Author: P. Alexandridis
Publisher: Elsevier
ISBN: 0080527108
Category : Science
Languages : en
Pages : 449
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Book Description
It is the belief of the editors of this book that the recognition of block copolymers as being amphiphilic molecules and sharing common features with other well-studied amphiphiles will prove beneficial to both the surfactant and the polymer communities. An aim of this book is to bridge the two communities and cross-fertilise the different fields. To this end, leading researchers in the field of amphiphilic block copolymer self-assembly, some having a background in surfactant chemistry, and others with polymer physics roots, have agreed to join forces and contribute to this book.The book consists of four entities. The first part discusses theoretical considerations behind the block copolymer self-assembly in solution and in the melt. The second part provides case studies of self-assembly in different classes of block copolymers (e.g., polyethers, polyelectrolytes) and in different environments (e.g., in water, in non-aqueous solvents, or in the absence of solvents). The third part presents experimental tools, ranging from static (e.g., small angle neutron scattering) to dynamic (e.g., rheology), which can prove valuable in the characterization of block copolymer self-assemblies. The fourth part offers a sampling of current applications of block copolymers in, e.g., formulations, pharmaceutics, and separations, applications which are based on the unique self-assembly properties of block copolymers.
Author: Ian W. Hamley
Publisher: John Wiley & Sons
ISBN: 0470016973
Category : Technology & Engineering
Languages : en
Pages : 300
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Book Description
This unique text discusses the solution self-assembly of block copolymers and covers all aspects from basic physical chemistry to applications in soft nanotechnology. Recent advances have enabled the preparation of new materials with novel self-assembling structures, functionality and responsiveness and there have also been concomitant advances in theory and modelling. The present text covers the principles of self-assembly in both dilute and concentrated solution, for example micellization and mesophase formation, etc., in chapters 2 and 3 respectively. Chapter 4 covers polyelectrolyte block copolymers - these materials are attracting significant attention from researchers and a solid basis for understanding their physical chemistry is emerging, and this is discussed. The next chapter discusses adsorption of block copolymers from solution at liquid and solid interfaces. The concluding chapter presents a discussion of selected applications, focussing on several important new concepts. The book is aimed at researchers in polymer science as well as industrial scientists involved in the polymer and coatings industries. It will also be of interest to scientists working in soft matter self-assembly and self-organizing polymers.
Author: George Zhao
Publisher: John Wiley & Sons
ISBN: 3527828737
Category : Technology & Engineering
Languages : en
Pages : 690
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Book Description
A comprehensive resource for new and veteran researchers in the field of self-assembling and functional materials In Functional Materials from Colloidal Self-assembly, a pair of distinguished researchers delivers a thorough overview of how the colloidal self-assembly approach can enable the design and fabrication of several functional materials and devices. Among other topics, the book explores the foundations of self-assembly in different systems, nucleation, the growth of nanoparticles, self-assembly of colloidal microspheres for photonic crystals and devices, and the self-assembly of amphiphilic molecules as a template for mesoporous materials. The authors also discuss the self-assembly of biomolecules, superstructures from self-assembly, architectures from self-assembly, and the applications of self-assembled nanostructures. Functional Materials from Colloidal Self-assembly provides a balanced approach to the theoretical background and applications of the subject, offering sound guidance to both experienced and early-career researchers. The book also delivers: A thorough introduction to the fundamentals of colloids, including the theory of nucleation and the growth of colloidal particles Comprehensive explorations of mechanisms and strategies for the self-assembly of colloidal particles, including DNA-mediated colloidal self-assembly Practical discussions of characterization techniques for self-assembled colloidal structures, including electron microscopy techniques and X-ray techniques In-depth examinations of biological and biomedical materials, including tissue engineering, drug loading and release, and biodetection Perfect for materials scientists, inorganic chemists, and catalytic chemists, Functional Materials from Colloidal Self-assembly is also a must-read reference for biochemists and surface chemists seeking a one-stop resource on self-assembling and functional materials.
Author: Redouane Borsali
Publisher: Springer Science & Business Media
ISBN: 140204464X
Category : Science
Languages : en
Pages : 1490
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Book Description
This 2-volume set includes extensive discussions of scattering techniques (light, neutron and X-ray) and related fluctuation and grating techniques that are at the forefront of this field. Most of the scattering techniques are Fourier space techniques. Recent advances have seen the development of powerful direct imaging methods such as atomic force microscopy and scanning probe microscopy. In addition, techniques that can be used to manipulate soft matter on the nanometer scale are also in rapid development. These include the scanning probe microscopy technique mentioned above as well as optical and magnetic tweezers.
