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Author: Carsten Bolm
Publisher: John Wiley & Sons
ISBN: 3527318232
Category : Science
Languages : en
Pages : 483
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Book Description
The use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis. This first comprehensive treatment of this important research field covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community. A must for organic, inorganic, catalytic and complex chemists, as well as those working with/on organometallics.
Author: Carsten Bolm
Publisher: John Wiley & Sons
ISBN: 3527318232
Category : Science
Languages : en
Pages : 483
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Book Description
The use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis. This first comprehensive treatment of this important research field covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community. A must for organic, inorganic, catalytic and complex chemists, as well as those working with/on organometallics.
Author: Shinji Murai
Publisher: Springer
ISBN: 3540685251
Category : Science
Languages : en
Pages : 275
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Book Description
In the last few years a large repetoire of methods for the activation of unreactive organic functionalities and for their use in organic synthesis has been developed. In this volume, areas ranging from the activation of C-H bonds to the chemical transformation of dinitrogen are authoritatively discussed by leading experts in the field. To activate means to be able to cleave otherwise inert chemical bonds. The cleavage and formation of chemical bonds is fundamental to organic synthesis; these new activation methodologies make hitherto infeasible reactions extremely easy and create new opportunities for innovative organic transformations, for both industry and academia. This is the first book that provides a thorough and timely coverage of both inorganic and organic synthetic aspects of bond activation, thus giving a broad overview of the field and allowing both inorganic and organic chemists ready access to the methodologies involved.
Author: Arkaitz Correa
Publisher: Springer
ISBN: 3319497847
Category : Science
Languages : en
Pages : 342
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Book Description
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Author: Antonio Bianconi
Publisher: Springer Science & Business Media
ISBN: 3642714900
Category : Science
Languages : en
Pages : 339
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Book Description
This book the second volume in the "Springer Series in Biophysics" col lects together contributions to the conference on "Biophysics and Syn chrotron Radiation" held in July 86 at Frascati. This meeting addressed the advances on the structure of biological molecules obtained by using synchrotron radiation. In fact it was most timely to review the results of the research in biophysics which is rapidly developing at synchrotron radiation facilities. Moreover, there was interest to discuss the new perspectives opened up by the future high brilliance synchrotron radia tion sources. With the use of synchrotron radiation, x-ray spectroscopy of biological molecules is firmly established in the techniques of EXAFS and XANES. Contributions to the detailed knowledge of local structure of active sites of metalloproteins by this approach are presented in this volume, together with a number of studies of -the interaction of metal ions with other important biological macromolecular systems. Structural determination of very large biological systems at high reso lution, including a protein and its substrate, are reported. The experi mental advances in protein crystallography presented here reduce the time for solving protein structures, thus satisfying a major require ment of the rapidly-expanding field of protein engineering.
Author: Alfred M. Spormann
Publisher: Springer Nature
ISBN: 3031282183
Category : Science
Languages : en
Pages : 345
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Book Description
This textbook examines the fundamental principles of microbial metabolism and how a microbe's ecology is intrinsically interwoven with and a consequence of its metabolism. Further, it answers many questions frequently asked by students, such as: What are the mechanistic connections between simple phenotypic traits, ecological patterns and microbial metabolism and diversity? In the process, readers will be introduced to essential topics like metabolism and metabolic pathways, flux of energy and nutrients, genome size and fitness, competition, selection and drift. Moreover, the book conveys fundamental principles that show students how to approach the field of microbiology from a different, more unifying angle, e.g., how microbes’ access to environmentally available energy resources and the specific metabolism involved lies at the root of every ecologically significant microbial speciation. This aspect, together with its special focus on metabolism and ecological implications, make the book a must-read for all students of microbiology.
