Mechanistic Studies on the OH-initiated Atmospheric Oxidation of Selected Aromatic Hydrocarbons

Mechanistic Studies on the OH-initiated Atmospheric Oxidation of Selected Aromatic Hydrocarbons PDF Author: Sascha Nehr
Publisher: Forschungszentrum Jülich
ISBN: 3893368043
Category :
Languages : en
Pages : 145

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Reactive Hydrocarbons in the Atmosphere

Reactive Hydrocarbons in the Atmosphere PDF Author: C. Nicholas Hewitt
Publisher: Elsevier
ISBN: 0080540309
Category : Science
Languages : en
Pages : 335

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Book Description
The vast family of volatile organic compounds plays a central role in the chemistry of the Earth's atmosphere. Reactive Hydrocarbons in the Atmosphere provides comprehensive and up-to-date reviews covering all aspects of the behavior, sources, occurrence, and chemistry of these compounds. The book considers both biogenic and anthropogenic sources, plus their effects in the atmosphere at local, regional, and global scales. - Covers a major component of atmospheric chemistry and air pollution - Considers both natural background chemistry and pollution processes - Provides authoritative reviews for a wide range of audiences

Atmospheric Chemistry

Atmospheric Chemistry PDF Author: Julian Heicklen
Publisher: Elsevier
ISBN: 0323151108
Category : Science
Languages : en
Pages : 423

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Book Description
Atmospheric Chemistry is a comprehensive treatment of atmospheric chemistry and covers topics ranging from the structure of the atmosphere to the chemistry of the upper atmosphere and the ionosphere. Atmospheric pollutants, hydrocarbon oxidation, and photochemical smog are also discussed, along with the reactions of O8 and singlet O2, the chemistry of SO2 and aerosols, and methods for controlling atmospheric pollution. This book is comprised of 10 chapters and begins with an overview of the composition and chemistry of the atmosphere as well as its physical characteristics and the chemistry of meteors. The next two chapters deal with the chemistry of the upper atmosphere and the ionosphere, with emphasis on neutral oxygen atmosphere, carbon-hydrogen-oxygen cycle, and the D region. The chemistry of atmospheric pollutants is also examined, along with hydrocarbon oxidation and photochemical smog. The remaining chapters focus on the reactions of O8 and singlet O2, the chemistry of SO2 and aerosols, and methods for controlling atmospheric pollution. This monograph should be useful to graduate students and scientists who wish to study atmospheric chemistry.

The Mechanisms of Atmospheric Oxidation of the Aromatic Hydrocarbons

The Mechanisms of Atmospheric Oxidation of the Aromatic Hydrocarbons PDF Author: Jack G. Calvert
Publisher: Oxford University Press
ISBN: 9780199771547
Category : Science
Languages : en
Pages : 570

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Book Description
This text reviews many of the aspects of the chemistry of the aromatic hydrocarbons and a consensus evaluation of the data by seven of the leading atmospheric scientists. The book covers topics ranging from the relative importance of the compounds in ozone and haze development to methods of estimating elemantary rate coefficients based on structural features of the compounds to mechanisms of aerosol generation and atmostpheric reaction of the polycyclic compounds to photochemical processes. It identifies features of the aromatic hydrocarbons requiring further study and appendicies give the structural formulas and nomenclature of the compounds reviewed in the book.

Volatile Organic Compounds in the Atmosphere

Volatile Organic Compounds in the Atmosphere PDF Author: Ralf Koppmann
Publisher: John Wiley & Sons
ISBN: 0470994150
Category : Science
Languages : en
Pages : 512

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Book Description
Every day, large quantities of volatile organic compounds (VOCs) are emitted into the atmosphere from both anthropogenic and natural sources. The formation of gaseous and particulate secondary products caused by oxidation of VOCs is one of the largest unknowns in the quantitative prediction of the earth’s climate on a regional and global scale, and on the understanding of local air quality. To be able to model and control their impact, it is essential to understand the sources of VOCs, their distribution in the atmosphere and the chemical transformations which remove these compounds from the atmosphere. In recent years techniques for the analysis of organic compounds in the atmosphere have been developed to increase the spectrum of detectable compounds and their detection limits. New methods have been introduced to increase the time resolution of those measurements and to resolve more complex mixtures of organic compounds. Volatile Organic Compounds in the Atmosphere describes the current state of knowledge of the chemistry of VOCs as well as the methods and techniques to analyse gaseous and particulate organic compounds in the atmosphere. The aim is to provide an authoritative review to address the needs of both graduate students and active researchers in the field of atmospheric chemistry research.