Author: Gunther Molau
Publisher: Springer Science & Business Media
ISBN: 1468419080
Category : Technology & Engineering
Languages : en
Pages : 326
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Book Description
The molecules of block and graft copolymers are molecules of a higher order; they consist of homopolymer subchains which are interconnected by chemical valence bonds. This structural com plexity is manifested in the unusual behavior of block and graft copolymers both in solution and in bulk. Many types of interac tions are possible in block and graft copolymers in the solid state. Polymer subchains of one molecule can interact with other polymer subchains which may belong to the same molecule or to different molecules. Since polymer chains of chemically different composition are usually incompatible, thermodynamically unfavorable as well as thermodynamically favorable interactions exist in the solid state. In solutions of block and graft copolymers, the sit uation becomes even more complex, because interactions between the solvent molecules and the various subchains of the copolymer mole cules occur in addition to the interactions between the polymer chains. This multitude of interactions gives rise to a wide spec trum of colloidal and morphological properties which have no paral lel in less complex polymer systems such as homopolymers or random copolymers. Research on the colloidal and morphological behavior of block and graft copolymers is a relatively new field of endeavor. It started in 1954, when F. M. Merrett fractionated mixtures of grafted na tural rubber with the corresponding homopolymers and observed that colloidal sols were formed at certain points during his fractional precipitations.
Author: Nikos Hadjichristidis
Publisher: John Wiley & Sons
ISBN: 0471461342
Category : Technology & Engineering
Languages : en
Pages : 445
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Book Description
Polymers may be classified as either homopolymers, consisting of one single repeating unit, or copolymers, consisting of two or more distinct repeating units. Block copolymers contain long contiguous blocks of two or more repeating units in the same polymer chain. Covering one of the hottest topics in polymer chemistry, Block Copolymers provides a coherent overview of the synthetic routes, physical properties, and applications of block copolymers. This pioneering text provides not only a guideline for developing synthetic strategies for creating block copolymers with defined characteristics, but also a key to the relationship between the physical properties of block copolymers and the structure and dynamics of materials. Covering features of the chemistry and physics of block copolymers that are not found in comparable texts, Block Copolymers illustrates the structure-activity relationship of block copolymers and offers suggestions for the design of specific applications. Divided into five sections-Block Copolymers includes chapters on: * Block Copolymers by Chemical Modification of Precursor Polymers * Nonlinear Block Copolymers * Adsorption of Block Copolymers at Solid-Liquid Interfaces * Theory of Block Copolymer Segregation * Phase Transformation Kinetics * Block Copolymer Morphology * Block Copolymer Dynamics Polymer chemists, physicists, chemical engineers, and materials scientists, as well as graduate students in polymer science, will find Block Copolymers to be an invaluable text.
Author: Massimo Lazzari
Publisher: John Wiley & Sons
ISBN: 3527610561
Category : Technology & Engineering
Languages : en
Pages : 447
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Book Description
This first book to take a detailed look at one of the key focal points where nanotechnology and polymers meet provides both an introductory view for beginners as well as in-depth knowledge for specialists in the various research areas involved. It investigates all types of application for block copolymers: as tools for fabricating other nanomaterials, as structural components in hybrid materials and nanocomposites, and as functional materials. The multidisciplinary approach covers all stages from chemical synthesis and characterization, presenting applications from physics and chemistry to biology and medicine, such as micro- and nanolithography, membranes, optical labeling, drug delivery, as well as sensory and analytical uses.
Author: Vasiliĭ Vladimirovich Korshak
Publisher:
ISBN:
Category : Polymerization
Languages : en
Pages : 252
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Book Description
Author: Zhibin Guan
Publisher: Springer Science & Business Media
ISBN: 3540877509
Category : Science
Languages : en
Pages : 262
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Book Description
Polyolefin is a major industry that is important for our economy and impacts every aspect of our lives. The discovery of new transition metal-based catalysts is one of the driving forces for the further advancement of this field. Whereas the classical heterogeneous Ziegler-Natta catalysts and homogeneous early transition metal metallocene catalysts remain the workhorses of the polyolefin industry, in roughly the last decade, tremendous progress has been made in developing non-metallocene-based olefin polymerization catalysts. Particularly, the discovery of late transition metal-based olefin polymerization catalysts heralds a new era for this field. These late transition metal complexes not only exhibit high activities rivaling their early metal counterparts, but more importantly they offer unique properties for polymer architectural control and copolymerization with polar olefins. In this book, the most recent major breakthroughs in the development of new olefin polymerization catalysts, including early metal metallocene and non-metallocene complexes and late transition metal complexes, are discussed by leading experts. The authors highlight the most important discoveries in catalysts and their applications in designing new polyolefin-based functional materials.
Author: Volker Abetz
Publisher: Springer Science & Business Media
ISBN: 9783540265801
Category : Technology & Engineering
Languages : en
Pages : 264
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Book Description
1 N. Hadjichristidis, M. Pitsikalis, H. Iatrou: Synthesis of Block Copolymers.- 2 V. Abetz: Phase Behaviour and Morphologies of Block Copolymers.-
