Chemical Complexity

Chemical Complexity PDF Author: Alexander S. Mikhailov
Publisher: Springer
ISBN: 3319573772
Category : Science
Languages : en
Pages : 209

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Book Description
This book provides an outline of theoretical concepts and their experimental verification in studies of self-organization phenomena in chemical systems, as they emerged in the mid-20th century and have evolved since. Presenting essays on selected topics, it was prepared by authors who have made profound contributions to the field. Traditionally, physical chemistry has been concerned with interactions between atoms and molecules that produce a variety of equilibrium structures - or the 'dead' order - in a stationary state. But biological cells exhibit a different 'living' kind of order, prompting E. Schrödinger to pose his famous question “What is life?” in 1943. Through an unprecedented theoretical and experimental development, it was later revealed that biological self-organization phenomena are in complete agreement with the laws of physics, once they are applied to a special class of thermodynamically open systems and non-equilibrium states. This knowledge has in turn led to the design and synthesis of simple inorganic systems capable of self-organization effects. These artificial 'living organisms' are able to operate on macroscopic to microscopic scales, even down to single-molecule machines. In the future, such research could provide a basis for a technological breakthrough, comparable in its impact with the invention of lasers and semiconductors. Its results can be used to control natural chemical processes, and to design artificial complex chemical processes with various functionalities. The book offers an extensive discussion of the history of research on complex chemical systems and its future prospects.

Chemical Complexity

Chemical Complexity PDF Author: Alexander S. Mikhailov
Publisher: Springer
ISBN: 3319573772
Category : Science
Languages : en
Pages : 209

Get Book Here

Book Description
This book provides an outline of theoretical concepts and their experimental verification in studies of self-organization phenomena in chemical systems, as they emerged in the mid-20th century and have evolved since. Presenting essays on selected topics, it was prepared by authors who have made profound contributions to the field. Traditionally, physical chemistry has been concerned with interactions between atoms and molecules that produce a variety of equilibrium structures - or the 'dead' order - in a stationary state. But biological cells exhibit a different 'living' kind of order, prompting E. Schrödinger to pose his famous question “What is life?” in 1943. Through an unprecedented theoretical and experimental development, it was later revealed that biological self-organization phenomena are in complete agreement with the laws of physics, once they are applied to a special class of thermodynamically open systems and non-equilibrium states. This knowledge has in turn led to the design and synthesis of simple inorganic systems capable of self-organization effects. These artificial 'living organisms' are able to operate on macroscopic to microscopic scales, even down to single-molecule machines. In the future, such research could provide a basis for a technological breakthrough, comparable in its impact with the invention of lasers and semiconductors. Its results can be used to control natural chemical processes, and to design artificial complex chemical processes with various functionalities. The book offers an extensive discussion of the history of research on complex chemical systems and its future prospects.

Engineering of Chemical Complexity

Engineering of Chemical Complexity PDF Author: Alexander S. Mikhailov
Publisher: World Scientific
ISBN: 9814390453
Category : Mathematics
Languages : en
Pages : 413

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Book Description
This review volume, co-edited by Nobel laureate G Ertl, provides a broad overview on current studies in the understanding of design and control of complex chemical systems of various origins, on scales ranging from single molecules and nano-phenomena to macroscopic chemical reactors. Self-organizational behavior and the emergence of coherent collective dynamics in reaction diffusion systems, reactive soft matter and chemical networks are covered. Special attention is paid to the applications in molecular cell biology and to the problems of biological evolution, synthetic biology and design of artificial living cells. Starting with a detailed introduction on the history of research on complex chemical systems, its current state of the art and perspectives, the book comprises 19 chapters that survey the current progress in particular research fields. The reviews, prepared by leading international experts, yield together a fascinating picture of a rapidly developing research discipline that brings chemical engineering to new frontiers.

Complexity in Chemistry, Biology, and Ecology

Complexity in Chemistry, Biology, and Ecology PDF Author: Danail D. Bonchev
Publisher: Springer Science & Business Media
ISBN: 038725871X
Category : Science
Languages : en
Pages : 359

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Book Description
The book offers new concepts and ideas that broaden reader’s perception of modern science. Internationally established experts present the inspiring new science of complexity, which discovers new general laws covering wide range of science areas. The book offers a broader view on complexity based on the expertise of the related areas of chemistry, biochemistry, biology, ecology, and physics. Contains methodologies for assessing the complexity of systems that can be directly applied to proteomics and genomics, and network analysis in biology, medicine, and ecology.

Chemical Complexity via Simple Models

Chemical Complexity via Simple Models PDF Author: Valeriy I. Bykov
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110464942
Category : Science
Languages : en
Pages : 374

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Book Description
This book is focused on mathematical modelling of chemical kinetics. The authors present the classification of basic models of chemical kinetics, thermokinetics and macrokinetics, as well as their application for the most important chemical transformations, such as combustion and catalysis. Readers will find a detailed description and analysis of different mathematical instruments which can be applied for simulation of reaction dynamics.

Kinetics of Chemical Reactions

Kinetics of Chemical Reactions PDF Author: Guy B. Marin
Publisher: John Wiley & Sons
ISBN: 3527342958
Category : Science
Languages : en
Pages : 462

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Book Description
This second, extended and updated edition presents the current state of kinetics of chemical reactions, combining basic knowledge with results recently obtained at the frontier of science. Special attention is paid to the problem of the chemical reaction complexity with theoretical and methodological concepts illustrated throughout by numerous examples taken from heterogeneous catalysis combustion and enzyme processes. Of great interest to graduate students in both chemistry and chemical engineering.

