Non-Equilibrium Thermodynamics

Non-Equilibrium Thermodynamics PDF Author: S. R. De Groot
Publisher: Courier Corporation
ISBN: 0486153509
Category : Science
Languages : en
Pages : 532

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Book Description
Classic monograph treats irreversible processes and phenomena of thermodynamics: non-equilibrium thermodynamics. Covers statistical foundations and applications with chapters on fluctuation theory, theory of stochastic processes, kinetic theory of gases, more.

Non-Equilibrium Thermodynamics

Non-Equilibrium Thermodynamics PDF Author: S. R. De Groot
Publisher: Courier Corporation
ISBN: 0486153509
Category : Science
Languages : en
Pages : 532

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Book Description
Classic monograph treats irreversible processes and phenomena of thermodynamics: non-equilibrium thermodynamics. Covers statistical foundations and applications with chapters on fluctuation theory, theory of stochastic processes, kinetic theory of gases, more.

Nonequilibrium Thermodynamics

Nonequilibrium Thermodynamics PDF Author: Yasar Demirel
Publisher: Newnes
ISBN: 0444595813
Category : Technology & Engineering
Languages : en
Pages : 787

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Book Description
Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. Nonequilibrium Thermodynamics, Third Edition emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapter on stochastic approaches to include the statistical thermodynamics, mesoscopic nonequilibrium thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems in thermodynamic analysis. This new addition also comes with more examples and practice problems. Informs and updates on all the latest developments in the field Contributions from leading authorities and industry experts A useful text for seniors and graduate students from diverse engineering and science programs to analyze some nonequilibrium, coupled, evolutionary, stochastic, and dissipative processes Highlights fundamentals of equilibrium thermodynamics, transport processes and chemical reactions Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical, and biological systems Presents a unified analysis for transport and rate processes in various time and space scales Discusses stochastic approaches in thermodynamic analysis including fluctuation and information theories Has 198 fully solved examples and 287 practice problems An Instructor Resource containing the Solution Manual can be obtained from the author: [email protected]

Understanding Non-equilibrium Thermodynamics

Understanding Non-equilibrium Thermodynamics PDF Author: Georgy Lebon
Publisher: Springer Science & Business Media
ISBN: 3540742522
Category : Science
Languages : en
Pages : 331

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Book Description
Discover the many facets of non-equilibrium thermodynamics. The first part of this book describes the current thermodynamic formalism recognized as the classical theory. The second part focuses on different approaches. Throughout the presentation, the emphasis is on problem-solving applications. To help build your understanding, some problems have been analyzed using several formalisms to underscore their differences and their similarities.

Non-equilibrium Thermodynamics of Heterogeneous Systems

Non-equilibrium Thermodynamics of Heterogeneous Systems PDF Author: Signe Kjelstrup
Publisher: World Scientific
ISBN: 9812779132
Category : Technology & Engineering
Languages : en
Pages : 451

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Book Description
The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.

Non-equilibrium Thermodynamics

Non-equilibrium Thermodynamics PDF Author: Istvan Gyarmati
Publisher: Springer Science & Business Media
ISBN: 3642510671
Category : Science
Languages : en
Pages : 195

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Book Description
Although nearly three years have elapsed since the publication of this work in Hungarian, it was decided to publish the English edition in the same form as the original, apart from some minor modifications. Since, recent research has been directed to the development of an exact theory of non-linear irreversible processes; we suggest to readers interested in similar tasks - such as the continuation of this boo- that they should study some new publications: "On the most general form of the Thermodynamic Integral Principle", Z. phys. Chem. 239 (1968) 133, and particularly: "On the Governing Principle of Dissi pative Processes", Ann. Phys. 7 (1969) 23. I have to thank my wife and Mr. W.F.HEINZ for the translation of the very concise Hungarian text. I also wish to express my gratitude to Dr. L.KARADI and Mr. Gy. VINCZE for reading the typescript with such care and to Mrs. A. R6sZLER, who typed the manuscript with great patience. I am deeply indebted to Professor ISTVAN SZABO for making this edition available so quickly and for including my work in the "En gineering Science Library". Finally, I would like to express my thanks to Springer-Verlag for the excellent edition and to the editorial staff for their readiness to meet my wishes.

