Catalytic Arylation Methods

Catalytic Arylation Methods PDF Author: Anthony J. Burke
Publisher: John Wiley & Sons
ISBN: 3527335188
Category : Science
Languages : en
Pages : 530

Get Book

Book Description
This "hands-on" approach to the topic of arylation consolidates the body of key research over the last ten years (and up to around 2014) on various catalytic methods which involve an arylation process. Clearly structured, the chapters in this one-stop resource are arranged according to the reaction type, and focus on novel, efficient and sustainable processes, rather than the well-known and established cross-coupling methods. The entire contents are written by two authors with academic and industrial expertise to ensure consistent coverage of the latest developments in the field, as well as industrial applications, such as C-H activation, iron and gold-catalyzed coupling reactions, cycloadditions or novel methodologies using arylboron reagents. A cross-section of relevant tried-and-tested experimental protocols is included at the end of each chapter for putting into immediate practice, along with patent literature. Due to its emphasis on efficient, "green" methods and industrial applications of the products concerned, this interdisciplinary text will be essential reading for synthetic chemists in both academia and industry, especially in medicinal and process chemistry.

Catalytic Arylation Methods

Catalytic Arylation Methods PDF Author: Anthony J. Burke
Publisher: John Wiley & Sons
ISBN: 3527335188
Category : Science
Languages : en
Pages : 530

Get Book

Book Description
This "hands-on" approach to the topic of arylation consolidates the body of key research over the last ten years (and up to around 2014) on various catalytic methods which involve an arylation process. Clearly structured, the chapters in this one-stop resource are arranged according to the reaction type, and focus on novel, efficient and sustainable processes, rather than the well-known and established cross-coupling methods. The entire contents are written by two authors with academic and industrial expertise to ensure consistent coverage of the latest developments in the field, as well as industrial applications, such as C-H activation, iron and gold-catalyzed coupling reactions, cycloadditions or novel methodologies using arylboron reagents. A cross-section of relevant tried-and-tested experimental protocols is included at the end of each chapter for putting into immediate practice, along with patent literature. Due to its emphasis on efficient, "green" methods and industrial applications of the products concerned, this interdisciplinary text will be essential reading for synthetic chemists in both academia and industry, especially in medicinal and process chemistry.

Modern Arylation Methods

Modern Arylation Methods PDF Author: Lutz Ackermann
Publisher: John Wiley & Sons
ISBN: 3527627332
Category : Science
Languages : en
Pages : 561

Get Book

Book Description
Today, arylation methods are belonging to the most important reaction types in organic synthesis. Lutz Ackermann, a young and ambitious professor has gathered a number of top international authors to present the first comprehensive book on the topic. Starting from a historical review, the book covers hot topics like Palladium-catalyzed arylation of N-H and alpha-C-H-acidic Bonds, Copper-catalyzed arylation of N-H and O-H Bonds, direct arylation reactions, carbanion aromatic synthesis, arylation reactions of alkenes, alkynes and much more. This compact source of high quality information is indispensable to synthetic chemists and those working in the pharmaceutical and chemical industry.

Development of Selective and Catalytic Arylation Methods for Sp2 and Sp3 C-H Bonds in Complex Organic Molecules

Development of Selective and Catalytic Arylation Methods for Sp2 and Sp3 C-H Bonds in Complex Organic Molecules PDF Author: Bengü Sezen
Publisher:
ISBN:
Category :
Languages : en
Pages : 926

Get Book

Book Description


Novel Methods for Catalytic Asymmetric Arylation

Novel Methods for Catalytic Asymmetric Arylation PDF Author: Alice Elizabeth Williamson
Publisher:
ISBN:
Category :
Languages : en
Pages :

Get Book

Book Description


Palladacycles

Palladacycles PDF Author: Anant Kapdi
Publisher: Elsevier
ISBN: 9780128155059
Category : Science
Languages : en
Pages : 0

Get Book

Book Description
Palladacycles: Catalysis and Beyond provides an overview of recent research in palladacycles in catalysis for cross-coupling and similar reactions. In the quest for developing highly efficient and robust palladium-based catalysts for C-C bond formation via cross-coupling reactions, palladacycles have played a significant role. In recent years, they have found a wide variety of applications, ranging from catalysts for cross-coupling and related reactions, to their more recent application as anticancer agents. This book explores early examples of the use of palladacyclic complexes in catalysis employing azobenzene and hydrazobenzene as coordinating ligands. Its applications in processes such as selective reduction of alkenes, alkynes, or nitroalkanes are also covered. Palladacycles: Catalysis and Beyond reveals the tremendous advances that have taken place in the potential applications of palladacycles as versatile catalysts in academia and industry. It is a valuable resource for synthetic chemists, organometallic chemists, and chemical biologists.

