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Author: Henry Hsieh
Publisher: CRC Press
ISBN: 9780824795238
Category : Technology & Engineering
Languages : en
Pages : 748
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Book Description
This work introduces the basic theories and experimental methods of anionic polymerization as well as the synthesis, analysis and characteristics of anionic polymerized products. It details the creation of linear and branched polymers, random and block copolymers, graft and macromonomers, and many other substances. The work emphasizes the relationship between fundamental principles and commercial applications.;College or university bookstores may purchase five or more copies at a special student price, available on request from Marcel Dekker, Inc.
Author: Henry Hsieh
Publisher: CRC Press
ISBN: 9780824795238
Category : Technology & Engineering
Languages : en
Pages : 748
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Book Description
This work introduces the basic theories and experimental methods of anionic polymerization as well as the synthesis, analysis and characteristics of anionic polymerized products. It details the creation of linear and branched polymers, random and block copolymers, graft and macromonomers, and many other substances. The work emphasizes the relationship between fundamental principles and commercial applications.;College or university bookstores may purchase five or more copies at a special student price, available on request from Marcel Dekker, Inc.
Author: Maurice Morton
Publisher: Elsevier
ISBN: 0323158846
Category : Science
Languages : en
Pages : 257
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Book Description
Anionic Polymerization: Principles and Practice describes the unique nature of the anionic mechanism of polymerization. This book is composed of two parts encompassing 11 chapters that cover the aspects of the synthetic possibilities inherent in this system. Part I deals with the various aspects of anionic polymerization mechanism, including the monomers, initiators, solvents, and the involved initiation and propagation reactions. This part also describes the copolymerization and organolithium polymerization reactions of styrene and dienes. Part II explores the applications of anionic polymerization in polymer synthesis. This part specifically tackles the synthesis of narrow molecular weight, branched and a,?-difunctional polymers, and block copolymers. Polymer chemists and researchers who work in the chemical industry and who would wish to utilize the unique features of anionic polymerization in the synthesis of new products will find this book invaluable.
Author: Michael Szwarc
Publisher: Springer
ISBN: 9783662153031
Category : Technology & Engineering
Languages : en
Pages : 190
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Book Description
Author: Nikos Hadjichristidis
Publisher: Springer
ISBN: 4431541861
Category : Technology & Engineering
Languages : en
Pages : 1075
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Book Description
This book presents these important facts: a) The mechanism of anionic polymerization, a more than 50-year challenge in polymer chemistry, has now become better understood; b) Precise synthesis of many polymers with novel architectures (triblock, multi-block, graft, exact graft, comb, cyclic, many armed stars with multi-components, dendrimer-like hyper-branched, and their structural mixed (co)polymers, etc.) have been advanced significantly; c) Based on such polymers, new morphological and self-organizing nano-objects and supra molecular assemblies have been created and widely studied and are considered nanodevices in the fields of nano science and technology; d) New high-tech and industrial applications for polymeric materials synthesized by anionic polymerization have been proposed. These remarkable developments have taken place in the last 15 years. Anionic polymerization continues to be the only truly living polymerization system (100 % termination free under appropriate conditions) and consequently the only one with unique capabilities in the synthesis of well-defined (i.e., precisely controlled molecular weight, nearly mono-disperse molecular weight distribution, structural and compositional homogeneity) complex macromolecular architectures. This book, with contributions from the world’s leading specialists, will be useful for all researchers, including students, working in universities, in research organizations, and in industry.
