
Pages : 114

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Book Description
Electrostatic forces are essential for the hierarchical structure of matter: electrons are bound to the atomic nucleus by electrostatic forces; atoms carry (partial) charges and ions with opposite charges attract and form (chemical) bonds. Small residual electrostatic forces between molecules allow them to form macroscopic structures such as crystals. Electrostatic interactions explain pseudo-forces used in popular computer programs used to model properties of atoms, molecules, and proteins. By beginning with the basics and then diving deeper into the topic, this book aims to familiarize the reader with electrostatic forces at the atomic and molecular level.

Powder Handling and Electrostatics

Powder Handling and Electrostatics PDF Author: Thomas B. Jones
Publisher: CRC Press
ISBN: 9780873714884
Category : Science
Languages : en
Pages : 118

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Book Description
The subject of this manual is safe practice for avoiding electrostatic discharge hazards in the manufacturing and processing of chemical and plastic powders. It is written with the practicing engineer and plant technician in mind. Practical information to enhance the process safety is provided in straightforward terms. The manual describes the basic phenomena of powder electrostatics, giving special emphasis to polymer powders. The identified types of electrostatic discharges are discussed and explanations of the conditions that favor or inhibit each type are given. A number of industrial incidents where ESD-induced dust ignitions occurred are reviewed, with the authors contributing their own views on causes and preventive measures. The important quantitative measures of electrostatic hazards are identified, along with the methods needed to perform meaningful measurements. Concrete recommendations, based on the authors' experience, are provided in the form of a list of "Do's" and "Don'ts" applicable in the plant environment. Finally, appendices provide a wealth of useful background data plus an informative "Q and A" section covering practical engineering issues. This manual will be extremely useful to chemical plant engineers, operating and maintenance personnel, safety engineers, processing plant engineers, design engineers, and consultants, as well as persons in the chemical, pharmaceutical, plastic, and food handling industries.

Chemical Applications of Atomic and Molecular Electrostatic Potentials

Chemical Applications of Atomic and Molecular Electrostatic Potentials PDF Author: Peter Politzer
Publisher: Springer Science & Business Media
ISBN: 147579634X
Category : Science
Languages : en
Pages : 473

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Book Description
On March 26-27, 1980, a symposium organized by one of us (P. P. ) was held at the l79th American Chemical Society National ~1eeting in Houston, Texas, under the sponsorship of the Theoretical Chemistry Subdivision of the Division of Physical Chemistry. The symposium was entitled "The Role of the Electrostatic Potential in Chemistry," and it served as a stimulus for this book. The original scope and coverage have been broadened, however; included here, in addition to contributions from the eleven invited symposium speakers and two of the poster-session participants, are four papers that were specially invited for this book. Furthermore, several authors have taken this opportunity to present at least partial reviews of the areas being discussed. Most of the manuscripts were completed in the late spring and early summer of 1980. We hope that this book will achieve two goals: First, we are trying to provide an overall picture, including recent advances, of current chemical research, both fundamental and applied, involving the electrostatic potential. Second, we want to convey an appreci ation of both the powers and also the limitations of the electro static potential approach. In order to achieve these goals, we have selected contributors whose research areas provide a very broad coverage of the field. Throughout the book, we have used a. u.

Electrostatic Hazards

Electrostatic Hazards PDF Author: Günter Luttgens
Publisher: Elsevier
ISBN: 0080505406
Category : Science
Languages : en
Pages : 179

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Book Description
In the US, UK and Europe there is in excess of one notifiable dust or electrostatic explosion every day of the year. This clearly makes the hazards associated with the handling of materials subject to either cause or react to electrostatic discharge of vital importance to anyone associated with their handling or industrial bulk use. This book provides a comprehensive guide to the dangers of static electricity and how to avoid them. It will prove invaluable to safety managers and professionals, as well as all personnel involved in the activities concerned, in the chemical, agricultural, pharmaceutical and petrochemical process industries. Electrostatic Hazards makes extended use of case studies to illustrate the principles being expounded, thereby making it far more open, accessible and attractive to the practitioner in industry than the highly theoretical texts which are also available. The authors have many years' experience in the area behind them, including the professional teaching of the content provided here. Günter Lüttgens is a widely acknowledged consultant who travels Europe providing training to major industrial corporations on this subject, whilst Norman Wilson practices what is written here in his professional capacity with the British Textile Technology Group. - Extended use of case studies to illustrate the principles.This makes the book far more open, accessible and attractive to the practitioner in industry than the highly theoretical texts also available - Authors have many years experience in the area - Both authors have been widely published with considerable previous book-writing experience

Electrostatics of Soft and Disordered Matter

Electrostatics of Soft and Disordered Matter PDF Author: David S. Dean
Publisher: CRC Press
ISBN: 9814411868
Category : Science
Languages : en
Pages : 434

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Book Description
Recently, there has been a surge of activity to elucidate the behavior of highly charged soft matter and Coulomb fluids in general. Such systems are ubiquitous, especially in biological matter where the length scale and the strength of the interaction between highly charged biomolecules are governed by strong electrostatic effects. Several interest

Biophysical Chemistry

Biophysical Chemistry PDF Author: John T. Edsall
Publisher: Academic Press
ISBN: 1483270580
Category : Science
Languages : en
Pages : 716

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Book Description
Biophysical Chemistry, Volume I: Thermodynamics, Electrostatics, and the Biological Significance of the Properties of Matter focuses on the biological aspects of the properties of matter, putting emphasis on the chemical elements, water and carbon dioxide, complex molecules, and proteins. The publication first elaborates on biochemistry and geochemistry, water and its biological significance, and the problems of protein structure. Discussions focus on the number of peptide chains in the molecule and nature of terminal groups, latent heat of fusion, characteristics of the amino acids derived from proteins, expansion of water in freezing, and the relative abundance of chemical elements in the universe. The text then takes a look at thermodynamics and the application to polar molecules and ionic solutions of electrostatics, including free energy of a charged sphere, image charges, salting-out effect, expressions for the change of fundamental thermodynamic functions, and chemical potentials. The book examines the conductivity of electrolytes, acid-base equilibria, and polybasic acids, bases, and ampholytes, including proteins. Topics include ionization of cysteine, isoelectric points of polyvalent ampholytes, hemoglobin, nature of acids and bases, measurement of conductivity, electrolytes as conductors, and the moving boundary method of determining transference numbers. The manuscript is a dependable reference for chemists and researchers interested in thermodynamics, electrostatics, and the biological value of the properties of matter.

The Chemical Bond in Inorganic Chemistry

The Chemical Bond in Inorganic Chemistry PDF Author: Ian David Brown
Publisher: Oxford University Press
ISBN: 0198742959
Category : Science
Languages : en
Pages : 331

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Book Description
The bond valence model, a description of acid-base bonding, is widely used for analysing and modelling the structures and properties of solids and liquids. Unlike other models of inorganic chemical bonding, the bond valence model is simple, intuitive, and predictive, and is accessible to anyone with a pocket calculator and a secondary school command of chemistry and physics. This new edition of 'The Chemical Bond in Inorganic Chemistry: The Bond Valence Model' shows how chemical properties arise naturally from the conflict between the constraints of chemistry and those of three-dimensional space. The book derives the rules of the bond valence model, as well as those of the traditional covalent, ionic and popular VSEPR models, by identifying the chemical bond with the electrostatic flux linking the bonded atoms. Most of the new edition is devoted to showing how to apply these ideas to real materials including crystals, liquids, glasses and surfaces. The work includes detailed examples of applications, and the final chapter explores the relationship between the flux and quantum theories of the bond.