Atomic Diffusion in Disordered Materials

Atomic Diffusion in Disordered Materials PDF Author: Minko Balkanski
Publisher: World Scientific
ISBN: 9789810227357
Category : Science
Languages : en
Pages : 316

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Book Description
This book describes a body of work whose ultimate goal is to optimize the design of microbatteries. It focuses on the fundamental properties of the structure and atomic diffusion in glassy materials which optimize the properties of the electrolyte. Experimental results and their phenomenological description of lithium borate glasses are extensively covered. Other chapters discuss the effects of barriers between the electrodes and the electrolyte and the book culminates with a description of actual progress in making applications of these materials to batteries, sensors and other devices.

Atomic Diffusion in Disordered Materials

Atomic Diffusion in Disordered Materials PDF Author: Minko Balkanski
Publisher: World Scientific
ISBN: 9789810227357
Category : Science
Languages : en
Pages : 316

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Book Description
This book describes a body of work whose ultimate goal is to optimize the design of microbatteries. It focuses on the fundamental properties of the structure and atomic diffusion in glassy materials which optimize the properties of the electrolyte. Experimental results and their phenomenological description of lithium borate glasses are extensively covered. Other chapters discuss the effects of barriers between the electrodes and the electrolyte and the book culminates with a description of actual progress in making applications of these materials to batteries, sensors and other devices.

Disordered Materials

Disordered Materials PDF Author: Stadford R. Ovshinsky
Publisher: Springer Science & Business Media
ISBN: 1468487450
Category : Science
Languages : en
Pages : 404

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Book Description
Landmark contributions to science and mechanisms for the origin of the phenomena, and technology are rarely recognized at the time of reached important conclusions about the physical publication. Few people, even in technical areas, nature of the materials at equilibrium and their recogni zed the importance of developments such as electronic nonequilibrium properties. Many of these the transistor, the laser, or electrophotography ideas were condensed into a publication for Physical until well after their successful demonstration. Review Letters, paper 1 in this collection. This So-called experts, in fact, tend to resist new paper immediately attracted attention to the field, inventions, a natural instinct based on a combina and directly lead to the initiation of large research tion of fear of obsolescent expertise and jealousy efforts at both industrial laboratories and univer- arising from lack of active participation in the ties throughout the world. Inevitably, there was discovery. the usual amount of controversy, with many experts Denigration of new ideas is a relatively simultaneously taking positions (2) and (3) above. safe modus operandi, since the vast majority It has now been well over 20 years since eventually are abandoned well short of commerciality. the original publication date, and an objective view However, a successful device can be identified by can be taken in hindsight.

Disordered Materials

Disordered Materials PDF Author: Paolo Ossi
Publisher: Springer Science & Business Media
ISBN: 3662051583
Category : Science
Languages : en
Pages : 294

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Book Description
This self-contained text introduces the physics of structurally disordered condensed systems at the level of advanced undergraduate and graduate students. Clearly presented and amply illustrated it provides stimulating and novel coverage of a difficult area. In this second edition, the treatment of the mode coupling theory of the glass transition has been enlarged and now connects to a new section on collective excitations in disordered systems.

Defects and Disorder in Crystalline and Amorphous Solids

Defects and Disorder in Crystalline and Amorphous Solids PDF Author: Richard Catlow
Publisher: Springer Science & Business Media
ISBN: 9401119422
Category : Science
Languages : en
Pages : 511

