An Introduction to Nonlinear Chemical Dynamics

An Introduction to Nonlinear Chemical Dynamics PDF Author: Irving R. Epstein
Publisher: Oxford University Press
ISBN: 0198025661
Category : Science
Languages : en
Pages : 407

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Book Description
Just a few decades ago, chemical oscillations were thought to be exotic reactions of only theoretical interest. Now known to govern an array of physical and biological processes, including the regulation of the heart, these oscillations are being studied by a diverse group across the sciences. This book is the first introduction to nonlinear chemical dynamics written specifically for chemists. It covers oscillating reactions, chaos, and chemical pattern formation, and includes numerous practical suggestions on reactor design, data analysis, and computer simulations. Assuming only an undergraduate knowledge of chemistry, the book is an ideal starting point for research in the field. The book begins with a brief history of nonlinear chemical dynamics and a review of the basic mathematics and chemistry. The authors then provide an extensive overview of nonlinear dynamics, starting with the flow reactor and moving on to a detailed discussion of chemical oscillators. Throughout the authors emphasize the chemical mechanistic basis for self-organization. The overview is followed by a series of chapters on more advanced topics, including complex oscillations, biological systems, polymers, interactions between fields and waves, and Turing patterns. Underscoring the hands-on nature of the material, the book concludes with a series of classroom-tested demonstrations and experiments appropriate for an undergraduate laboratory.

An Introduction to Nonlinear Chemical Dynamics

An Introduction to Nonlinear Chemical Dynamics PDF Author: Irving R. Epstein
Publisher: Oxford University Press
ISBN: 0198025661
Category : Science
Languages : en
Pages : 407

Get Book

Book Description
Just a few decades ago, chemical oscillations were thought to be exotic reactions of only theoretical interest. Now known to govern an array of physical and biological processes, including the regulation of the heart, these oscillations are being studied by a diverse group across the sciences. This book is the first introduction to nonlinear chemical dynamics written specifically for chemists. It covers oscillating reactions, chaos, and chemical pattern formation, and includes numerous practical suggestions on reactor design, data analysis, and computer simulations. Assuming only an undergraduate knowledge of chemistry, the book is an ideal starting point for research in the field. The book begins with a brief history of nonlinear chemical dynamics and a review of the basic mathematics and chemistry. The authors then provide an extensive overview of nonlinear dynamics, starting with the flow reactor and moving on to a detailed discussion of chemical oscillators. Throughout the authors emphasize the chemical mechanistic basis for self-organization. The overview is followed by a series of chapters on more advanced topics, including complex oscillations, biological systems, polymers, interactions between fields and waves, and Turing patterns. Underscoring the hands-on nature of the material, the book concludes with a series of classroom-tested demonstrations and experiments appropriate for an undergraduate laboratory.

Nonlinear Dynamics and Chaos

Nonlinear Dynamics and Chaos PDF Author: Steven H. Strogatz
Publisher: CRC Press
ISBN: 0429961111
Category : Mathematics
Languages : en
Pages : 532

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Book Description
This textbook is aimed at newcomers to nonlinear dynamics and chaos, especially students taking a first course in the subject. The presentation stresses analytical methods, concrete examples, and geometric intuition. The theory is developed systematically, starting with first-order differential equations and their bifurcations, followed by phase plane analysis, limit cycles and their bifurcations, and culminating with the Lorenz equations, chaos, iterated maps, period doubling, renormalization, fractals, and strange attractors.

Nonlinear Dynamics

Nonlinear Dynamics PDF Author: Marc R Roussel
Publisher: Morgan & Claypool Publishers
ISBN: 1643274643
Category : Science
Languages : en
Pages : 190

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Book Description
This book uses a hands-on approach to nonlinear dynamics using commonly available software, including the free dynamical systems software Xppaut, Matlab (or its free cousin, Octave) and the Maple symbolic algebra system. Detailed instructions for various common procedures, including bifurcation analysis using the version of AUTO embedded in Xppaut, are provided. This book also provides a survey that can be taught in a single academic term covering a greater variety of dynamical systems (discrete versus continuous time, finite versus infinite-dimensional, dissipative versus conservative) than is normally seen in introductory texts. Numerical computation and linear stability analysis are used as unifying themes throughout the book. Despite the emphasis on computer calculations, theory is not neglected, and fundamental concepts from the field of nonlinear dynamics such as solution maps and invariant manifolds are presented.