Non-equilibrium Thermodynamics and Statistical Mechanics

Non-equilibrium Thermodynamics and Statistical Mechanics PDF Author: Phil Attard
Publisher: OUP Oxford
ISBN: 019163977X
Category : Science
Languages : en
Pages : 480

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Book Description
`Non-equilibrium Thermodynamics and Statistical Mechanics: Foundations and Applications' builds from basic principles to advanced techniques, and covers the major phenomena, methods, and results of time-dependent systems. It is a pedagogic introduction, a comprehensive reference manual, and an original research monograph. Uniquely, the book treats time-dependent systems by close analogy with their static counterparts, with most of the familiar results of equilibrium thermodynamics and statistical mechanics being generalized and applied to the non-equilibrium case. The book is notable for its unified treatment of thermodynamics, hydrodynamics, stochastic processes, and statistical mechanics, for its self-contained, coherent derivation of a variety of non-equilibrium theorems, and for its quantitative tests against experimental measurements and computer simulations. Systems that evolve in time are more common than static systems, and yet until recently they lacked any over-arching theory. 'Non-equilibrium Thermodynamics and Statistical Mechanics' is unique in its unified presentation of the theory of non-equilibrium systems, which has now reached the stage of quantitative experimental and computational verification. The novel perspective and deep understanding that this book brings offers the opportunity for new direction and growth in the study of time-dependent phenomena. 'Non-equilibrium Thermodynamics and Statistical Mechanics' is an invaluable reference manual for experts already working in the field. Research scientists from different disciplines will find the overview of time-dependent systems stimulating and thought-provoking. Lecturers in physics and chemistry will be excited by many fresh ideas and topics, insightful explanations, and new approaches. Graduate students will benefit from its lucid reasoning and its coherent approach, as well as from the chem12physof mathematical techniques, derivations, and computer algorithms.

Statistical Thermodynamics of Nonequilibrium Processes

Statistical Thermodynamics of Nonequilibrium Processes PDF Author: Joel Keizer
Publisher: Springer Science & Business Media
ISBN: 1461210542
Category : Science
Languages : en
Pages : 517

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Book Description
The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.

Non-equilibrium Thermodynamics and the Production of Entropy

Non-equilibrium Thermodynamics and the Production of Entropy PDF Author: Axel Kleidon
Publisher: Springer Science & Business Media
ISBN: 9783540224952
Category : Science
Languages : en
Pages : 288

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Book Description
The present volume studies the application of concepts from non-equilibrium thermodynamics to a variety of research topics. Emphasis is on the Maximum Entropy Production (MEP) principle and applications to Geosphere-Biosphere couplings. Written by leading researchers from a wide range of backgrounds, the book presents a first coherent account of an emerging field at the interface of thermodynamics, geophysics and life sciences.

Aspects of Non-equilibrium Thermodynamics

Aspects of Non-equilibrium Thermodynamics PDF Author: Wolfgang Muschik
Publisher: World Scientific
ISBN: 9789810200879
Category : Science
Languages : en
Pages : 124

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Book Description
In six lectures aspects of modern non-equilibrium thermodynamics of discrete systems as well as continuum theoretical concepts are represented. Starting out with survey and introduction, state spaces are defined, the existence of internal energy is investigated, and Clausius inequality including negative absolute temperature is derived by diagram technique. Non-equilibrium contact quantities, such as contact temperature ? the dynamic analogue of thermostatic temperature ? and chemical potentials are phenomenologically defined and quantumstatistically founded. Using Clausius inequality the existence of non-negative entropy production is proved which allows to formulate a dissipation inequality in continuum thermodynamics. The transition between thermodynamics of discrete systems and continuum thermodynamics with respect to contact quantities is considered. Different possibilities of exploiting the dissipation inequality for getting constraints for constitutive equations are discussed. Finally hyperbolic heat conduction in non-extended thermodynamics is treated.

Non-equilibrium Thermodynamics for Engineers

Non-equilibrium Thermodynamics for Engineers PDF Author:
Publisher: World Scientific
ISBN: 9814329916
Category : Science
Languages : en
Pages : 273

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Book Description
The book describes in a simple and practical way what non-equilibrium thermodynamics is and how it can add to engineering fields. It explains how to describe proper equations of transport, more precise than used so far, and how to use them to understand the waste of energy resources in central unit processes in the industry. It introduces the entropy balance as an additional equation to use, to create consistent thermodynamic models, and a systematic method for minimizing energy losses that are connected with transport of heat, mass, charge, momentum and chemical reactions. Readership: Senior undergraduate and graduate students in physics, chemistry, chemical engineering and mechanical engineering.