Author: Rui Shang
Publisher: Springer
ISBN: 9811031932
Category : Science
Languages : en
Pages : 225
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Book Description
This thesis presents the latest developments in new catalytic C–C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C–H bonds with high step efficiency. In this regard, it explores a mechanistic understanding of the newly discovered decarboxylative couplings and the catalytic reactivity of the iron catalyst with the help of density functional theory calculation. The thesis is divided into two parts, the first of which focuses on the development of a series of previously unexplored, inexpensive carboxylate salts as useful building blocks for the formation of various C–C bonds to access valuable chemicals. In turn, the second part is devoted to several new C–C bond formation methodologies using the most ubiquitous transition metal, iron, as a catalyst, and using the ubiquitous C–H bond as the coupling partner.
Author: Kenneth D. Karlin
Publisher: John Wiley & Sons
ISBN: 1118094352
Category : Science
Languages : en
Pages : 417
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Book Description
Covers the vastly expanding subject of oxidative processes mediated by copper ions within biological systems Copper-mediated biological oxidations offer a broad range of fundamentally important and potentially practical chemical processes that cross many chemical and pharmaceutical disciplines. This newest volume in the Wiley Series on Reactive Intermediates in Chemistry and Biology is divided into three logical areas within the topic of copper/oxygen chemistry— biological systems, theory, and bioinorganic models and applications—to explore the biosphere for its highly evolved and thus efficient oxidative transformations in the discovery of new types of interactions between molecular oxygen and copper ion. Featuring a diverse collection of subject matter unified in one complete and comprehensive resource, Copper-Oxygen Chemistry probes the fundamental aspects of copper coordination chemistry, synthetic organic chemistry, and biological chemistry to reveal both the biological and chemical aspects driving the current exciting research efforts behind copper-oxygen chemistry. In addition, Copper-Oxygen Chemistry: Addresses the significantly increasing literature on oxygen-atom insertion and carbon-carbon bond-forming reactions as well as enantioselective oxidation chemistries Progresses from biological systems to spectroscopy and theory, and onward to bioinorganic models and applications Covers a wide array of reaction types such as insertion and dehydrogenation reactions that utilize the cheap, abundant, and energy-containing O2 molecule With thorough coverage by prominent authors and researchers shaping innovations in this growing field, this valuable reference is essential reading for bioinorganic chemists, as well as organic, synthetic, and pharmaceutical chemists in academia and industry.
Author: Anthony John Kirby
Publisher: Royal Society of Chemistry
ISBN: 0854041753
Category : Science
Languages : en
Pages : 286
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Book Description
Designing artificial systems with catalytic efficiencies to rival those of natural enzymes is one of the great challenges facing science today. This introduction to the exciting area of artificial enzymes is suitable for both students and more senior researchers.
Author: Kenneth D. Karlin
Publisher: John Wiley & Sons
ISBN: 1118148207
Category : Science
Languages : en
Pages : 628
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Book Description
This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 57 continues to report recent advances with a significant, up-to-date selection of contributions from internationally-recognized researchers. The chapters of this volume are devoted to the following topics: Mechanisms of Water Oxidation Catalyzed by Ruthenium Coordination Complexes; Biomimetic and non-biological dinuclear Mx+-complex catalyzed alcoholysis reactions of phosphoryl transfer reactions; Photoactivated DNA Cleavage and Anticancer Activity of 3d-Metal Complexes; and more.
Author: Daniel L. Purich
Publisher: Elsevier
ISBN: 0123809258
Category : Science
Languages : en
Pages : 915
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Book Description
Far more than a comprehensive treatise on initial-rate and fast-reaction kinetics, this one-of-a-kind desk reference places enzyme science in the fuller context of the organic, inorganic, and physical chemical processes occurring within enzyme active sites. Drawing on 2600 references, Enzyme Kinetics: Catalysis & Control develops all the kinetic tools needed to define enzyme catalysis, spanning the entire spectrum (from the basics of chemical kinetics and practical advice on rate measurement, to the very latest work on single-molecule kinetics and mechanoenzyme force generation), while also focusing on the persuasive power of kinetic isotope effects, the design of high-potency drugs, and the behavior of regulatory enzymes. - Historical analysis of kinetic principles including advanced enzyme science - Provides both theoretical and practical measurements tools - Coverage of single molecular kinetics - Examination of force generation mechanisms - Discussion of organic and inorganic enzyme reactions