From Strange Simplicity to Complex Familiarity

From Strange Simplicity to Complex Familiarity PDF Author: Manfred Eigen
Publisher: OUP Oxford
ISBN: 0191633070
Category : Science
Languages : en
Pages : 1583

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Book Description
This book presents a vivid argument for the almost lost idea of a unity of all natural sciences. It starts with the "strange" physics of matter, including particle physics, atomic physics and quantum mechanics, cosmology, relativity and their consequences (Chapter I), and it continues by describing the properties of material systems that are best understood by statistical and phase-space concepts (Chapter II). These lead to entropy and to the classical picture of quantitative information, initially devoid of value and meaning (Chapter III). Finally, "information space" and dynamics within it are introduced as a basis for semantics (Chapter IV), leading to an exploration of life and thought as new problems in physics (Chapter V). Dynamic equations - again of a strange (but very general) nature - bring about the complex familiarity of the world we live in. Surprising new results in the life sciences open our eyes to the richness of physical thought, and they show us what can and what cannot be explained by a Darwinian approach. The abstract physical approach is applicable to the origins of life, of meaningful information and even of our universe.

Computational Aspects for Large Chemical Systems

Computational Aspects for Large Chemical Systems PDF Author: E. Clementi
Publisher: Springer Science & Business Media
ISBN: 3642931448
Category : Science
Languages : en
Pages : 191

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Book Description
1. 1 STATEMENT OF THE PROBLEM Quantum chemistry judged not from the ever present possibility of unex pected developments but on the basis of the achievements in the last fifty years, is predominantly limited to attempts to solve for the energy and expectation values of wave functions representing, in the limit, an exact solution to the Schroedinger equation. Because of well-known dif ficulties in system with more than about 50 electrons, the adopted ap proximations are generally rather crude. As examples of quantum chemical approximations we mention the total or partial neglects of electron correlation, the neglect of relativistic effects, the use of subminimal basis sets, the still present neglect of inner-core electrons in semi-empirical methods, the acceptance of the Born-Oppenheimer approximations, and so on. In general, the larger the system, in terms of the number of electrons, the cruder the approxima tion. In a way, the present status of quantum chemistry might appear as nearly paradoxical. Indeed, for small systems, where very accurate ex periments are often available, and therefore, there is not a great need to obtain (from quantum chemistry) predictions of new data but rather ,a theoretical interpretation of the existing data, we find increasi~gly powerful and reliable quantum chemical methods and techniques.

Biological Complexity and the Dynamics of Life Processes

Biological Complexity and the Dynamics of Life Processes PDF Author: J. Ricard
Publisher: Elsevier
ISBN: 0080860958
Category : Science
Languages : en
Pages : 369

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Book Description
The aim of this book is to show how supramolecular complexity of cell organization can dramatically alter the functions of individual macromolecules within a cell. The emergence of new functions which appear as a consequence of supramolecular complexity, is explained in terms of physical chemistry. The book is interdisciplinary, at the border between cell biochemistry, physics and physical chemistry. This interdisciplinarity does not result in the use of physical techniques but from the use of physical concepts to study biological problems. In the domain of complexity studies, most works are purely theoretical or based on computer simulation. The present book is partly theoretical, partly experimental and theory is always based on experimental results. Moreover, the book encompasses in a unified manner the dynamic aspects of many different biological fields ranging from dynamics to pattern emergence in a young embryo. The volume puts emphasis on dynamic physical studies of biological events. It also develops, in a unified perspective, this new interdisciplinary approach of various important problems of cell biology and chemistry, ranging from enzyme dynamics to pattern formation during embryo development, thus paving the way to what may become a central issue of future biology.

Diversity and Complexity

Diversity and Complexity PDF Author: Scott E. Page
Publisher: Princeton University Press
ISBN: 1400835143
Category : Political Science
Languages : en
Pages : 304

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Book Description
This book provides an introduction to the role of diversity in complex adaptive systems. A complex system--such as an economy or a tropical ecosystem--consists of interacting adaptive entities that produce dynamic patterns and structures. Diversity plays a different role in a complex system than it does in an equilibrium system, where it often merely produces variation around the mean for performance measures. In complex adaptive systems, diversity makes fundamental contributions to system performance. Scott Page gives a concise primer on how diversity happens, how it is maintained, and how it affects complex systems. He explains how diversity underpins system level robustness, allowing for multiple responses to external shocks and internal adaptations; how it provides the seeds for large events by creating outliers that fuel tipping points; and how it drives novelty and innovation. Page looks at the different kinds of diversity--variations within and across types, and distinct community compositions and interaction structures--and covers the evolution of diversity within complex systems and the factors that determine the amount of maintained diversity within a system. Provides a concise and accessible introduction Shows how diversity underpins robustness and fuels tipping points Covers all types of diversity The essential primer on diversity in complex adaptive systems

The Chemistry of Cosmic

The Chemistry of Cosmic PDF Author: David A Williams
Publisher: Royal Society of Chemistry
ISBN: 1782620478
Category : Science
Languages : en
Pages : 320

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Book Description
This is the first book devoted to a study of the chemistry of cosmic dust, presenting current thinking on the subject distilled from many publications in surface and solid-state science, and in astronomy.