Atmospheric Chemical Compounds

Atmospheric Chemical Compounds PDF Author: T. E. Graedel
Publisher: Elsevier
ISBN: 0080918425
Category : Science
Languages : en
Pages : 745

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Book Description
This practical reference examines the structure and properties of the atmosphere, including listings of compounds in clouds, fog, rain, snow, and ice; a listing of compounds detected in the stratosphere; and a compendium of compounds in indoor air. An introduction to carcinogenicity and bioassay of atmospheric compounds is also presented. Readers will find the extensive cross-referencing especially useful--compounds can be located by chemical type, name, CAS registry number, or source.

Mechanisms of Atmospheric Oxidation of the Oxygenates

Mechanisms of Atmospheric Oxidation of the Oxygenates PDF Author: Jack Calvert
Publisher: OUP USA
ISBN: 0199767076
Category : Science
Languages : en
Pages : 1634

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Book Description
Prepared by an international team of eminent atmospheric scientists, Mechanisms of Atmospheric Oxidation of the Oxygenates is an authoritative source of information on the role of oxygenates in the chemistry of the atmosphere. The oxygenates, including the many different alcohols, ethers, aldehydes, ketones, acids, esters, and nitrogen-atom containing oxygenates, are of special interest today due to their increased use as alternative fuels and fuel additives. This book describes the physical properties of oxygenates, as well as the chemical and photochemical parameters that determine their reaction pathways in the atmosphere. Quantitative descriptions of the pathways of the oxygenates from release or formation in the atmosphere to final products are provided, as is a comprehensive review and evaluation of the extensive kinetic literature on the atmospheric chemistry of the different oxygenates and their many halogen-atom substituted analogues. This book will be of interest to modelers of atmospheric chemistry, environmental scientists and engineers, and air quality planning agencies as a useful input for development of realistic modules designed to simulate the atmospheric chemistry of the oxygenates, their major oxidation products, and their influence on ozone and other trace gases within the troposhere.

Ozone-Forming Potential of Reformulated Gasoline

Ozone-Forming Potential of Reformulated Gasoline PDF Author: National Research Council
Publisher: National Academies Press
ISBN: 0309064457
Category : Science
Languages : en
Pages : 270

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Book Description
The Committee on Ozone-Forming Potential for Reformulated Gasoline was asked whether the existing body of scientific and technical information is sufficient to permit a robust evaluation and comparison of the emissions from motor vehicles using different reformulated gasolines based on their ozone-forming potentials and to assess the concomitant impact of that approach on air-quality benefits of the use of oxygenates within the RFG program. As part of its charge, the committee was asked to consider (1) the technical soundness of various approaches for evaluating and comparing the relative ozone-forming potentials of RFG blends, (2) technical aspects of various air-quality issues related to RFG assessment, and (3) the sensitivity of evaluations of the relative ozone-forming potentials to factors related to fuel properties and the variability of vehicle technologies and driving patterns.

Alkenes and Aromatics

Alkenes and Aromatics PDF Author: Peter Taylor
Publisher: Royal Society of Chemistry
ISBN: 9780854046805
Category : Education
Languages : en
Pages : 192

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Book Description
Describes the reaction mechanisms associated with electrophilic attack on carbon-carbon double bonds.

Modeling of Atmospheric Chemistry

Modeling of Atmospheric Chemistry PDF Author: Guy P. Brasseur
Publisher: Cambridge University Press
ISBN: 1108210953
Category : Science
Languages : en
Pages : 631

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Book Description
Mathematical modeling of atmospheric composition is a formidable scientific and computational challenge. This comprehensive presentation of the modeling methods used in atmospheric chemistry focuses on both theory and practice, from the fundamental principles behind models, through to their applications in interpreting observations. An encyclopaedic coverage of methods used in atmospheric modeling, including their advantages and disadvantages, makes this a one-stop resource with a large scope. Particular emphasis is given to the mathematical formulation of chemical, radiative, and aerosol processes; advection and turbulent transport; emission and deposition processes; as well as major chapters on model evaluation and inverse modeling. The modeling of atmospheric chemistry is an intrinsically interdisciplinary endeavour, bringing together meteorology, radiative transfer, physical chemistry and biogeochemistry, making the book of value to a broad readership. Introductory chapters and a review of the relevant mathematics make this book instantly accessible to graduate students and researchers in the atmospheric sciences.