Understanding Nonlinear Dynamics

Understanding Nonlinear Dynamics PDF Author: Daniel Kaplan
Publisher: Springer Science & Business Media
ISBN: 1461208238
Category : Mathematics
Languages : en
Pages : 438

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Book Description
Mathematics is playing an ever more important role in the physical and biological sciences, provoking a blurring of boundaries between scientific disciplines and a resurgence of interest in the modern as well as the classical techniques of applied mathematics. This renewal of interest, both in research and teaching, has led to the establishment of the series: Texts in Applied Mathematics ( TAM). The development of new courses is a natural consequence of a high level of excitement on the research frontier as newer techniques, such as numerical and symbolic computer systems, dynamical systems, and chaos, mix with and reinforce the traditional methods of applied mathematics. Thus, the purpose of this textbook series is to meet the current and future needs of these advances and encourage the teaching of new courses. TAM will publish textbooks suitable for use in advanced undergraduate and beginning graduate courses, and will complement the Applied Mathematical Sciences (AMS) series, which will focus on advanced textbooks and research level monographs. About the Authors Daniel Kaplan specializes in the analysis of data using techniques motivated by nonlinear dynamics. His primary interest is in the interpretation of irregular physiological rhythms, but the methods he has developed have been used in geo physics, economics, marine ecology, and other fields. He joined McGill in 1991, after receiving his Ph.D from Harvard University and working at MIT. His un dergraduate studies were completed at Swarthmore College. He has worked with several instrumentation companies to develop novel types of medical monitors.

Chemical Oscillations and Instabilities

Chemical Oscillations and Instabilities PDF Author: Peter Gray
Publisher: Oxford University Press on Demand
ISBN: 9780198558644
Category : Literary Criticism
Languages : en
Pages : 453

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Book Description
Scientists in many fields are now expressing considerable interest in non-linearity and the ideas of oscillations and chaos. Chemical reactions provide perfect examples of these phenomena, as oscillating reactions, explosions, ignition, travelling waves, patterns, quasiperiodicity, and chaosare all features of chemical kinetics.Now available in paperback, this book introduces non-linear phenomena in chemical kinetics using simple model schemes. These models involve chemical feedback, such as chain branching, autocatalysis, and self-heating. The emphasis is on physical and pictorial representation, and on identifying thosegross features which are essential. The experimental conditions under which such behaviour will occur can be predicted using simple mathematical recipes, and these are also included.The first part of the book begins with a discussion of long-lived oscillations for autocatalytic or exothermic reactions in closed vessels. Stationary states, bistability, and oscillations in continuous flow reactors and diffusion cells are then considered. This is followed by chemical wavepropagation and by pattern selection and oscillations. Complex oscillations, quasiperiodicity, and chemical chaos, either forced or spontaneous, are introduced. Part 2 deals with real experimental systems, describing observed experimental behaviour and its interpretation in terms of the underlyingchemical mechanisms or simplified models. The Belousov-Zhabotinskii reactions is discussed in some detail as the most extensively studied system, and the behaviour of important gas phase reactions is presented.

Perspectives of Nonlinear Dynamics: Volume 1

Perspectives of Nonlinear Dynamics: Volume 1 PDF Author: E. Atlee Jackson
Publisher: CUP Archive
ISBN: 9780521426329
Category : Mathematics
Languages : en
Pages : 532

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Book Description
The dynamics of physical, chemical, biological, or fluid systems generally must be described by nonlinear models, whose detailed mathematical solutions are not obtainable. To understand some aspects of such dynamics, various complementary methods and viewpoints are of crucial importance. In this book the perspectives generated by analytical, topological and computational methods, and interplays between them, are developed in a variety of contexts. This book is a comprehensive introduction to this field, suited to a broad readership, and reflecting a wide range of applications. Some of the concepts considered are: topological equivalence; embeddings; dimensions and fractals; Poincaré maps and map-dynamics; empirical computational sciences vis-á-vis mathematics; Ulam's synergetics; Turing's instability and dissipative structures; chaos; dynamic entropies; Lorenz and Rossler models; predator-prey and replicator models; FPU and KAM phenomena; solitons and nonsolitons; coupled maps and pattern dynamics; cellular automata.

Introduction to Nonlinear Science

Introduction to Nonlinear Science PDF Author: G. Nicolis
Publisher: Cambridge University Press
ISBN: 9780521467827
Category : Mathematics
Languages : en
Pages : 274

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Book Description
The aim of this book is to develop a unified approach to nonlinear science, which does justice to its multiple facets and to the diversity and richness of the concepts and tools developed in this field over the years. Nonlinear science emerged in its present form following a series of closely related and decisive analytic, numerical and experimental developments that took place over the past three decades. It appeals to an extremely large variety of subject areas, but, at the same time, introduces into science a new way of thinking based on a subtle interplay between qualitative and quantitative techniques, topological and metric considerations and deterministic and statistical views. Special effort has been made throughout the book to illustrate both the development of the subject and the mathematical techniques, by reference to simple models. Each chapter concludes with a set of problems. This book will be of great value to graduate students in physics, applied mathematics, chemistry, engineering and biology taking courses in nonlinear science and its applications.