Author: T.E. Hogen-Esch
Publisher: Springer Science & Business Media
ISBN: 9400931751
Category : Technology & Engineering
Languages : en
Pages : 453
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Book Description
Over the years the field of anionic polymerization has attracted numerous outstanding scientists, and today it still is being pursued by many researchers all over the world. The exciting discovery of termination-less polymerization processes and living polymers culminating in the development of narrow molecular weight polymers, star polymers, and tailor-made block and graft copolymers, contributed immensely to the rapid expansion of polymer science. Areas of active research in anionic polymerization presently include the structure of ion pairs and their role in regulating polymer structure, ring opening polymerization of heterocyclic monomers, synthesis of well-defined block and graft copolymers including the application of macromers in such systems, telechelic polymers with functional end groups, and other topics. New developments in the organic chemistry of carbanions such as dipolar carbanions impinge on the field of anionic polymerization. More sophisticated characterization techniques have been instrumental in obtaining better correlations between the structure of polymers and that of intermediates leading to their formation. This book contains the proceedings of the international symposium on "Recent Advances in Anionic Polymerization and Related Processes" which was held at the 1986 spring meeting of the American Chemical Society. It was the first Polymer Division-sponsored meeting exclusively devoted to anionic polymerization since the Houston ACS meeting in the spring of 1980. The proceedings of that meeting were published in the book "Anionic Polymerization", ACS Symposium Series No. 166, edited by Dr. J. E. McGrath.
Author: Broja Mohan Mandal
Publisher: World Scientific
ISBN: 9814322466
Category : Science
Languages : en
Pages : 468
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Book Description
Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.
Author: Maurice Morton
Publisher: Academic Press
ISBN:
Category : Science
Languages : en
Pages : 264
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Book Description
Anionic Polymerization: Principles and Practice describes the unique nature of the anionic mechanism of polymerization. This book is composed of two parts encompassing 11 chapters that cover the aspects of the synthetic possibilities inherent in this system. Part I deals with the various aspects of anionic polymerization mechanism, including the monomers, initiators, solvents, and the involved initiation and propagation reactions. This part also describes the copolymerization and organolithium polymerization reactions of styrene and dienes. Part II explores the applications of anionic polymerization in polymer synthesis. This part specifically tackles the synthesis of narrow molecular weight, branched and a,?-difunctional polymers, and block copolymers. Polymer chemists and researchers who work in the chemical industry and who would wish to utilize the unique features of anionic polymerization in the synthesis of new products will find this book invaluable.
Author: George Odian
Publisher: John Wiley & Sons
ISBN: 0471274003
Category : Technology & Engineering
Languages : en
Pages : 850
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Book Description
The new edition of a classic text and reference The large chains of molecules known as polymers are currently used in everything from "wash and wear" clothing to rubber tires to protective enamels and paints. Yet the practical applications of polymers are only increasing; innovations in polymer chemistry constantly bring both improved and entirely new uses for polymers onto the technological playing field. Principles of Polymerization, Fourth Edition presents the classic text on polymer synthesis, fully updated to reflect today's state of the art. New and expanded coverage in the Fourth Edition includes: * Metallocene and post-metallocene polymerization catalysts * Living polymerizations (radical, cationic, anionic) * Dendrimer, hyperbranched, brush, and other polymer architectures and assemblies * Graft and block copolymers * High-temperature polymers * Inorganic and organometallic polymers * Conducting polymers * Ring-opening polymer ization * In vivo and in vitro polymerization Appropriate for both novice and advanced students as well as professionals, this comprehensive yet accessible resource enables the reader to achieve an advanced, up-to-date understanding of polymer synthesis. Different methods of polymerization, reaction parameters for synthesis, molecular weight, branching and crosslinking, and the chemical and physical structure of polymers all receive ample coverage. A thorough discussion at the elementary level prefaces each topic, with a more advanced treatment following. Yet the language throughout remains straightforward and geared towards the student. Extensively updated, Principles of Polymerization, Fourth Edition provides an excellent textbook for today's students of polymer chemistry, chemical engineering, and materials science, as well as a current reference for the researcher or other practitioner working in these areas.
Author: Krzysztof Matyjaszewski
Publisher: John Wiley & Sons
ISBN: 9783527324927
Category : Science
Languages : en
Pages : 640
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Book Description
Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.
Author: Gary L. Krieger
Publisher:
ISBN:
Category : Vacuum technology
Languages : en
Pages : 32
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Book Description