Hypervalent Iodine in Organic Synthesis

Hypervalent Iodine in Organic Synthesis PDF Author: A. Varvoglis
Publisher: Academic Press
ISBN: 0080534368
Category : Science
Languages : en
Pages : 245

Get Book

Book Description
This book describes the fascinating chemistry of the many kinds of organic compounds of hypervalent iodine. Each chapter deals with a particular iodine compound or families of compounds which have been used as reagents in a plethora of useful transformations. These include assorted oxidation, such as with the precious Dess-Martin reagent as well as with a wide range of further reactions. Prominent features of hypervalent iodine reagents derived from iodobenzene are: ready availability, operational simplicity, mild reaction conditions, and high efficiency. They are environmentally safe and can be recycled. New species may be easily prepared by introducing substituents in the benzene ring or changing the ligand attached to iodine. Their combination with other reagents broadens considerably their synthetic potential. Today, no synthetic chemist can afford to ignore the valuable hypervalentiodine reagents. Features up-to-date coverage of a wide range of topics Includes many tables featuring a diversity of reactivity, and a comprehensive index Acts as a comprehensive, up-to-date reference on all aspects of hypervalent iodine chemistry Contains a section on unusual efficiency of hypervalent iodine reactions

Catalytic Methods in Asymmetric Synthesis

Catalytic Methods in Asymmetric Synthesis PDF Author: Michelangelo Gruttadauria
Publisher: John Wiley & Sons
ISBN: 1118087984
Category : Science
Languages : en
Pages : 721

Get Book

Book Description
This book covers advances in the methods of catalytic asymmetric synthesis and their applications. Coverage moves from new materials and technologies to homogeneous metal-free catalysts and homogeneous metal catalysts. The applications of several methodologies for the synthesis of biologically active molecules are discussed. Part I addresses recent advances in new materials and technologies such as supported catalysts, supports, self-supported catalysts, chiral ionic liquids, supercritical fluids, flow reactors and microwaves related to asymmetric catalysis. Part II covers advances and milestones in organocatalytic, enzymatic and metal-based mediated asymmetric synthesis, including applications for the synthesis of biologically active molecules. Written by leading international experts, this book consists of 16 chapters with 2000 References and illustrations of 560 schemes and figures.

Comprehensive Heterocyclic Chemistry IV

Comprehensive Heterocyclic Chemistry IV PDF Author: David St. Clair Black
Publisher:
ISBN: 9780323912679
Category : Heterocyclic chemistry
Languages : en
Pages : 0

Get Book

Book Description


Synthetic Methods for Conjugated Polymer and Carbon Materials

Synthetic Methods for Conjugated Polymer and Carbon Materials PDF Author: Mario Leclerc
Publisher: John Wiley & Sons
ISBN: 3527339981
Category : Technology & Engineering
Languages : en
Pages : 312

Get Book

Book Description
A concise and practical overview of the most important modern synthetic aspects of conjugated polymers and carbon materials, including their properties and applications. Well structured, this book summarizes recent achievements, outlines the current state and reviews research trends. As such, a wide variety of polymerization techniques are included on both a strategic as well as a practical level, including Stille, Suzuki , and direct (hetero)arylation polymerizations. Furthermore, it covers various carbon-rich materials, such as graphene and carbon nanotubes, followed by a look at how the different synthetic pathways and strategies influence their final properties, for example, for use in organic electronic devices. The whole is rounded off with a discussion of future technology advances. An essential reference for newcomers as well as experienced researchers in the field.

Science of Synthesis: Catalytic Transformations via C-H Activation Vol. 1

Science of Synthesis: Catalytic Transformations via C-H Activation Vol. 1 PDF Author: Jin-Quan Yu
Publisher: Thieme
ISBN: 3131766816
Category : Science
Languages : en
Pages : 756

Get Book

Book Description
The reference work Science of Synthesis: Catalytic Transformations via C-H Activation covers the state of the art in C-H activation chemistry. Experts in the field present the best synthetic methods including typical or general experimental procedures. As such, this two volume set can serve as both a basis for the practical application of the techniques discussed, and as an educational resource to lay the foundations for future research. Volume 1 concerns the formation of C-C bonds by both arene and hetarene C-H activation. For the arenes the material is subdivided into arylation (using palladium(0), palladium(II)/palladium(IV), palladium(II), and ruthenium(II) catalysts), vinylation (using various palladium and ruthenium(III) catalysts), and alkylation (using various metal catalysts in combination with either functionalized alkanes or alkenes). For the hetarenes, the related coupling strategies are covered as a single topic using a variety of metal catalysts and coupling partners.