Introduction to Nonlinear Dynamics for Physicists

Introduction to Nonlinear Dynamics for Physicists PDF Author: H D I Abarbanel
Publisher: World Scientific
ISBN: 9814504122
Category : Science
Languages : en
Pages : 168

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Book Description
This series of lectures aims to address three main questions that anyone interested in the study of nonlinear dynamics should ask and ponder over. What is nonlinear dynamics and how does it differ from linear dynamics which permeates all familiar textbooks? Why should the physicist study nonlinear systems and leave the comfortable territory of linearity? How can one progress in the study of nonlinear systems both in the analysis of these systems and in learning about new systems from observing their experimental behavior? While it is impossible to answer these questions in the finest detail, this series of lectures nonetheless successfully points the way for the interested reader. Other useful problems have also been incorporated as a study guide. By presenting both substantial qualitative information about phenomena in nonlinear systems and at the same time sufficient quantitative material, the author hopes that readers would learn how to progress on their own in the study of such similar material hereon. Contents:IntroductionNonlinear Oscillator without DissipationEquilibrium States of a Nonlinear Oscillator with DissipationOscillations in Systems with Nonlinear Dissipation-GeneratorsThe Van der Pol GeneratorThe Poincaré MapSlow and Fast Motions in Systems with One Degree of FreedomForced Nonlinear Oscillators: Linear and Nonlinear ResonancesForced Generator: SynchronizationCompetition of ModesPoincaré Indices and Bifurcations of Equilibrium StatesResonance Interactions between OscillatorsSolitonsSteady Propagation of Shock WavesFormation of Shock WavesSolitons. Shock Waves. Wave Interaction. The Spectral ApproachWeak Turbulence. Random Phase ApproximationRegular Patterns in Dissipative MediaDeterministic Chaos. Qualitative DescriptionDescription of a Circuit with Chaos. Chaos in MapsBifurcations of Periodic Motions. Period DoublingControlled Nonlinear Oscillator. IntermittencyScenarios of the Onset of Chaos. Chaos through Quasi-PeriodicityCharacteristics of Chaos. Experimental Observation of ChaosMultidimensional Chaos. Discrete Ginzburg-Landau ModelProblems to Accompany the Lectures Readership: Physicists. keywords: “These lecture notes briefly introduce the reader to new ideas, so would be a useful addition to a library or a source of ideas for lectures or projects; a good student may also find this text useful as a quick introduction to many new ideas.” Contemporary Physics “Introduction to Nonlinear Dynamics for Physicists … is a compact and fairly terse high-level set of 24 lectures.” New Scientist

Chemical Oscillations, Waves, and Turbulence

Chemical Oscillations, Waves, and Turbulence PDF Author: Y. Kuramoto
Publisher: Springer Science & Business Media
ISBN: 3642696899
Category : Science
Languages : en
Pages : 165

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Book Description
Tbis book is intended to provide a few asymptotic methods which can be applied to the dynamics of self-oscillating fields of the reaction-diffusion type and of some related systems. Such systems, forming cooperative fields of a large num of interacting similar subunits, are considered as typical synergetic systems. ber Because each local subunit itself represents an active dynamical system function ing only in far-from-equilibrium situations, the entire system is capable of showing a variety of curious pattern formations and turbulencelike behaviors quite unfamiliar in thermodynamic cooperative fields. I personally believe that the nonlinear dynamics, deterministic or statistical, of fields composed of similar active (Le., non-equilibrium) elements will form an extremely attractive branch of physics in the near future. For the study of non-equilibrium cooperative systems, some theoretical guid ing principle would be highly desirable. In this connection, this book pushes for ward a particular physical viewpoint based on the slaving principle. The dis covery of tbis principle in non-equilibrium phase transitions, especially in lasers, was due to Hermann Haken. The great utility of this concept will again be dem onstrated in tbis book for the fields of coupled nonlinear oscillators.

Introduction to Nonlinear Optical Effects in Molecules and Polymers

Introduction to Nonlinear Optical Effects in Molecules and Polymers PDF Author: Paras N. Prasad
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 328

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Book Description
Molecular Dynamics in Restricted Geometries Edited by Joseph Klafter and J. M. Drake This investigation of the chemistry and physics of complex systems focuses on the role of spatial restrictions on molecular movement. A practical source-book for researchers in chemical physics, chemical engineering, and condensed matter physics, and for graduate students in these fields, it covers a broad range of topics and critically evaluates methods as they are employed. Among the many topics it covers are: relaxation and diffusion in restricted geometries, excitation energy transfer and photoinduced electron transfer phenomena in some confined systems, electron excitation transport in micelles, polymers and multilayers, and electron excitation transport on polymer chains. 1989 (0 471-60176-4) 437 pp.