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Book Description
The study of defects and disorder in solids remains a central topic in solid state science. Developments in the field continue to be promoted by new experimental and theoretical techniques, while further impetus for the study of disorder in solids is provided by the growing range of applications of solid state materials in which disorder at the atomic level plays a crucial rOle. In this book we attempt to present a survey of fundamental and applied aspects of the field. We consider the basic aspects of defective crystalline and amorphous solids. We discuss recent studies of structural, electronic, transport, thermodynamic and spectroscopic properties of such materials. Experimental and theoretical methodologies are reviewed, and detailed consideration is given to materials such as fast ion conductors and amorphous semiconductors that are of importance in an applied context. Any survey of this large field is necessarily selective. We have chosen to emphasise insulating (especially oxidic) and semi-conducting materials. But many of the approaches and techniques we describe apply generally across the entire field of solid state science. This volume is based on a NATO ASI held at the Residencia Santa Teresa de Jesus, Madrid in September 1991. The Editor is grateful to the NATO Scientific Affairs Division for their sponsorship of this School. Thanks are also due to all who participated in and lectured at the school, but especially to the organising committee of A. V. Chadwick, G. N. Greaves, M. Grigorkiewicz, J. H. Harding and S. Kalbitzer. C. R. A.

Disordered Materials and Interfaces: Volume 407

Disordered Materials and Interfaces: Volume 407 PDF Author: Herman Z. Cummins
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 450

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Book Description
This book focuses on the fractal aspects of materials and disordered systems. Disorder plays a critical role in many naturally occurring and manufactured materials, both at the microscopic level (e.g., glasses) and the macroscopic level (e.g., foams, dendritic alloys, porous rock). The book addresses the dynamical processes involved in the formation and characterization of a wide range of disordered materials. Topics include: porous media; colloids; chemical reactions; dynamical aspects of the liquid-glass transition; disordered materials and surfaces and scaling and nanostructures.

Structural and magnetic disorder in crystalline materials

Structural and magnetic disorder in crystalline materials PDF Author: Davide Gambino
Publisher: Linköping University Electronic Press
ISBN: 9176850811
Category :
Languages : en
Pages : 83

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Book Description
Disorder in crystalline materials can take different forms and originate from different sources. In particular, temperature introduces disorder in any kind of material. This can be observed as the appearance of vacant lattice sites in an otherwise perfect crystal, or as a random distribution of different elements on the same lattice in an alloy; at the same time, if the material is magnetic, temperature induces disorder also on the magnetic degrees of freedom. In this thesis, different levels of disorder associated to structure and magnetism are investigated by means of density functional theory and thermodynamic models. I start with diffusion of Ti vacancies in TiN, which is studied by means of nonequilibrium ab initio molecular dynamics using the color diffusion algorithm at different temperatures. The result is an Arrhenius behavior of Ti vacancy jump rates. A method to perform structural relaxations in magnetic materials in their hightemperature paramagnetic phase is then developed based on the disordered local moments approach in order to study vacancies, interstitial atoms, and combinations of defects in paramagnetic bcc Fe and B1 CrN, as well as the mixing enthalpy of bcc Fe1?xCrx random alloys. A correction to the energetics of every system due to the relaxation in the disordered magnetic state is observed in all cases. Not related to temperature and disorder, but very important for an accurate description of magnetic materials, is the choice of the exchange and correlation functional to be employed in the first principles calculations. We have investigated the performance of a recently developed meta-GGA functional, the strongly constrained and appropriately normed (SCAN) functional, in comparison with the more commonly used LDA and PBE on the ferromagnetic elemental solids bcc Fe, fcc Ni, and hcp Co, and SCAN it is found to give negligible improvements, if not a worsening, in the description of these materials. Finally, the coupling between vibrational and magnetic degrees of freedom is discussed by reviewing the literature and proposing an investigation of the influence of vibrations on longitudinal spin fluctuations. These excitations are here studied by means of thermodynamic models based on Landau expansion of the energy in even powers of the magnitude of the local magnetic moments. We find that vibrational and magnetic disorder alter the energy landscapes as a function of moment size also in bcc Fe, which is often considered a Heisenberg system, inducing a more itinerant electron behavior.

Kinetics of Materials

Kinetics of Materials PDF Author: Robert W. Balluffi
Publisher: John Wiley & Sons
ISBN: 0471749303
Category : Science
Languages : en
Pages : 672

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Book Description
A classroom-tested textbook providing a fundamental understandingof basic kinetic processes in materials This textbook, reflecting the hands-on teaching experience of itsthree authors, evolved from Massachusetts Institute of Technology'sfirst-year graduate curriculum in the Department of MaterialsScience and Engineering. It discusses key topics collectivelyrepresenting the basic kinetic processes that cause changes in thesize, shape, composition, and atomistic structure of materials.Readers gain a deeper understanding of these kinetic processes andof the properties and applications of materials. Topics are introduced in a logical order, enabling students todevelop a solid foundation before advancing to more sophisticatedtopics. Kinetics of Materials begins with diffusion, offering adescription of the elementary manner in which atoms and moleculesmove around in solids and liquids. Next, the more complex motion ofdislocations and interfaces is addressed. Finally, still morecomplex kinetic phenomena, such as morphological evolution andphase transformations, are treated. Throughout the textbook, readers are instilled with an appreciationof the subject's analytic foundations and, in many cases, theapproximations commonly used in the field. The authors offer manyextensive derivations of important results to help illuminate theirorigins. While the principal focus is on kinetic phenomena incrystalline materials, select phenomena in noncrystalline materialsare also discussed. In many cases, the principles involved apply toall materials. Exercises with accompanying solutions are provided throughoutKinetics of Materials, enabling readers to put their newfoundknowledge into practice. In addition, bibliographies are offeredwith each chapter, helping readers to investigate specializedtopics in greater detail. Several appendices presenting importantbackground material are also included. With its unique range of topics, progressive structure, andextensive exercises, this classroom-tested textbook provides anenriching learning experience for first-year graduate students.

Thermodynamics, Diffusion and the Kirkendall Effect in Solids

Thermodynamics, Diffusion and the Kirkendall Effect in Solids PDF Author: Aloke Paul
Publisher: Springer
ISBN: 331907461X
Category : Science
Languages : en
Pages : 543

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Book Description
In this book basic and some more advanced thermodynamics and phase as well as stability diagrams relevant for diffusion studies are introduced. Following, Fick’s laws of diffusion, atomic mechanisms, interdiffusion, intrinsic diffusion, tracer diffusion and the Kirkendall effect are discussed. Short circuit diffusion is explained in detail with an emphasis on grain boundary diffusion. Recent advances in the area of interdiffusion will be introduced. Interdiffusion in multi-component systems is also explained. Many practical examples will be given, such that researches working in this area can learn the practical evaluation of various diffusion parameters from experimental results. Large number of illustrations and experimental results are used to explain the subject. This book will be appealing for students, academicians, engineers and researchers in academic institutions, industry research and development laboratories.

Fundamentals of Rock Physics

Fundamentals of Rock Physics PDF Author: Nikolai Bagdassarov
Publisher: Cambridge University Press
ISBN: 1108390196
Category : Science
Languages : en
Pages : 566

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Book Description
Rock physics encompasses practically all aspects of solid and fluid state physics. This book provides a unified presentation of the underlying physical principles of rock physics, covering elements of mineral physics, petrology and rock mechanics. After a short introduction on rocks and minerals, the subsequent chapters cover rock density, porosity, stress and strain relationships, permeability, poroelasticity, acoustics, conductivity, polarizability, magnetism, thermal properties and natural radioactivity. Each chapter includes problem sets and focus boxes with in-depth explanations of the physical and mathematical aspects of underlying processes. The book is also supplemented by online MATLAB exercises to help students apply their knowledge to numerically solve rock physics problems. Covering laboratory and field-based measurement methods, as well as theoretical models, this textbook is ideal for upper-level undergraduate and graduate courses in rock physics. It will also make a useful reference for researchers and professional scientists working in geoscience and petroleum engineering.

Physics, Uspekhi

Physics, Uspekhi PDF Author:
Publisher:
ISBN:
Category : Physics
Languages : en
Pages : 488

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Book Description